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Cluster chemistry. 85. Addition of a gold acetylide to an Ru5 cluster. X-ray structure of AuRu5(μ5-C2PPh2)(μ-C2Ph)(μ-PPh2)(CO)13(PPh3)

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Abstract

The reaction between Ru5(μ5-C2PPh2)(μ-PPh2)(CO)13 and Au(C2Ph)(PPh3) afforded AuRu5(μ5-C2PPh2)(μ-C2Ph)(μ-PPh2)(CO)13 (PPh3), in which the Ru5 cluster has a scorpion geometry; the Au(PPh3) group bridges one of the Ru-Ru bonds of the Ru3 triangle, while the C2Ph group bridges one of the tail Ru-Ru vectors.

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References

  1. C. J. Adams, M. I. Bruce, B. W. Skelton, and A. H. White,J. Organomet. Chem., Part 84, submitted.

  2. M. I. Bruce, M. L. Williams, B. W. Skelton, and A. H. White (1989).J. Organomet. Chem. 369, 393.

    Google Scholar 

  3. M. I. Bruce, M. J. Liddell, and B. K. Nicholson (1990).Appl. Organomet. Chem. 4, 457.

    Google Scholar 

  4. M. Catti, G. Gervasio, and S. A. Mason (1977).J. Chem. Soc., Dalton Trans. 2260.

  5. P. Braunstein, G. Predieri, A. Tiripicchio, and E. Sappa (1982).Inorg. Chim. Acta 63, 113.

    Google Scholar 

  6. M. I. Bruce, M. J. Liddell, and E. R. T. Tiekink (1990).J. Organomet. Chem. 391, 81.

    Google Scholar 

  7. M. I. Bruce, E. Horn, J. G. Matisons, and M. R. Snow (1984).Aust. J. Chem. 37, 1163.

    Google Scholar 

  8. S. R. Hall and J. M. Stewart, eds. (1989). XTAL Users' Manual, Version 2.6, Universities of Western Australia and Maryland.

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Authors and Affiliations

  1. Jordan Laboratories, Department of Physical and Inorganic Chemistry, University of Adelaide, P.O. Box 498, 5001, Adelaide, South Australia

    Chris J. Adams & Michael I. Bruce

  2. Department of Chemistry, University of Western Australia, 6009, Nedlands, Western Australia

    Brian W. Skelton & Allan H. White

Authors
  1. Chris J. Adams
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  2. Michael I. Bruce
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  3. Brian W. Skelton
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  4. Allan H. White
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For Part 84, see Ref. 1.

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Adams, C.J., Bruce, M.I., Skelton, B.W. et al. Cluster chemistry. 85. Addition of a gold acetylide to an Ru5 cluster. X-ray structure of AuRu5(μ5-C2PPh2)(μ-C2Ph)(μ-PPh2)(CO)13(PPh3). J Clust Sci 3, 219–227 (1992). https://doi.org/10.1007/BF00702884

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  • DOI: https://doi.org/10.1007/BF00702884

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