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Microstructure of copolymers of vinylidene cyanide, methacrylonitrile and acrylonitrile with methyl α acetoxyacrylate, a captodative monomer

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Summary

Copolymers of vinylidene cyanide (1a) methacrylonitrile (1b) and acrylonitrile (1c) with a captodative monomer, methyl α acetoxyacrylate were synthesized by radical copolymerization and their microstructures were studied by 13C NMR spectroscopy.

The copolymer of 1a with methyl α-acetoxyacrylate (2) has mostly an alternating structure but the copolymers of 1b and 1c with 2 are rather statistical. The measurement of their reactivity ratios for these two reactions is in agreement with the proposed structures.

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Authors and Affiliations

  1. Faculté des Sciences de Saint-Etienne, Laboratoire de Chimie Organique Macromoléculaire, 23, rue Dr. Michelon, F-42023, Saint-Etienne Cedex 2, France

    Jean-Pierre Monthéard, Amar Zerroukhi & Isabelle Ouillon

  2. Faculté des Sciences et Technique “Gueliz”, Département de Chimie, Université de Cadi Ayyad, BP 618, Marrakech, Maroc

    Mustapha Raihane

  3. Service Central d'Analyse, CNRS, BP22, F-69390, Vernaison, France

    Quang-Tho Pham

Authors
  1. Jean-Pierre Monthéard
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  2. Amar Zerroukhi
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  3. Isabelle Ouillon
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  4. Mustapha Raihane
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  5. Quang-Tho Pham
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Monthéard, JP., Zerroukhi, A., Ouillon, I. et al. Microstructure of copolymers of vinylidene cyanide, methacrylonitrile and acrylonitrile with methyl α acetoxyacrylate, a captodative monomer. Polymer Bulletin 36, 709–716 (1996). https://doi.org/10.1007/BF00338634

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  • DOI: https://doi.org/10.1007/BF00338634

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