Issue 7, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and reactivity of areneruthenium pyranone and pyridinone complexes

Glen Capper,   Lee C. Carter,   David L. Davies,   John Fawcett  and  David R. Russell  

Abstract

The complexes [Ru(mes)Cl(L)](mes = 1,3,5-trimethylbenzene; HL = a pyranone or a pyridinone) have been synthesised and characterised. Reaction of [Ru(mes)Cl(L)](HL = 2-ethyl-3-hydroxypyran-4-one) with CO in the presence of AgBF4 gave [Ru(mes)L(CO)][BF4]. This carbonyl complex reacts with nucleophiles to give substitution products [Ru(mes)L(L′)][BF4](L′= H2O or H2NCH2Ph). One of the initial complexes, [Ru(mes)Cl(L)](HL = 2-methyl-3-hydroxypyran-4-one) and the carbonyl complex have been characterised by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/DT9960001399
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 1399-1403

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Synthesis and reactivity of areneruthenium pyranone and pyridinone complexes

G. Capper, L. C. Carter, D. L. Davies, J. Fawcett and D. R. Russell, J. Chem. Soc., Dalton Trans., 1996, 1399 DOI: 10.1039/DT9960001399

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