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  • 1
    Online-Ressource
    Online-Ressource
    American Geophysical Union (AGU) ; 2000
    In:  Geophysical Research Letters Vol. 27, No. 14 ( 2000-07-15), p. 2117-2120
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 27, No. 14 ( 2000-07-15), p. 2117-2120
    Materialart: Online-Ressource
    ISSN: 0094-8276
    Sprache: Englisch
    Verlag: American Geophysical Union (AGU)
    Publikationsdatum: 2000
    ZDB Id: 2021599-X
    ZDB Id: 7403-2
    SSG: 16,13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    In: Global Biogeochemical Cycles, American Geophysical Union (AGU), Vol. 14, No. 1 ( 2000-03), p. 373-387
    Kurzfassung: Measurements of air‐sea gas exchange rates are reported from two deliberate tracer experiments in the southern North Sea during February 1992 and 1993. A conservative tracer, spores of the bacterium Bacillus globigii var. Niger , was used for the first time in an in situ air‐sea gas exchange experiment. This nonvolatile tracer is used to correct for dispersive dilution of the volatile tracers and allows three estimations of the transfer velocity for the same time period. The first estimation of the power dependence of gas transfer on molecular diffusivity in the marine environment is reported. This allows the impact of bubbles on estimates of the transfer velocity derived from changes in the helium/sulphur hexafluoride ratio to be assessed. Data from earlier dual tracer experiments are reinterpreted, and findings suggest that results from all dual tracer experiments are mutually consistent. The complete data set is used to test published parameterizations of gas transfer with wind speed. A gas ex‐ change relationship that shows a dependence on wind speed intermediate between those of Liss and Merlivat [1986] and Wanninkhof [1992] is found to be optimal. The dual tracer data are shown to be reasonably consistent with global estimates of gas exchange based on the uptake of natural and bomb‐derived radiocarbon. The degree of scatter in the data when plotted against wind speed suggests that parameters not scaling with wind speed are also influencing gas exchange rates.
    Materialart: Online-Ressource
    ISSN: 0886-6236 , 1944-9224
    Sprache: Englisch
    Verlag: American Geophysical Union (AGU)
    Publikationsdatum: 2000
    ZDB Id: 2021601-4
    SSG: 12
    SSG: 13
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  • 3
    Online-Ressource
    Online-Ressource
    Elsevier BV ; 2002
    In:  Atmospheric Environment Vol. 36, No. 32 ( 2002-10), p. 5119-5120
    In: Atmospheric Environment, Elsevier BV, Vol. 36, No. 32 ( 2002-10), p. 5119-5120
    Materialart: Online-Ressource
    ISSN: 1352-2310
    Sprache: Englisch
    Verlag: Elsevier BV
    Publikationsdatum: 2002
    ZDB Id: 216368-8
    ZDB Id: 1499889-0
    SSG: 14
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Online-Ressource
    Online-Ressource
    Elsevier BV ; 2001
    In:  Earth and Planetary Science Letters Vol. 189, No. 3-4 ( 2001-07), p. 277-283
    In: Earth and Planetary Science Letters, Elsevier BV, Vol. 189, No. 3-4 ( 2001-07), p. 277-283
    Materialart: Online-Ressource
    ISSN: 0012-821X
    RVK:
    Sprache: Englisch
    Verlag: Elsevier BV
    Publikationsdatum: 2001
    ZDB Id: 300203-2
    ZDB Id: 1466659-5
    SSG: 16,13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    Online-Ressource
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    American Association for the Advancement of Science (AAAS) ; 2002
    In:  Science Vol. 297, No. 5584 ( 2002-08-16), p. 1151-1154
    In: Science, American Association for the Advancement of Science (AAAS), Vol. 297, No. 5584 ( 2002-08-16), p. 1151-1154
    Kurzfassung: Alkyl nitrates are a significant component of the “odd nitrogen” reservoir and play an important role in regulating tropospheric ozone levels in remote marine regions. Measurements of methyl and ethyl nitrate in seawater and air samples along two Atlantic Ocean transects provide the first direct evidence for an oceanic source of these compounds. Equatorial surface waters were highly supersaturated (up to 800%) in both species, with the waters in the temperate regions generally being closer to equilibrium. A simple box model calculation suggests that the equatorial source could be a major component of the local atmospheric alkyl nitrate budget.
