Description: Carbonate deposition at two core sites in the subarctic Pacific (48°N, 133°W; 2.9 km and 3.7 km water depth) follows the standard Pacific carbonate cycles, with glacial values being increased over interglacial values. Benthicδ13C follows the global trend; that is, glacial values are more negative than interglacial values. Comparison with the benthicδ13C record of North Atlantic DSDP Site 552 (56°N, 23°W; 2.3 km water depth) shows the North Pacific records to be nearly in phase with and continuously more negative relative to the North Atlantic record. This suggests that concentrations of∑CO2(org) were permanently higher in the North Pacific than in the North Atlantic during the past 750,000 years conceivably supporting the hypothesis that there was no deep-water forming in the late Pleistocene North Pacific. Whereas one would expect that the North Pacific deep waters were continuously more corrosive to carbonates than deep waters in the North Atlantic, carbonate deposition at the deep North Pacific core sites is enhanced during glacial periods, and occasionally higher than at shallow North Atlantic Site 552 even though Site 552 was probably above lysocline-depth during most of the late Pleistocene. This apparent paradox can be resolved only by invoking an increase in alkalinity in the glacial North Pacific which would have increased the degree of carbonate ion saturation and thereby improved the state of carbonate preservation.

Description: Benthic (Uvigerina spp., Cibicidoides spp., Gyroidinoides spp.) and planktonic (N. pachyderma sinistral, G. bulloides) stable isotope records from three core sites in the central Gulf of Alaska are used to infer mixed-layer and deepwater properties of the late glacial Subarctic Pacific. Glacial-interglacial amplitudes of the planktonic δ18O records are 1.1–1.3‰, less than half the amplitude observed at core sites at similar latitudes in the North Atlantic; these data imply that a strong, negative δw anomaly existed in the glacial Subarctic mixed layer during the summer, which points to a much stronger low-salinity anomaly than exists today. If true, the upper water column in the North Pacific would have been statically more stable than today, thus suppressing convection even more efficiently. This scenario is further supported by vertical (i.e., planktic versus benthic) δ18O and δ13C gradients of 〉1‰, which suggest that a thermohaline link between Pacific deep waters and the Subarctic Pacific mixed layer did not exist during the late glacial. Epibenthic δ13C in the Subarctic Pacific is more negative than at tropical-subtropical Pacific sites but similar to that recorded at Southern Ocean sites, suggesting ventilation of the deep central Pacific from mid-latitude sources, e.g., from the Sea of Japan and Sea of Okhotsk. Still, convection to intermediate depths could have occurred in the Subarctic during the winter months when heat loss to the atmosphere, sea ice formation, and wind-driven upwelling of saline deep waters would have been most intense. This would be beyond the grasp of our planktonic records which only document mixed-layer temperature-salinity fields extant during the warmer seasons. Also we do not have benthic isotope records from true intermediate water depths of the Subarctic Pacific.

Description: Stable isotopes in benthic foraminifera from Pacific sediments are used to assess hypotheses of systematic shifts in the depth distribution of oceanic nutrients and carbon during the ice ages. The carbon isotope differences between ~1400 and ~3200 m depth in the eastern Pacific are consistently greater in glacial than interglacial maxima over the last ~370 kyr. This phenomenon of "bottom heavy" glacial nutrient distributions, which Boyle proposed as a cause of Pleistocene CO2 change, occurs primarily in the 1/100 and 1/41 kyr**-1 "Milankovitch" orbital frequency bands but appears to lack a coherent 1/23 kyr**-1 band related to orbital precession. Averaged over oxygen-isotope stages, glacial delta13C gradients from ~1400 to ~3200 m depth are 0.1 per mil greater than interglacial gradients. The range of extreme shifts is somewhat larger, 0.2 to 0.5 per mil . In both cases, these changes in Pacific delta13C distributions are much smaller than observed in shorter records from the North Atlantic. This may be too small to be a dominant cause of atmospheric pCO2 change, unless current models underestimate the sensitivity of pCO2 to nutrient redistributions. This dampening of Pacific relative to Atlantic delta13C depth gradient favors a North Atlantic origin of the phenomenon, although local variations of Pacific intermediate water masses can not be excluded at present.

Description: Benthic (Uvigerina spp., Cibicidoides spp., Gyroidinoides spp.) and planktonic (N. pachyderma sinistral, G. bulloides) stable isotope records from three core sites in the central Gulf of Alaska are used to infer mixed-layer and deepwater properties of the late glacial Subarctic Pacific. Glacial-interglacial amplitudes of the planktonic delta18O records are 1.1-1.3 per mil, less than half the amplitude observed at core sites at similar latitudes in the North Atlantic; these data imply that a strong, negative deltaw anomaly existed in the glacial Subarctic mixed layer during the summer, which points to a much stronger low-salinity anomaly than exists today. If true, the upper water column in the North Pacific would have been statically more stable than today, thus suppressing convection even more efficiently. This scenario is further supported by vertical (i.e., planktic versus benthic) delta18O and delta13C gradients of 〉1 per mil, which suggest that a thermohaline link between Pacific deep waters and the Subarctic Pacific mixed layer did not exist during the late glacial. Epibenthic delta13C in the Subarctic Pacific is more negative than at tropical-subtropical Pacific sites but similar to that recorded at Southern Ocean sites, suggesting ventilation of the deep central Pacific from mid-latitude sources, e.g., from the Sea of Japan and Sea of Okhotsk. Still, convection to intermediate depths could have occurred in the Subarctic during the winter months when heat loss to the atmosphere, sea ice formation, and wind-driven upwelling of saline deep waters would have been most intense. This would be beyond the grasp of our planktonic records which only document mixed-layer temperature-salinity fields extant during the warmer seasons. Also we do not have benthic isotope records from true intermediate water depths of the Subarctic Pacific.