GLORIA

GEOMAR Library Ocean Research Information Access

X

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
Material
Publisher
Person/Organisation
Language
Years
FID
Subjects(RVK)
  • 1
    Online Resource
    Online Resource
    Microwave and low-frequency vibrational spectra of bullvalene
    Elsevier BV ; 1976
    In:  Journal of Molecular Spectroscopy Vol. 60, No. 1-3 ( 1976-3), p. 188-196
    Details
    In: Journal of Molecular Spectroscopy, Elsevier BV, Vol. 60, No. 1-3 ( 1976-3), p. 188-196
    Type of Medium: Online Resource
    ISSN: 0022-2852
    URL: Article
    DOI: 10.1016/0022-2852(76)90125-9
    Language: English
    Publisher: Elsevier BV
    Publication Date: 1976
    detail.hit.zdb_id: 1469771-3
    SSG: 11
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 2
    Online Resource
    Online Resource
    Microwave spectrum of F2CO: Excited vibrational states and Coriolis coupling
    Elsevier BV ; 1963
    In:  Journal of Molecular Spectroscopy Vol. 10, No. 1-6 ( 1963-1), p. 155-160
    Details
    In: Journal of Molecular Spectroscopy, Elsevier BV, Vol. 10, No. 1-6 ( 1963-1), p. 155-160
    Type of Medium: Online Resource
    ISSN: 0022-2852
    URL: Article
    DOI: 10.1016/0022-2852(63)90165-6
    Language: English
    Publisher: Elsevier BV
    Publication Date: 1963
    detail.hit.zdb_id: 1469771-3
    SSG: 11
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 3
    Online Resource
    Online Resource
    Microwave Spectrum, Ring-Puckering Potential Function, and Dipole Moment of Methylenecyclobutane
    AIP Publishing ; 1968
    In:  The Journal of Chemical Physics Vol. 49, No. 7 ( 1968-10-01), p. 3041-3049
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 49, No. 7 ( 1968-10-01), p. 3041-3049
    Abstract: The microwave spectra of methylenecyclobutane in the ground state and in the first six excited states of the ring-puckering vibration have been assigned. The υ = 0 state and υ = 1 state are very close in energy and are strongly coupled giving rise to nonrigid-rotor spectra. Analysis shows the energy difference to be 33 592 MHz. This energy difference together with the vibrational dependence of the rotational constants gives the ring-puckering potential function to be 7.65(X4 − 9.15X2) cm−1 where X is a reduced ring-puckering coordinate. This potential function contains a barrier to ring inversion of 160 ± 40 cm−1. The a component of the dipole moment is found to be 0.514 D in the ground state and to have the ring-puckering vibrational dependence μa = 0.496 + 0.0051 〈X2〉υυ (debye).
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.1670547
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1968
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 4
    Online Resource
    Online Resource
    Comments on the Structure of 1,1,1-Trifluoro-2-butyne
    AIP Publishing ; 1959
    In:  The Journal of Chemical Physics Vol. 30, No. 4 ( 1959-04-01), p. 1101-1102
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 30, No. 4 ( 1959-04-01), p. 1101-1102
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.1730094
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1959
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 5
    Online Resource
    Online Resource
    Anharmonic Potential Constants and Their Dependence upon Bond Length
    AIP Publishing ; 1961
    In:  The Journal of Chemical Physics Vol. 35, No. 2 ( 1961-08-01), p. 458-464
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 35, No. 2 ( 1961-08-01), p. 458-464
    Abstract: Empirical study of cubic and quartic vibrational force constants for diatomic molecules shows them to be approximately exponential functions of internuclear distance. A family of curves is obtained, determined by the location of the bonded atoms in rows of the periodic table. Displacements between successive curves correspond closely to those in Badger's rule for quadratic force constants (for which the parameters are redetermined to accord with all data now available). Constants for excited electronic and ionic states appear on practically the same curves as those for the ground states. Predictions based on the diatomic correlations agree with the available cubic constants for bond stretching in polyatomic molecules, regardless of the type of bonding involved. Some implications of these regularities are discussed.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.1731952
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1961
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 6
    Online Resource
    Online Resource
    Microwave Spectrum and Dipole Moment of Cyclopentadiene
    AIP Publishing ; 1956
    In:  The Journal of Chemical Physics Vol. 24, No. 3 ( 1956-03-01), p. 635-636
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 24, No. 3 ( 1956-03-01), p. 635-636
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.1742585
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1956
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 7
    Online Resource
    Online Resource
    Influence of Vibrations on Molecular Structure Determinations. I. General Formulation of Vibration—Rotation Interactions
    AIP Publishing ; 1962
    In:  The Journal of Chemical Physics Vol. 37, No. 8 ( 1962-10-15), p. 1668-1686
