Description: The sediment record from Rodderberg potentially provides a climate and environmental record spanning at least the last ca 130 ka. Results from a low resolution pilot study reveal characteristic fluctuations that can be related to global climate variability as reflected in marine isotope stages and document the potential of this site for continuous and high-resolution investigations of the Middle to Late Pleistocene. Here we document the tentative lithology drilled, and show how the elemental composition can be interpreted with regard to lake level fluctuations, related redox conditions, but also to grain-size distribution and changes in lacustrine productivity. Finally, based on major lithological changes, a preliminary depth/age model is suggested that allows reassessing published luminescence ages from the same site.

Description: Four seismic surveys and a stratigraphic record from southernmost Patagonia (Argentina) based on 51 AMS-14C dates obtained in the framework of ICDP expedition 5022 "Potrok Aike Maar Lake Sediment Archive Drilling Project" (PASADO) provide a database to compare the 106 m composite profile from the lake centre with piston cores from the littoral and outcrops in the catchment area. Based on event correlation using distinct volcanic ash layers with unique geochemical composition and optically stimulated luminescence (OSL) dates on feldspars, sediment records are firmly linked. This approach allows to match the sediment record with water levels during the past ca. 49 ka providing evidence for lake level variations. Reconstructed lake levels were 20 m higher than today during the last Glacial until the early Holocene. With the migration of the Southern Hemispheric Westerlies over this site the lake level dropped ca. 55 m for a period of two millennia. Thereupon the water balance was more positive again causing a stepwise rise of the lake level until the maximum was reached during the Little Ice Age with a subsequent lowering since the 20th century. We suggest that the mid- to late-Holocene lake level variation is caused by intensity changes of the Southern Hemispheric Westerlies.

Description: The sedimentary archive from Laguna Potrok Aike is the only continuous record reaching back to the last Glacial period in continental southeastern Patagonia. Located in the path of the Southern Hemisphere westerly winds and in the source region of dust deposited in Antarctica during Glacial periods, southern Patagonia is a vantage point to reconstruct past changes in aeolian activity. Here we use high-resolution rock-magnetic and physical grain size data from site 2 of the International Continental scientific Drilling Program (ICDP) Potrok Aike maar lake Sediment Archive Drilling prOject (PASADO) in order to develop magnetic proxies of dust and wind intensity at 52°S since 51,200 cal BP. Rock-magnetic analysis indicate the magnetic mineral assemblage is dominated by detrital magnetite. Based on the estimated flux of magnetite to the lake and comparison with distal dust records from the Southern Ocean and Antarctica, kLF is interpreted as a dust indicator in the dust source of southern Patagonia at the millennial time scale, when ferrimagnetic grain size and coercivity influence is minimal. Comparison to physical grain-size data indicates that the median destructive field of isothermal remanent magnetisation (MDFIRM) mostly reflects medium to coarse magnetite bearing silts typically transported by winds for short-term suspension. Comparison with wind-intensity proxies from the Southern Hemisphere during the last Glacial period and with regional records from Patagonia since the last deglaciation including marine, lacustrine and peat bog sediments as well as speleothems reveals similar variability with MDFIRM up to the centennial time scale. MDFIRM is interpreted as a wind-intensity proxy independent of moisture changes for southeastern Patagonia, with stronger winds capable of transporting coarser magnetite bearing silts to the lake.

