Issue 22, 1995
From the journal:

Journal of the Chemical Society, Dalton Transactions

Complexes of Rh(C5Me5) with picolinic acid, pyrones and pyridinones

Andrew P. Abbott,   Glen Capper,   David L. Davies,   John Fawcett  and  David R. Russell  

Abstract

Picolinic acid (pyridine-2-carboxylic acid), pyrones and pyridinones (HL) reacted with [{Rh(C5Me5)Cl2}2] and sodium methoxide to give complexes [Rh(C5Me5)Cl(L)] which are all soluble in water. The structures where HL = picolinic acid or 2-methylpyran-4-one have been determined by X-ray diffraction. The aquation of the complexes when dissolved in water has been examined by NMR spectroscopy and conductivity measurements and the results indicate an equilibrium between chloro and aqua species which is fast on the NMR time-scale.

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Article information

DOI
https://doi.org/10.1039/DT9950003709
Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 3709-3713

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Complexes of Rh(C5Me5) with picolinic acid, pyrones and pyridinones

A. P. Abbott, G. Capper, D. L. Davies, J. Fawcett and D. R. Russell, J. Chem. Soc., Dalton Trans., 1995, 3709 DOI: 10.1039/DT9950003709

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