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HNC-type approximation for transport processes in electrolytic solutions

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Abstract

On the basis of the diffusion approach in the theory of transport processes of electrolytic solutions we introduce a “direct correlation force” as a generalization of the direct correlation function in equilibrium. Starting from an approximation for the three-particle distribution function we derive a HNC (hypernetted chain)-type equation for calculation of binary distribution functions in nonequilibrium. The derivation is consistent with equilibrium theory.

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Authors and Affiliations

  1. Sektion Physik der Wilhelm-Pieck-UniversitÄt Rostock, 2500, Rostock, Germany

    Dietrich Kremp, Hartmut Krienke & Rainer SÄndig

  2. Sektion Physik der Humboldt-UniversitÄt zu Berlin, 1040, Berlin, Germany

    Werner Ebeling

Authors
  1. Dietrich Kremp
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  2. Werner Ebeling
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  3. Hartmut Krienke
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  4. Rainer SÄndig
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Kremp, D., Ebeling, W., Krienke, H. et al. HNC-type approximation for transport processes in electrolytic solutions. J Stat Phys 33, 99–106 (1983). https://doi.org/10.1007/BF01009751

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  • DOI: https://doi.org/10.1007/BF01009751

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