Description: The Schwalbenberg II loess-paleosol sequence (LPS) denotes a key site for Marine Isotope Stage (MIS 3) in Western Europe owing to eight succeeding cambisols, which primarily constitute the Ahrgau Subformation. Therefore, this LPS qualifies as a test candidate for the potential of temporal high-resolution geochemical data obtained X-ray fluorescence (XRF) scanning of discrete samplesproviding a fast and non-destructive tool for determining the element composition. The geochemical data is first contextualized to existing proxy data such as magnetic susceptibility (MS) and organic carbon (Corg) and then aggregated to element log ratios characteristic for weathering intensity [LOG (Ca/Sr), LOG (Rb/Sr), LOG (Ba/Sr), LOG (Rb/K)] and dust provenance [LOG (Ti/Zr), LOG (Ti/Al), LOG (Si/Al)]. Generally, an interpretation of rock magnetic particles is challenged in western Europe, where not only magnetic enhancement but also depletion plays a role. Our data indicates leaching and top-soil erosion induced MS depletion at the Schwalbenberg II LPS. Besides weathering, LOG (Ca/Sr) is susceptible for secondary calcification. Thus, also LOG (Rb/Sr) and LOG (Ba/Sr) are shown to be influenced by calcification dynamics. Consequently, LOG (Rb/K) seems to be the most suitable weathering index identifying the Sinzig Soils S1 and S2 as the most pronounced paleosols for this site. Sinzig Soil S3 is enclosed by gelic gleysols and in contrast to S1 and S2 only initially weathered pointing to colder climate conditions. Also the Remagen Soils are characterized by subtle to moderate positive excursions in the weathering indices. Comparing the Schwalbenberg II LPS with the nearby Eifel Lake Sediment Archive (ELSA) and other more distant German, Austrian and Czech LPS while discussing time and climate as limiting factors for pedogenesis, we suggest that the lithologically determined paleosols are in-situ soil formations. The provenance indices document a Zr-enrichment at the transition from the Ahrgau to the Hesbaye Subformation. This is explained by a conceptual model incorporating multiple sediment recycling and sorting effects in eolian and fluvial domains.

Description: The volcanogenic lake Laguna Potrok Aike, Santa Cruz, Argentina, reveals an unprecedented continuous high resolution climatic record for the steppe regions of southern Patagonia. With the applied multi-proxy approach rapid climatic changes before the turn of the first millennium were detected followed by medieval droughts which are intersected by moist and/or cold periods of varying durations and intensities. The 'total inorganic carbon' content was identified as a sensitive lake level indicator. This proxy suggests that during the late Middle Ages (ca. AD 1230-1410) the lake level was rather low representing a signal of the 'Medieval Climate Anomaly' in southeastern Patagonia. At the beginning of the 'Little Ice Age' the lake level rose considerably staying on a high level during the whole period. Subsequently, the lake level lowered again in the course of the 20th century.

Description: This study provides a detailed geochemical record of one of the most detailed loess-paleosol sequence (LPS) in Hungary covering Marine Isotope Stage (MIS) 6 to MIS 2. Süttő is situated in the northwestern Carpathian Basin at the transition between oceanic and continental climate. We investigated weathering intensity, dust provenance and sedimentation dynamics by high-resolution X-ray fluorescence (XRF) scanning of discrete samples in comparison with quantitative XRF and other published proxy data such as grain-size, magnetic susceptibility and micromorphology. Multivariate statistics unravel pedogenesis in terms of decalcification and grain-size dynamics as processes controlling the elemental composition. Furthermore, high-resolution chemostratigraphy indicates geochemical homogeneity for mature MIS 5 paleosols and the modern soil. Together with the A-CN-K plot providing no hint for K-feldspar weathering, semi-arid continental paleoenvironmental conditions are considered as prevailing. Dust provenance is studied by geochemical reference literature data from potential ultimate dust source areas, Th/metal ratios and comparison with the composition of the upper continental crust (UCC). Results indicate a felsic rock composition and a stable dust source, albeit immediate (adjacent Danube floodplains) and ultimate dust sources (surrounding mountain belts) need to be distinguished. According to the Sr-K-Rb plot, the Austroalpine cover nappes area northwest of Süttő might be the dominant ultimate dust source. The weathering-resistant elements Al, Ti and Zr as well as Zr/metal ratios indicate Zr addition and thus strongest sediment sorting and/ or recycling during MIS 6. Since Al, Ti and Zr show minimal correlations with grain-size, we suggest a cascade-alike transport pathway from ultimate source to sink involving multiple sediment recycling and sorting cycles in both fluvial and eolian domains. Therefore, this study highlights how high-resolution qualitative geochemical data contributes to a better understanding of paleoenvironmental and sedimentation dynamics at LPS. Application of such a versatile geochemical screening tool is of broad interest to the scientific community working on (terrestrial) paleoenvironmental archives that are commonly discretely sampled.