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Integrity and Structural Characteristics of the M6E8 (E=S, Se, Te) Cluster Core: Syntheses and Structures of [Co6S8(PR3)6]n+ (R=Me2Ph, n=1; R=OMe, n=0)

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Abstract

Two new members of the hexanuclear series [Co6S8(PR3)6]n+, complexes [Co6S8(PMe2Ph)6](ClO4) (1) and [Co6S8P(OMe)3 6] (2), have been synthesizes and characterized by X-ray diffraction analyses. Their formation process was postulated to go through trinuclear μ3--S bridged moieties. The structural characteristics of the M6E8P6 skeleton of a whole series of [M6E8(PR3)6]n+ (M=Co, Cr, Fe, Mo; E=S, Se, Te) complexes are presented in terms of atomic distances and core volumes.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, 510275, People's Republic of China

    Bei-Sheng Kang, Xiang-Yang Yu, Hua-Xin Zhang, Ye-Xiang Tong, Cheng-Yong Su, Zhong-Ning Chen & Han-Qin Liu

  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, People's Republic of China

    Ting-Bin Wen

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  1. Bei-Sheng Kang
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Kang, BS., Wen, TB., Yu, XY. et al. Integrity and Structural Characteristics of the M6E8 (E=S, Se, Te) Cluster Core: Syntheses and Structures of [Co6S8(PR3)6]n+ (R=Me2Ph, n=1; R=OMe, n=0). Journal of Cluster Science 10, 429–443 (1999). https://doi.org/10.1023/A:1022681127451

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