Publication Date:
2017-07-25
Description:
IJERPH, Vol. 14, Pages 828: Synthesis and Ion-Exchange Properties of Graphene Th(IV) Phosphate Composite Cation Exchanger: Its Applications in the Selective Separation of Lead Metal Ions International Journal of Environmental Research and Public Health doi: 10.3390/ijerph14070828 Authors: Tauseef Rangreez Inamuddin Abdullah Asiri Basma Alhogbi Mu. Naushad In this study, graphene Th(IV) phosphate was prepared by sol–gel precipitation method. The ion-exchange behavior of this cation-exchanger was studied by investigating properties like ion-exchange capacity for various metal ions, the effect of eluent concentration, elution behavior, and thermal effect on ion-exchange capacity (IEC). Several physicochemical properties as Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) study, thermal studies, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) studies were also carried out. The material possessed an IEC of 1.56 meq·dry·g−1 of the exchanger and was found to be nano-composite. The selectivity studies showed that the material is selective towards Pb(II) ions. The selectivity of this cation-exchanger was demonstrated in the binary separation of Pb(II) ions from mixture with other metal ions. The recovery was found to be both quantitative and reproducible.
Print ISSN:
1661-7827
Electronic ISSN:
1660-4601
Topics:
Energy, Environment Protection, Nuclear Power Engineering
,
Medicine
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