    Materialart: Online-Ressource
    ISSN: 0036-8075 , 1095-9203
    RVK:
    RVK:
    Sprache: Englisch
    Verlag: American Association for the Advancement of Science (AAAS)
    Publikationsdatum: 2002
    ZDB Id: 128410-1
    ZDB Id: 2066996-3
    ZDB Id: 2060783-0
    SSG: 11
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    Online-Ressource
    Online-Ressource
    Cambridge University Press (CUP) ; 2004
    In:  Antarctic Science Vol. 16, No. 4 ( 2004-12), p. 517-529
    In: Antarctic Science, Cambridge University Press (CUP), Vol. 16, No. 4 ( 2004-12), p. 517-529
    Kurzfassung: The flux of gases between the atmosphere and the oceans can be calculated from the product of the concentration difference across the sea surface and a kinetic term, often called a transfer velocity. The transfer velocity is frequently parameterized in terms of wind speed, although the actual exchange process is also affected by waves, bubbles, wind fetch, and less certainly by surfactants and chemical reactivity. There is currently an uncertainty of about a factor of two in using the wind speed parameterization. In view of the windiness of the Southern Ocean, transfer velocities will often be high, although there are few published in situ measurements of transfer rates made in the region. Data for gas concentration fields in the Southern Ocean are generally sparse compared to other better studied oceanic areas. In this paper we discuss what is known for the region for carbon dioxide, including the oceanic sink for man-made inputs to the atmosphere; dimethyl sulphide, where there appears to be a substantial source, which has the potential for a significant climatic effect due to the low particulate loading in the region; and organo-halogen and alkyl nitrate gases, where marine emissions may play an important role in controlling the oxidation capacity of the Antarctic atmosphere.
    Materialart: Online-Ressource
    ISSN: 0954-1020 , 1365-2079
    Sprache: Englisch
    Verlag: Cambridge University Press (CUP)
    Publikationsdatum: 2004
    ZDB Id: 2104104-0
    ZDB Id: 1009128-2
    SSG: 12
    SSG: 13
    SSG: 14
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    Online-Ressource
    Online-Ressource
    Wiley ; 2002
    In:  Journal of Phycology Vol. 38, No. 4 ( 2002-08), p. 630-638
    In: Journal of Phycology, Wiley, Vol. 38, No. 4 ( 2002-08), p. 630-638
    Kurzfassung: When attacked by herbivores, land plants can produce a variety of volatile compounds that attract carnivorous mutualists. Plants and carnivores can benefit from this symbiotic relationship, because the induced defensive interaction increases foraging success of the carnivores, while reducing the grazing pressure exerted by the herbivores on the plants. Here, we examine whether aquatic phytoplankton use volatile chemical cues in analogous tritrophic interactions. Marine algae produce several classes of biogenic gases such as non‐methane hydrocarbons, organohalogens, ammonia and methylamines, and dimethylsulfide. The grazing‐induced release of marine biogenic volatiles is poorly understood, however, and its effect on the chemical ecology of plankton and the foraging behavior of predators is essentially unknown. We outline grazing‐induced defenses in algae and highlight the biogenic production of volatiles when phytoplankton are attacked by herbivores. The role of chemical signaling in marine ecology presents several possible avenues for future research, and we believe that progress in this area will result in better understanding of species competition, bloom development, and the structuring of food webs in the sea. This has further implications for biogeochemical cycles, because several key compounds are emitted that influence the chemistry of the atmosphere and global climate.
    Materialart: Online-Ressource
    ISSN: 0022-3646 , 1529-8817
    RVK:
    Sprache: Englisch
    Verlag: Wiley
    Publikationsdatum: 2002
    ZDB Id: 281226-5
    ZDB Id: 1478748-9
    SSG: 12
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 8
    Online-Ressource
    Online-Ressource
    World Scientific Pub Co Pte Ltd ; 2000
    In:  International Journal of Modern Physics B Vol. 14, No. 29n31 ( 2000-12-20), p. 3753-3758
    In: International Journal of Modern Physics B, World Scientific Pub Co Pte Ltd, Vol. 14, No. 29n31 ( 2000-12-20), p. 3753-3758
    Kurzfassung: High-resolution, high-energy, X-ray diffraction results are presented for the study of weak charge ordering phenomenon. By utilizing X-rays in the 100 keV region the dramatic increase in the penetration depth allows for both bulk-sensitive and high-resolution measurements to be made. The strontium doped La 2 NiO 4 system is a prototypical system in the understanding of strong electron-phonon coupling, and the resultant effects on material properties. At doping levels of 1/3 and 1/2 commensurate charge modulations are observed indicating real-space charge stripes. We have measured the correlation lengths of these charge stripes using both 100 keV X-rays and 8.3 keV X-rays. In comparing our results we have observed that the charge stripes appear to be well correlated in the near-surface region with correlation lengths ξ≈2400Å. However, our bulk sensitive measurements show that the charge stripes appear in a possible stripe glass phase with a correlation length of only ξ≈300Å. Our measurements on the 3D charge order manganite system Nd 0.5 Sr 0.5 MnO 3 show that the charge ordering appears to be well correlated in the bulk of the sample in contrast to our nickelate results.
    Materialart: Online-Ressource
    ISSN: 0217-9792 , 1793-6578
    RVK:
    Sprache: Englisch
    Verlag: World Scientific Pub Co Pte Ltd
    Publikationsdatum: 2000
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