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  • 1
    ISSN: 1573-0417
    Keywords: diatoms ; temperature ; sediment traps ; seasonal succession ; resuspension ; Lake Holzmaar
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The seasonal sedimentation pattern of diatom valves in Lake Holzmaar was investigated during 1995 by deploying sediment traps at three different lake depths. According to the sedimentation pattern, the major reproduction zone of diatoms was restricted to the upper 6 m of the water body. The population growth started late in April and blooms of Cyclotella cf. comensis Grun., which dominates the plankton diatoms, and Fragilaria crotonensis Kitton were collected in traps during June and September, and July, respectively. During summer, the seasonal sedimentation pattern of each taxon, as collected in the upper traps, was reflected in the concentrations in the lowest trap. However, in May and from September onwards, the community composition in the lowest trap and augmented trapping rates suggest both sediment focusing and resuspension of bottom sediments. The temperature signals as recorded by δ18O values of diatom valves should, therefore, reflect integrated temperatures between 0 and 6 m depth. However, temperatures during summer and autumn are expected to be accentuated in the sedimentary record since the isotopic signal is weighted by both the number and the weight-mass of the valves. During summer, the transfer of these signals by the sedimenting diatoms retains the information pattern recorded, while in spring and autumn/winter additional influxes caused by resuspension may somewhat alter those temperature informations. The proxy signals finally stored in the sediments, may, therefore, not precisely represent the successive temperatures currently recorded during 1995 within mid-lake.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The kinetics of the cationic polymerization of trioxane initiated by perchloric acid is analyzed as a simultaneous polymerization and crystallization process. The details of the crystal growth such as nucleation, distribution of crystal sizes, development of growth spirals etc. have been investigated by electron and light microscopic techniques. The mechanism of polymerization can be understood as a catalyzed crystal growth. A well defined population of crystals is formed during a nucleation event at the start of the polymerization. An adsorption equilibrium with regard to the catalyst is then established in the presence of the rather large surface area of the growing polymer crystals. Assuming a Langmuir-type adsorption behaviour, the observed growth features (growth spirals) can be quantitatively interpreted on the basis of the BCF-theory of crystal growth. The current concepts on the molecular mechanism of cationic polymerization of cyclic formals have been modified such as to take into account that each chemical step of the polymerization is a building step of the crystal too.
    Additional Material: 24 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2016-12-01
    Description: When using biomarkers such as n-alkanes as tools for paleo-environmental reconstructions, it is imperative to determine their specific sources for each setting. Towards that goal, we analysed a set of various potential organic matter (OM) sources such as aquatic and terrestrial plants, dust, and soils from Laguna Potrok Aike (LPA) and surrounding areas in Southern Patagonia. We determined chain length distributions and hydrogen (δD) and carbon (δ13C) isotopic compositions of n-alkanes of different OM sources in order to quantify their relative contributions to lake sediments. Our results reveal that mid-chain n-alkane, n-C23, is predominantly produced by submerged aquatic plants, whereas long-chain n-alkanes (n-C29 to n-C31) are derived from various terrestrial sources. We estimated their relative contributions to the sediment using two approaches, i.e. based on the n-alkane distributions and their δD and δ13C values. Both approaches result in similar estimates of aquatic and terrestrial contributions for mid- and long-chain n-alkanes to the sediment. 62-73% of the mid-chain n-C23 alkanes originate from aquatic sources while 66-77% of the long-chain n-alkanes originate from dust and 14-30% from terrestrial plants. Our study shows that mid-chain n-alkanes such as n-C23 alkane in LPA are derived mainly from aquatic macrophytes and thus have the potential to record changes in lake-water isotopic composition. In contrast, the n-C29 alkane reflects the isotopic signal of various terrestrial sources from Southern Patagonia.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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  • 4
    Publication Date: 2016-11-19
