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Micellar effect of sodium dodecyl sulfate on the reactions between iron(II) and p-benzoquinone, and iron(III) and hydroquinone

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Abstract

The micellar effet of sodium dodecyl sulfate (SDS) on the initial stages of the reaction between (1) Fe(II) and p-benzoquinone, and (2) Fe(III) and hydroquinone have been investigated. In the former case acceleration was observed, the rate-[surfactant] profile showing a maximum. SDS has an inhibitory effect on the latter reaction. Kinetic analysis has been carried out using Berezin's approach.

Abstract

Исследовали мицеллярный эффект додецилсульфата натрия (ДСН) на начальной стадии реакции 1) Fe(II) с парабензохиноном и 2) Fe(III) с гидрохиноном. В первом случае наблюдали ускорение и кривая зависимости скорости от концентрации ПАВ-а обладает максимумом. ДСН оказывает ингибирующий эффект на вторую реакцию. Исходя из модели Березина, произведен кинетический анализ.

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Authors and Affiliations

  1. School of Chemistry, Andhra University, 530 003, Visakhapatnam, India

    P. V. Subba Rao, G. S. R. Krishna Rao, K. Ramakrishna & P. S. N. Murty

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  1. P. V. Subba Rao
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  2. G. S. R. Krishna Rao
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  3. K. Ramakrishna
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  4. P. S. N. Murty
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Subba Rao, P.V., Krishna Rao, G.S.R., Ramakrishna, K. et al. Micellar effect of sodium dodecyl sulfate on the reactions between iron(II) and p-benzoquinone, and iron(III) and hydroquinone. React Kinet Catal Lett 43, 209–216 (1991). https://doi.org/10.1007/BF02075435

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  • DOI: https://doi.org/10.1007/BF02075435

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