Digitale Medien
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
86 (1987), S. 4401-4405
ISSN:
1089-7690
Quelle:
AIP Digital Archive
Thema:
Physik
,
Chemie und Pharmazie
Notizen:
The emission spectra of 31 bands of HCl+(A 2Σ+→X 2Π) have been obtained using hollow cathode discharges. Relative intensities were determined by comparison with computer generated spectra. Treatment of the data within the r-centroid (r¯v′v″) approximation shows that the electronic transition moment decreases strongly for large internuclear distances (r centroid). The transition moment can be fitted by the expression R2e =0.543r¯ 3.29v′v″ ×exp(−2.69r¯ 2v′v″) in atomic units for 1.1〈r¯v′v″ 〈1.8 A(ring).
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1063/1.452710
Permalink
|
Standort |
Signatur |
Einschränkungen |
Verfügbarkeit |