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 37, No. 8 ( 1962-10-15), p. 1668-1686
    Abstract: The structure of a polyatomic molecule derived from observed spectroscopic moments of inertia differs appreciably from both the equilibrium structure and the zero-point average structure. A perturbation expansion of the moments of inertia is derived here in a form which allows the vibrational displacements to be referred to any fixed configuration of the atoms as origin. A method for evaluating the expansion coefficients is given which proceeds ``atom by atom.'' Linear WXYZ, branched WXYZ, and symmetric WXY3 molecules are treated in detail. Empirical data show that the anharmonicity of the vibrations gives rise to the most important of the corrections required to obtain the equilibrium structure. Except for a few molecules, the anharmonicity is not accurately known. It is shown, however, that to a practical approximation the anharmonic contributions are completely absorbed in displacing the average configuration from the equilibrium one. Therefore the moments of inertia for the zero-point average configuration of a molecule can be derived from the observed effective moments by applying corrections which depend only upon the harmonic part of the vibrational potential.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.1733357
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1962
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 8
    Online Resource
    Online Resource
    Microwave Spectrum and Internal Rotation of 1-Chloro-2-Butyne
    AIP Publishing ; 1959
    In:  The Journal of Chemical Physics Vol. 31, No. 4 ( 1959-10-01), p. 939-943
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 31, No. 4 ( 1959-10-01), p. 939-943
    Abstract: The microwave spectrum of CH3C≡CCH2Cl has been investigated in the region from 20–30 kMc. The existence of nearly free internal rotation gives rise to regions of very dense absorption. Transitions of the type ΔJ = 1, ΔK = 0 have been identified for the ground torsional state (m = 0). The ground state spectrum is that of an effective rigid rotor with the rotational constants modified by the internal rotation. Values for the effective rotational constants are 17 631, 1490.55, 1385.06 Mc for the Cl35 species; and 17 329, 1459.76, 1357.26 Mc for the Cl37 species. These rotational constants permit an upper bound of 100 cal/mole to be established for the barrier to internal rotation. A structural analysis indicates that the CCl bond is longer than in CH3Cl.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.1730555
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1959
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 9
    Online Resource
    Online Resource
    Microwave Spectrum and Internal Rotation of Ethyl Cyanide
    AIP Publishing ; 1959
    In:  The Journal of Chemical Physics Vol. 31, No. 6 ( 1959-12-01), p. 1500-1505
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 31, No. 6 ( 1959-12-01), p. 1500-1505
    Abstract: The microwave spectrum of ethyl cyanide has been studied in the region from 17–36 kMc. Both parallel and perpendicular transitions have been assigned. Rotational constants (Mc) for the ground vibrational state are a0=27 663.30, b0=4714.14, c0=4235.14, DJ=0.0035, DJK=—0.0496. From Stark effects the dipole moment is calculated to be μa=3.78 D, μb=1.38 D, μ=4.02 D. Hyperfine splittings lead to a value of —3.3 Mc for the quadrupole coupling of the N14 nucleus along the a axis. Rotational transitions of molecules in several excited vibrational states have also been measured. A Coriolis interaction between the torsional mode and the in-plane CCN bend has been found and is discussed. Splittings of transitions of molecules in the first excited torsional state show that the barrier hindering internal rotation of the methyl group is 3.05 kcal/mole.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.1730643
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1959
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
  • 10
    Online Resource
    Online Resource
    Microwave spectrum, structure, and dipole moment of 1,1-difluorocyclopropane
    AIP Publishing ; 1975
    In:  The Journal of Chemical Physics Vol. 62, No. 6 ( 1975-03-15), p. 2469-2473
    Details
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 62, No. 6 ( 1975-03-15), p. 2469-2473
    Abstract: The microwave spectra of five isotopic species of 1,1−diffluorocyclopropane have been studied in the region 18−40 GHz. Structural parameters were obtained: r (C1C2) = 1.464±0.002 Å, r (C2C2′) = 1.553±0.001 Å, r (CF) = 1.355±0.002 Å, r (CH) = 1.082±0.002 Å, & FCF = 108.4±0.2°, & C2C1C2′ = 64.1±0.1°, & HCH = 116.9±0.2°. The dipole moment has been determined to be 2.32±0.02 D. Rotational transitions belonging to a vibrational state of A symmetry at about 327 cm−1 and to a vibrational state of B symmetry at about 351 cm−1 have also been observed.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    URL: Article
    DOI: 10.1063/1.430725
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1975
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
    Online Resource
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...