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Luminescence and sensory properties of PMMA films doped with a boron chelate

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Abstract

The optical sensory properties of polymethylmethacrylate films doped with 2,2-difluoro-4-methylnaphtho-[2,1-e]-1,3,2-dioxaborine (1) for water vapor are found. A mechanism of the optical response is proposed: water molecules contribute through hydrogen bonds to the dissociation of aggregates of 1 having intense excimer luminescence of J-aggregates. A sharp quenching of luminescence is observed. The spectrum of the films after exposure to water vapor corresponds to the monomer luminescence of 1.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok, 690022, Russia

    A. G. Mirochnik & E. V. Fedorenko

  2. Institute of Automation and Control Processes, Far East Branch, Russian Academy of Sciences, Vladivostok, 690041, Russia

    I. G. Nagornyi

  3. Far Eastern Federal University, Vladivostok, 690091, Russia

    O. A. Starovoit

Authors
  1. A. G. Mirochnik
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  2. E. V. Fedorenko
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  3. I. G. Nagornyi
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  4. O. A. Starovoit
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Corresponding author

Correspondence to A. G. Mirochnik.

Additional information

Original Russian Text © A.G. Mirochnik, E.V. Fedorenko, I.G. Nagornyi, O.A. Starovoit, 2017, published in Optika i Spektroskopiya, 2017, Vol. 122, No. 5, pp. 787–791.

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Mirochnik, A.G., Fedorenko, E.V., Nagornyi, I.G. et al. Luminescence and sensory properties of PMMA films doped with a boron chelate. Opt. Spectrosc. 122, 764–767 (2017). https://doi.org/10.1134/S0030400X17050149

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  • DOI: https://doi.org/10.1134/S0030400X17050149

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