    Description: Laguna Potrok Aike is an exceptional site in the southern hemisphere’s mid-latitudes because it records changes in the hydrological regime through lake-level variations in a continuous, high-resolution sedi- ment record back into the late Pleistocene. In this study, driving forces of lake-level changes at Laguna Potrok Aike are evaluated by means of process studies using data from an extensive multi-year moni- toring in and around the lake. Lake-volume changes were calculated with an energy-budget/bulk- transfer approach and translated into lake-level variations, which were then compared to pressure sensor data. Calculated lake levels are in broad agreement with measured data. We hypothesize that on short time scales, lake-level fluctuations are mainly driven by the precipitation-to-evaporation ratio. Apart from changing catchment conditions, relative humidity, precipitation, temperature, wind strength and wind direction have the most important influence on the hydrological balance of the lake. Lake level decreases during periods of persistently high wind speeds from westerly directions, whereas, during periods with more frequent occurrences of easterly winds, it increases. These situations are linked to a strengthening of the Southern Hemispheric Westerlies in the first and more frequent blocking situa- tions in the latter case. Although lake-level changes at Laguna Potrok Aike show some degree of simi- larity to variations of the El Niño Southern Oscillation (ENSO) and the Southern Hemisphere Annular Mode (SAM), a persistent correspondence remains to be documented. Water chemistry and sediment-trap data suggest that lake-internal carbonate precipitation is highly sensitive to short-term changes in the lake water volume and, thus, to lake-level variations. However, it becomes obvious that the sedimentary carbonate record, representing changes on longer time scales, is not linearly linked to lake-level changes, hence complicating quantitative lake-level reconstructions back in time. We suggest that short-term changes in authigenic carbonate production are mainly driven by changing precipitation/evaporation ratios probably superimposed on longer-term changes in ground- water input that represent a buffered climate signal. Scenario calculations for a period of 60 years show that changes of the controlling meteorological parameters in the range of 15-17% can lead to lake-level changes with a magnitude comparable to the reconstructed Holocene and Lateglacial extreme situations. In addition, modifications in the water- retaining capacity of the lake can also produce large lake-level changes. It is hypothesized that the development or disappearance of permafrost in the catchment of Laguna Potrok Aike during the Last Glacial/Interglacial transition may have changed the water-retaining capacity tremendously. The lake- level reconstructions for Laguna Potrok Aike might express some of the meridional climate variability observed in coupled general circulation model (CGCM) simulations for southern South America for the Last Glacial Maximum (LGM) and the mid Holocene.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 5
    Publication Date: 2024-03-19
    Description: Oxygen isotopes in biogenic silica (δ18OBSi) from lake sediments allow for quantitative reconstruction of past hydroclimate and proxy-model comparison in terrestrial environments. The signals of individual records have been attributed to different factors, such as air temperature (Tair), atmospheric circulation patterns, hydrological changes, and lake evaporation. While every lake has its own local set of drivers of δ18O variability, here we explore the extent to which regional or even global signals emerge from a series of paleoenvironmental records. This study provides a comprehensive compilation and combined statistical evaluation of the existing lake sediment δ18OBSi records, largely missing in other summary publications (i.e. PAGES network). For this purpose, we have identified and compiled 71 down-core records published to date and complemented these datasets with additional lake basin parameters (e.g. lake water residence time and catchment size) to best characterize the signal properties. Records feature widely different temporal coverage and resolution, ranging from decadal-scale records covering the past 150 years to records with multi-millennial-scale resolution spanning glacial-interglacial cycles. The best coverage in number of records (NCombining double low line37) and data points (NCombining double low line2112) is available for Northern Hemispheric (NH) extratropical regions throughout the Holocene (roughly corresponding to Marine Isotope Stage 1; MIS 1). To address the different variabilities and temporal offsets, records were brought to a common temporal resolution by binning and subsequently filtered for hydrologically open lakes with lake water residence times 〈100 years. For mid- to high-latitude (〉45°N) lakes, we find common δ18OBSi patterns among the lake records during both the Holocene and Common Era (CE). These include maxima and minima corresponding to known climate episodes, such as the Holocene Thermal Maximum (HTM), Neoglacial Cooling, Medieval Climate Anomaly (MCA) and the Little Ice Age (LIA). These patterns are in line with long-term air temperature changes supported by previously published climate reconstructions from other archives, as well as Holocene summer insolation changes. In conclusion, oxygen isotope records from NH extratropical lake sediments feature a common climate signal at centennial (for CE) and millennial (for Holocene) timescales despite stemming from different lakes in different geographic locations and hence constitute a valuable proxy for past climate reconstructions.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
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