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Treatment of Acid Mine Drainage Using a Fly Ash Zeolite Column

Behandlung von saurem Grubenwasser in Säulen gefüllt mit Zeoliten aus Flugasche

Tratamiento de drenaje ácido de minas usando una columna de zeolita de ceniza volante

粉煤灰合成沸石处理酸性矿山废水

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Abstract

Acid mine drainage (AMD) and fly ash from thermal power plants both pose substantial environmental problems in India. Fly ash from the Talcher super thermal power plant was converted into zeolite and used in a column to treat AMD from the abandoned Gorbi opencast mines (Singrauli coalfields, NCL). The pH of the mine water increased, and 100 % of the total hardness, Ca hardness, Mg hardness, Mn, Zn, Pb, Cd, Ni, and acidity were removed, along with 99 % of the Fe and 90 % of the Cu.

Zusammenfassung

Sowohl saure Grubenwässer als auch Flugaschen aus Wärmekraftwerken stellen in Indien ein erhebliches Umweltproblem dar. Flugasche des Talcher Großkraftwerkes wurde in Zeolite umgewandelt und in einer Säule für die Behandlung von saurem Grubenwasser aus den stillgelegten Gorbi Tagebauen (Singrauli Kohlefelder, NCL) benutzt. Der pH-Wert des Grubenwassers stieg und 100 % Gesamthärte, Ca- und Mg-Härte, Mn, Zn, Pb, Cd, Ni und Azidität sowie 99 % Fe und 90 % Cu wurden beseitigt.

Resumen

El drenaje ácido de minas (AMD) y las cenizas volantes provenientes de centrales térmicas, plantean serios problemas ambientales en India. Las cenizas volantes de la planta Talcher fueron convertidas en zeolitas y usadas en una columna para tratar AMD proveniente de las minas a cielo abierto Gorbi (campos de carbon Singrauli, NCL), abandonadas hace tiempo. El pH del agua de la mina se incrementó y el 100 % de la dureza total, dureza en Ca, dureza en Mg, Mn, Zn, Pb, Cd, Ni y acidez fue removida, además del 99 % del Fe y 90 % del Cu.

抽象

火电厂酸性矿山废水(AMD)和粉煤灰都将引发印度严重的环境问题。本文利用由Talcher超级电厂粉煤灰合成的沸石作为淋滤柱填料,处理弃Gorbi露天矿(NCL公司辛格劳利煤田)的酸性矿山废水。经处理,矿山废水pH值提高,总硬度、Ca硬度、Mg硬度、锰(Mn)、锌(Zn)、铅(Pb)、镉(Cd)、镍(Ni)及酸度的去除率达100 %,铁(Fe)和铜(Cu)的去除率分别达99 %和90 %。

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References

  • Akcil C, Koldas S (2006) Acid mine drainage (AMD): cause, treatment and case studies. J Clean Prod 14:1139–1145. doi:10.1016/j.jclepro.2004.09.006

    Article  Google Scholar 

  • Arnold EG, Lemore SC, Andrew DE (1992) Standard methods for examination of water and waste water, 18th edn. American Public Health Association, Washington DC

    Google Scholar 

  • ASTM D 4874–95 (1995) Standard test method for leaching solid material in a column apparatus. Annual book of ASTM standards, vol 11.04. American Society for Testing and Materials (ASTM), West Conshohocken, pp 78–84

    Google Scholar 

  • Azapagic A (2004) Developing a framework for sustainable development indicators for the mining and minerals industry. J Clean Prod 12:639–662. doi:10.1016/S0959-6526(03)00075-1

    Article  Google Scholar 

  • Cama J, Ayora C, Querol X, Gonor J (2005) Dissolution kinetics of synthetic zeolite NaP1 and its implication to zeolite treatment of contaminated water. Environ Sci Technol 39:4871–4877. doi:10.1021/es0500512

    Article  Google Scholar 

  • Derkowski A, Franus W, Beran E, Czimerova A (2006) Properties and potential applications of zeolitic materials produced from fly ash using simple method of synthesis. Powder Technol 166:47–54

    Article  Google Scholar 

  • Doye I, Duchesne J (2003) Neutralisation of acid mine drainage with alkaline industrial residues: laboratory investigation using batch leaching test. Appl Geochem 18:1197–1213. doi:10.1016/S0883-2927(02)00246-9

    Article  Google Scholar 

  • Fungaro DA, Izidoro JDC (2006) Remediation of acid mine drainage using zeolites synthesised from coal fly ash. Quim Nova 29(4):735–740

    Article  Google Scholar 

  • Inada M, Tsujimoto H, Eguchi Y, Enomoto N, Hojo J (2005) Microwave assisted zeolite synthesis from coal fly ash in hydrothermal process. Fuel 84:1482–1486. doi:10.1016/j.fuel.2005.02.002

    Article  Google Scholar 

  • Indian Standard IS: 3025 (2009) Methods of sampling and test (physical and chemical) for water used in industry, Bureau of Indian Standards, New Delhi

