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Few-wall carbon nanotubes covalently functionalized by ferrocene groups for bioelectrochemical devices.

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Abstract

The present work reports the covalent functionalization of few-wall CNTs (FWCNTs) by ferrocene derivatives to i) improve their dispersion efficiency in water and ii) to graft electroactive chemical groups on their side-walls in order to promote electron transfer to biomolecules. The functionalized CNTs (f-CNTs) are used to modify a glassy carbon electrode and this modified electrode is used for oxidizing the cofactor NADH (dihydronicotinamide adenine dinucleotide).

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Acknowledgments

This work has been supported by the French National Research Agency (ANR), project ANR-10-BLAN-0819-01-SPRINT.

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Authors and Affiliations

  1. Laboratoire de Chimie Physique et Microbiologie pour l’Environnement, UMR 7564 CNRS-Lorraine University, F-54602, Villers-les-Nancy, France

    Naoual Allali, Veronika Urbanova, Jeremy Waldbock, Mathieu Etienne, Martine Mallet, Alain Walcarius & Manuel Dossot

  2. Laboratoire de Structure et Réactivité des Systèmes Moléculaires Complexes, UMR 7565 CNRS-Lorraine University, F-54506, Vandoeuvre-les-Nancy, France

    Naoual Allali, Victor Mamane & Yves Fort

  3. Département P2M, Institut Jean Lamour, UMR 7198 CNRS-Lorraine University, Ecole des Mines, F-54042, Nancy, France

    Xavier Devaux

  4. Département CP2S, Institut Jean Lamour UMR 7198 CNRS-Lorraine University, F-54506, Vandoeuvre-les-Nancy, France

    Brigitte Vigolo & Edward McRae

  5. Department of Engineering Sciences and Mathematics, Lulea Technical University, SE-97187, Lulea, Sweden

    Naoual Allali, Maxime Noël & Alexander V. Soldatov

Authors
  1. Naoual Allali
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  2. Veronika Urbanova
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  3. Victor Mamane
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  4. Jeremy Waldbock
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  5. Mathieu Etienne
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  6. Martine Mallet
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  7. Xavier Devaux
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  8. Brigitte Vigolo
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  9. Yves Fort
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  10. Alain Walcarius
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  11. Maxime Noël
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  12. Alexander V. Soldatov
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  13. Edward McRae
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  14. Manuel Dossot
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Allali, N., Urbanova, V., Mamane, V. et al. Few-wall carbon nanotubes covalently functionalized by ferrocene groups for bioelectrochemical devices.. MRS Online Proceedings Library 1451, 111–116 (2012). https://doi.org/10.1557/opl.2012.1337

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  • DOI: https://doi.org/10.1557/opl.2012.1337

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