Skip to main content
SpringerLink
Log in

Crystal structure of the hemitoluene solvate of racemiccis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr3 and toluene moieties

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The complexcis-[Ru(bpy)2(PPr3)Cl+][ClO −4 ] · 0.5 (toluene) crystallizes as a racemate in the monoclinic space group P21/n. Both the PPr3 ligand and the toluene of crystallization are subject to disorder. Ruthenium—ligand distances are: Ru−PPr3=2.348(2) Å, Ru−Cl=2.426(2) Å and Ru−N(bpy)=2.035(6)–2.112(5) Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Churchill, M.R.; Krajkowski, L.M.; Huynh, M.H.V.; Takeuchi, K.J.J. Chem. Cryst. 1996,26, 111.

    Google Scholar 

  2. Churchill, M.R.; Krajkowski, L.M.; Huynh, M.H.V.; Takeuchi, K.J.J. Chem. Cryst. 1996,26, 67.

    Google Scholar 

  3. Churchill, M.R.; Krajkowski, L.M.; Huynh, M.H.V.; Takeuchi, K.J.J. Chem. Cryst. 1996,26, 347.

    Google Scholar 

  4. Churchill, M.R.; Lake, C.H.; Bessel, C.A.; Huynh, M.H.V. McCourt, J.; Takeuchi, K.J.J. Chem. Cryst. 1996,26, 267.

    Google Scholar 

  5. Marmion, M.E.; Takeuchi, K.J.J. Am. Chem. Soc. 1988,110, 1472.

    Google Scholar 

  6. Raymond, K.Chem. Eng. News 1983,61 (Dec 5), 4.

    Google Scholar 

  7. Wosely, W.C.J. Chem. Educ. 1973,50, A335.

    Google Scholar 

  8. Bearden, J.A.Rev. Mod. Phys. 1967,39, 78.

    Google Scholar 

  9. Churchill, M.R.; Lashewycz, R.A.; Rotella, F.J.Inorg. Chem. 1977,16, 265.

    Google Scholar 

  10. Sheldrick, G.M..SHELTXL PLUS, An integrated system for solving, refining and displaying crystal structures from diffraction data; For Nicolet R3m/V; University of Göttingen, Germany, 1987.

    Google Scholar 

  11. Sheldrick, G.M.SHELTXL PLUS, Siemens Analytical Instruments; Madison, WI, 1989.

  12. International Tables for X-Ray Crystallography; Kynoch Press: Birmingham, England. Volume 4, 1974: (a) pp. 99–101 (b) pp. 149–150.

  13. Churchill, M.R.Inorg. Chem. 1973,12, 1213.

    Google Scholar 

  14. Churchill, M.R.; See, R.F.; Bessell, C.A.; Takeuchi, K.J.,J. Chem. Cryst. 1996,26, 543.

    Google Scholar 

  15. Churchill, M.R.; Bau, R.Inorg. Chem. 1968,7, 2606.

    Google Scholar 

  16. Bau, R.; Fontal, B.; Kaesz, H.D.; Churchill, M.R.J. Am. Chem. Soc. 1967,89, 6374.

    Google Scholar 

Download references

Author information

Author notes

  1. Ronald F. See

    Present address: Department of Chemistry, Saint Louis University, 63103, St. Louis, Missouri

Authors and Affiliations

  1. Department of Chemistry, Natural Sciences & Mathematics Complex, North Campus, University at Buffalo, State University of New York, 14260-3000, Buffalo, New York, 14260-3000

    Melvyn Rowen Churchill, Ronald F. See, Carol A. Bessel & Kenneth J. Takeuchi

Authors
  1. Melvyn Rowen Churchill
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ronald F. See
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Carol A. Bessel
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kenneth J. Takeuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Churchill, M.R., See, R.F., Bessel, C.A. et al. Crystal structure of the hemitoluene solvate of racemiccis-bis(bipyridyl)chloro(tri-n-propylphosphine)ruthenium(II) perchlorate, a species with disordered PPr3 and toluene moieties. J Chem Crystallogr 26, 667–675 (1996). https://doi.org/10.1007/BF01991962

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01991962

Key Words

Search

Navigation