    Google Scholar 

  • Jain KA, Gaggar S (2013) Present status of availability, utilization and other options to increase effective use of fly ash in India. Presented, 3rd Annual International Summit: fly ash utilisation, New Delhi, India, Mission Energy Foundation, Mumbai, India

  • Johnson DB (2003) Chemical and microbiological characteristics of mineral spoils and drainage waters at abandoned coal and metal mines. Water Air Soil Pollut 3:47–66. doi:10.1023/A:1022107520836

    Article  Google Scholar 

  • Johnson DB, Hallberg KB (2005) Acid mine drainage remediation options: a review. Sci Total Environ 338:3–14. doi:10.1016/j.scitotenv.2004.09.002

    Article  Google Scholar 

  • Leggo PJ (1994) Use of zeolitic tuff for control and recycling of effluents. In: Institution of Mining and Metallurgy, Hydrometallurgy, Springer, Netherlands, pp 815–824

  • Li LY, Tazaki K, Lai R, Shiraki K, Asada R, Watanabe H, Chen M (2008) Treatment of acid rock drainage by Clinoptilolite - Adsorptivity and Structural stability for different pH environments. Appl Clay Sci 39(1–2):1–9

    Article  Google Scholar 

  • McKinnon W, Choung JW, Xu Z, Finch JA (2000) Magnetic seed in ambient temperature ferrite process applied to acid mine drainage treatment. Environ Sci Technol 34:2576–2581. doi:10.1021/es9910863

    Article  Google Scholar 

  • Mondragon F, Rincon F, Sierra L, Escobar J, Ramirez J, Fernandez J (1990) New perspectives for coal ash utilization; synthesis of zeolitic materials. Fuel 69:263–266. doi:10.1016/0016-2361(90)90187-u

    Article  Google Scholar 

  • Moreno N, Querol X, Carles A (2001) Utilisation of zeolites synthesized from coal fly ash for the purification of acid mine waters. Environ Sci Technol 35:3526–3534. doi:10.1021/es0002924

    Article  Google Scholar 

  • Moriyama R, Takeda S, Onozaki M, Katayama Y, Shiota K, Fukuda T, Sugihara H, Tani Y (2005) Large scale synthesis of artificial zeolite from coal fly ash with a small charge of alkaline solution. Fuel 84:1455–1461. doi:10.1016/j.fuel.2005.02.026

    Google Scholar 

  • Motsi T, Rowson NA, Simmons MJH (2009) Adsorption of heavy metals from acid mine drainage by natural zeolite. Int J Miner Process 92(1–2):42–48

    Article  Google Scholar 

  • Prasad B, Mortimer RJG (2011) Treatment of acid mine drainage using fly ash zeolite. Water Air Soil Poll 218:667–679

    Article  Google Scholar 

  • Prasad B, Maity S, Kumari S, Mortimer RJG (2012) Synthesis and characterisation of zeolite prepared from coal ash by hydrothermal process. Environ Technol 33(1):37–50

    Article  Google Scholar 

  • Rios CA, Williams CD, Roberts CL (2008) Removal of heavy metals from acid mine drainage using coal fly ash, natural clinker and synthetic zeolites. J Hazard Mater 156:23–35. doi:10.1016/j.jhazmat.2007.11.123

    Article  Google Scholar 

  • Somerset V, Petrik I, Iwuoha E (2008) Alkaline hydrothermal conversion of fly ash filtrates into zeolite: the removal of mercury and lead ion from wastewaters. J Environ Manage 87:125–131. doi:10.1016/j.jenvman.2007.01.033

    Article  Google Scholar 

  • Tsishvili GV, Andronikashvili TG, Kirov GN, Filizova LD (1992) Natural zeolites. Ellis Horwood Ltd, London

    Google Scholar 

  • Xenidis A, Mylona E, Paspaliaris I (2002) Potential use of lignite fly ash for control of acid generation from sulphidic wastes. Waste Manage 22:631–636. doi:10.1016/S0956-053X(01)00053-8

    Article  Google Scholar 

  • Quirol X, Moreno N, Umana JC, Alastuey A, Hernandez E, Lopez-Solar A, Plana F (2002) Synthesis of zeolites from coal fly ash: an overview. Int J Coal Geol 50:413–423

    Article  Google Scholar 

Download references

Acknowledgments

The authors are grateful to the Ministry of Coal, Government of India for funding the Grant-in-aid project on AMD treatment. The authors are also grateful to Dr. Amalendu Sinha, Director of the Central Institute of Mining and Fuel Research Institute, Dhanbad, India for the support provided during the investigation period.

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Correspondence to Bably Prasad.

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Prasad, B., Kumar, H. Treatment of Acid Mine Drainage Using a Fly Ash Zeolite Column. Mine Water Environ 35, 553–557 (2016). https://doi.org/10.1007/s10230-015-0373-1

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