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  • Articles  (3)
  • 1
    Publication Date: 2016-06-07
    Description: Large quantities of methane are stored in hydrates and permafrost within shallow marine sediments in the Arctic Ocean. These reservoirs are highly sensitive to climate warming, but the fate of methane released from sediments is uncertain. Here, we review the principal physical and biogeochemical processes that regulate methane fluxes across the seabed, the fate of this methane in the water column, and potential for its release to the atmosphere. We find that, at present, fluxes of dissolved methane are significantly moderated by anaerobic and aerobic oxidation of methane. If methane fluxes increase then a greater proportion of methane will be transported by advection or in the gas phase, which reduces the efficiency of the methanotrophic sink. Higher freshwater discharge to Arctic shelf seas may increase stratification and inhibit transfer of methane gas to surface waters, although there is some evidence that increased stratification may lead to warming of sub-pycnocline waters, increasing the potential for hydrate dissociation. Loss of sea-ice is likely to increase wind speeds and sea-air exchange of methane will consequently increase. Studies of the distribution and cycling of methane beneath and within sea ice are limited, but it seems likely that the sea-air methane flux is higher during melting in seasonally ice-covered regions. Our review reveals that increased observations around especially the anaerobic and aerobic oxidation of methane, bubble transport, and the effects of ice cover, are required to fully understand the linkages and feedback pathways between climate warming and release of methane from marine sediments.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-25
    Description: © The Author(s), 2015. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 8364–8380, doi:10.1002/2015JC011062.
    Description: When wind speeds are 2–10 m s−1, reflective contrasts in the ocean surface make oil slicks visible to synthetic aperture radar (SAR) under all sky conditions. Neural network analysis of satellite SAR images quantified the magnitude and distribution of surface oil in the Gulf of Mexico from persistent, natural seeps and from the Deepwater Horizon (DWH) discharge. This analysis identified 914 natural oil seep zones across the entire Gulf of Mexico in pre-2010 data. Their ∼0.1 µm slicks covered an aggregated average of 775 km2. Assuming an average volume of 77.5 m3 over an 8–24 h lifespan per oil slick, the floating oil indicates a surface flux of 2.5–9.4 × 104 m3 yr−1. Oil from natural slicks was regionally concentrated: 68%, 25%, 7%, and 〈1% of the total was observed in the NW, SW, NE, and SE Gulf, respectively. This reflects differences in basin history and hydrocarbon generation. SAR images from 2010 showed that the 87 day DWH discharge produced a surface-oil footprint fundamentally different from background seepage, with an average ocean area of 11,200 km2 (SD 5028) and a volume of 22,600 m3 (SD 5411). Peak magnitudes of oil were detected during equivalent, ∼14 day intervals around 23 May and 18 June, when wind speeds remained 〈5 m s−1. Over this interval, aggregated volume of floating oil decreased by 21%; area covered increased by 49% (p 〈 0.1), potentially altering its ecological impact. The most likely causes were increased applications of dispersant and surface burning operations.
    Description: DoE Grant Number: DE-NT0005638; National Science Foundation Grant Number: EF-0801741; Bureau of Ocean Energy Management Grant Number: M12PC00003
    Keywords: Remote sensing ; SAR ; Oil pollution ; Deepwater Horizon ; Natural seeps
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2011-12-01
    Description: A newly modified acoustic method was used to derive time-dependent bubble emission size distributions and to monitor associated zooplankton behavior at a methane seep emitted from the northeast Pacific continental shelf in 150 m water depth near Grays Harbor, Washington State, USA. Instrumentation consisted of a seafloor mooring with an upward-oriented 200 kHz sonar that imaged the column's lower 100 m for 33 h during September 2009. The profiler observed several highly variable methane bubble streams venting from a large carbonate-lined pockmark. Other acoustic data and visual observations confirmed that the gas bubbles reached the sea surface and were highly variable in nature. Individual bubble traces in the acoustic sonar images were used to derive vertical bubble velocities with a mean value of 24.6 ± 2.5 cm s-1 over the entire depth range. Some bubbles entering the acoustic image at shallower water depths exhibited a slower rise velocity of 22.2 ± 2.4 cm s-1 and likely originated from adjacent emission sites. Measured rise velocities were too slow to be clean, uncoated bubbles. We therefore assumed that the bubbles were surfactant coated with a Gaussian-shaped size distribution peaking at an observed radius of 7500 ± 100 µm. If the flux derived from these measurements was assumed to be relatively constant over time, total methane issuing from only one of the ~20 active bubble vents at the pockmark site is estimated as ~9 kg yr-1, similar to the flux from other reported marine CH4 vent sites.
    Electronic ISSN: 1553-040X
    Topics: Geosciences
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