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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Notizen: Synthese Dicyclopentadienyl-Titan(IV)- substituierter Carbodiimide/Syntheses of Dicyclopentadienyl-Titanium(IV) Substituted Carbodiimides

  • Herbert Plenio and Herbert W. Roesky
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1989-0121
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(MeCp)2Ti(NCO)(NCNSiMe3) (1), Cp2Ti(NCO)(NCNSiMe3) (2) and Cp2Ti(NCNSiMe3)2 (3) are formed by the reaction of (MeCp)Ti(NCO)2 and Cp2Ti(NCO)2 with LiN(SiMe3)2. All three new com pounds are thermally and hydrolytically unstable red solids that were characterized by mass spectrometry. 1H NMR and elemental analysis.

Keywords: Carbodiimides; Titanium; Isocyanate; Synthesis
Received: 1988-7-29
Published Online: 2014-6-2
Published in Print: 1989-1-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 44 Issue 1

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Articles in the same Issue

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Contents
Synthese und Kristallstruktur von tetramerem N,N'-Diphenylformamidinato-gold(I), [Au(PhNCH NPh)]4/Synthesis and Structure of Tetrameric N,N'-Diphenylformamidinato Gold(I), [Au(PhNCHNPh)]4
Synthesis and Crystal and Molecular Structure of trans-Dichloro(ethanedial dioximato(1—)-N,N')(ethanedial dioxime-N,N')rhodium(III)
Die Struktur von [(tert-C4H9)3PI][W(CO)4l3] — ein Beitrag zur Diskussion des Akzeptorverhaltens von Iodphosphoniumionen/ The Structure of [(tert-C4H9)3PI][W(CO)4l3] — a Contribution on the Acceptor Properties of Iodophosphonium Ions
Zur Photoionisation und Ionenfragmentation von SF4/Photoionization and Ion Fragmentation of SF4
Photoionisationsmassenspektren von MethyI(trifluormethyl)sulfan CH3SCF3 [1]/Photoionization Mass Spectra of Methyl(trifluoromethyl)sulfan CH3SCF3 [1]
Photoionenspektroskopie an Schwefelchloridpentafluorid SF5Cl, das Ionisationspotential von Schwefelpentafluorid SF5/Photoion Spectroscopy of Sulfurchloridepentafluoride SF5Cl, the Ionization Potential of Sulfurpentafluoride SF5
Dithiocarbimates from Sulfonamides, Part 1: Preparation and X-Ray Crystal Structures of K2[S2C = N—SO2—C6H5] · 2H2O and K2[S2C = N—SO2—C6H4—Cl] · 2H2O
Dithiocarbimates from Sulfonamides, Part 2: Preparation and X-Ray Crystal Structures o f (PPh4)2[Ni(S2C = N —S 0 2—Ph)2] and (PPh4)2[Ni(S2C = N —S 0 2—C6H4—CI)2] * 2 H20
Neue Übergangsmetallkomplexe mit dem Liganden Me2S(O )=NPPh2=N— /New Transition Metal Complexes with the Ligand Me2S(O)=NPPh2=N —
Dibenzoylmethane Reaction with Dichlorophenylphosphine: Oxygen Transfer from Carbon to Phosphorus via a Defined C2PO3 Phosphorane
Borylierung von Sulfamiden, Sulfoniminen und Sulfondiiminen/Borylation of Sulfamides, Sulfonimines and Sulfonediimines
13C- und 15N-NMR-spektroskopische Untersuchungen einiger Pentacarbonylchrom-Aminophosphan-Komplexe/13C and 15N NMR Spectroscopic Study of Some Pentacarbonylchromium-Aminophosphane Complexes
Phasendiagramme einiger Methylhalogensilane mit Pyridin und Lutidin Phase Diagrams of Methylhalogenosilanes with Pyridine and Lutidine
Reaktionen der Natrium-Komplexe aromatischer Ether mit Dichlor(diorganylamino)boranen/Reactions of Sodium Complexes of Aromatic Ethers with Dichloro(diorganylamino)boranes
Schwingungsspektren der Clusterverbindung Nb6F15/Vibrational Spectrum of the Cluster Compound Nb6F15
Synthesis of Water Soluble Tetrairidium Clusters Suitable for Heavy Atom Labelling of Proteins
Chemie an starren Grenzflächen, 9 [1]. Eigenschaften und Verhalten Oniumgruppen-modifizierter Aerosile Einige Beispiele interpartikulärer Reaktionen/Chemistry on Rigid Interfaces, 9 [1]. Properties and Behaviour of Onium Group Modified Aerosils Some Examples of Interparticular Reactions
The Synthesis of Some Cyclopentadienyliron-Indium Complexes
Notizen: Synthese Dicyclopentadienyl-Titan(IV)- substituierter Carbodiimide/Syntheses of Dicyclopentadienyl-Titanium(IV) Substituted Carbodiimides
Notizen: Synthese und Struktur von 2,4,6,8-Tetrakis(diisopropylamino)- 2,4,6,8-tetrabora-tricyclo-[3.3.0.03,7]-octan Synthesis and Structure of 2,4,6,8-Tetrakis(diisopropylamino)- 2,4,6,8-tetrabora-tricyclo-[3.3.0.03,7]-octane
Notizen: Synthesis and Silica Gel Promoted Rearrangement of 5-Methylthio-3-carbo-t-butoxy-pent-3-en-2-one
Notizen: Phasendiagramme von Systemen, bestehend aus Aluminiumhalogeniden und Pyridiniumhalogeniden, III. Die Phasendiagramme der Systeme Aluminiumbromid-Pyridiniumiodid und Aluminiumchlorid-Pyridiniumbromid/Phase Diagrams of Aluminium Halide- Pyridinium Halide Systems, III. Determination of the Phase Diagrams Aluminium Bromide-Pyridinium Iodide and Aluminium Chloride-Pyridinium Bromide
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