In:
The Journal of Chemical Physics, AIP Publishing, Vol. 53, No. 5 ( 1970-09-01), p. 1682-1685
Kurzfassung:
The ESR spectra have been obtained for six complexes with the general formulas [Ni(diars)2X2] X and [Co(diars)2X2] 0, where X is Cl, Br, and NCS and diars is o-phenylenebis(dimethylarsine), using pure polycrystalline solids and, in the case of the nickel complexes, solutions, and frozen solutions. Ligand hyperfine interactions with 75As, 35,37Cl, 79,81Br, and 14N have been observed and discussed. The data suggest that a model based on d7 Ni(III) with a Ag2 ground state may be adequate for these complexes.
Materialart:
Online-Ressource
ISSN:
0021-9606
,
1089-7690
Sprache:
Englisch
Verlag:
AIP Publishing
Publikationsdatum:
1970
ZDB Id:
3113-6
ZDB Id:
1473050-9
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