In:
New Journal of Chemistry, Royal Society of Chemistry (RSC), Vol. 47, No. 18 ( 2023), p. 8951-8959
Kurzfassung:
In this work, cobalt complexes 1 and 2 were synthesized from ligands L 1 (1,2-bis(2-phenyl-2-(pyridin-2-yl)hydrazineylidene)ethane) and L 2 (1,2-bis(2-(pyridin-2-yl)hydrazineylidene)ethane) in moderate yields. These complexes were characterized by UV-visible, IR and ESI-MS spectroscopic studies. The molecular structure of complex 1 was determined by X-ray crystallography. Complexes 1 and 2 were employed as catalysts for the oxidation of sp 3 C–H bonds. A total of 12 substrates were investigated for the oxidation of benzylic and aliphatic sp 3 C–H bonds. A reaction pathway was proposed and possible reactive intermediate species was successfully characterized by ESI-MS spectroscopic studies.
Materialart:
Online-Ressource
ISSN:
1144-0546
,
1369-9261
Sprache:
Englisch
Verlag:
Royal Society of Chemistry (RSC)
Publikationsdatum:
2023
ZDB Id:
1472933-7
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