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  • chlorinated compound  (5)
  • Analytical Chemistry and Spectroscopy  (4)
Publikationsart
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Verlag/Herausgeber
Erscheinungszeitraum
  • 1
    Digitale Medien
    Digitale Medien
    Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - Trichloroethylene (1998)
    Springer
    Environmental monitoring and assessment 53 (1998), S. 467-487 
    Details
    ISSN: 1573-2959
    Schlagwort(e): risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; trichloroethylene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract This risk assessment on trichloroethylene (TRI) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 19 studies for fish, 30 studies for invertebrates and 14 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 150 µg/l. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.1 µg TRI/l water and a worst case PEC of 3.5 µg TRI/l water. The calculated PEC/PNEC ratios give a safety margin of 40 to 1,500 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern for food chain accumulation is expected.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1006066600350
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  • 2
    Digitale Medien
    Digitale Medien
    Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - Chloroform (1998)
    Springer
    Environmental monitoring and assessment 53 (1998), S. 401-424 
    Details
    ISSN: 1573-2959
    Schlagwort(e): risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; chloroform
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract This risk assessment on chloroform was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 23 studies for fish, 17 studies for invertebrates and 10 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a typical PNEC value of 72 µg/l. Due to limitations of the studies evaluated, a worst PNEC of 1 µg/l could also be used. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.2 µg chloroform per litre of water and a worst case PEC of 5 to 11.5 µg chloroform per litre of water. The calculated PEC/PNEC ratios give a safety margin of 6 to 360 between the predicted no effect concentration and the exposure concentrations. A worst case ratio, however, points to a potential risk for sensitive species. Refinement of the assessment is necessary by looking for more data. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1006010515371
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  • 3
    Digitale Medien
    Digitale Medien
    Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - Tetrachloroethylene (1998)
    Springer
    Environmental monitoring and assessment 53 (1998), S. 489-508 
    Details
    ISSN: 1573-2959
    Schlagwort(e): risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; tetrachloroethylene
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract This risk assessment on tetrachloroethylene (PER) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 18 studies for fish, 13 studies for invertebrates and 8 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 51 µg/l. Most of the available monitoring data apply to rivers and estuary waters and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.2 µg PER/l water and a worst case PEC of 2.5 µg PER/l water. The calculated PEC/PNEC ratios give a safety margin of 20 to 250 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1006018717188
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  • 4
    Digitale Medien
    Digitale Medien
    Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - 1,1,2-Trichloroethane (1998)
    Springer
    Environmental monitoring and assessment 53 (1998), S. 447-466 
    Details
    ISSN: 1573-2959
    Schlagwort(e): risk assessment ; chlorinated compound ; marine ; environmental ; exposure ; aquatic toxicity ; monitoring
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract This risk assessment on 1,1,2-trichloroethane (T112) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 22 studies for fish, 45 studies for invertebrates and 9 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 300 µg/l. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.01 µg T112/l water and a worst case PEC of 5 µg T112/l water. The calculated PEC/PNEC ratios give a safety margin of 60 to 30,000 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1006014616279
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  • 5
    Digitale Medien
    Digitale Medien
    Euro Chlor Risk Assessment for the Marine Environment Osparcom Region: North Sea - 1,2-Dichloroethane (1998)
    Springer
    Environmental monitoring and assessment 53 (1998), S. 425-445 
    Details
    ISSN: 1573-2959
    Schlagwort(e): risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; 1,2-dichloroethane
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik
    Notizen: Abstract This risk assessment on 1,2-dichloroethane (EDC) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 21 studies for fish, 17 studies for invertebrates and 7 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 1100 µg/l. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.5 µg EDC/l and a worst case PEC of 6.4 µg EDC/l. The calculated PEC/PNEC ratios give a safety margin of 170 to 2200 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1023/A:1006062532209
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  • 6
    Digitale Medien
    Digitale Medien
    Polymer molecular weight distribution: Results from matrix-assisted laser desorption ionization compared with those from gel-permeation chromatography (1995)
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 9 (1995), S. 91-92 
    Details
    ISSN: 0951-4198
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Physik
    Notizen: A sample of poly(methyl methacrylate) (PMMA), of which the molecular weight was known from light-scattering measurements, was subjected to gel-perrneation-chromatographic analysis, and the resulting Weight versus log molecular weight (MW) plot was converted by suitable computation to a Number versus linear MW plot. This could then be compared directly with the matrix-assisted laser desorption ionization MW distribution results obtained for the same sample. The MW distributions obtained by the two methods were significantly different. Two explanations for the discrepancy are offered.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/rcm.1290090119
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  • 7
    Digitale Medien
    Digitale Medien
    Mass spectral studies on 7-azabicyclo (2.2.1) heptane systemsNCL Communication No. 1703. (1973)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 7 (1973), S. 1419-1422 
    Details
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An attempt has been made to rationalise the major fragmentation modes of a few C2, C3 disubstituted 7-p-toluene sulphonyl and 7-carbobenzyloxy-7-azabicyclo (2.2.1) heptanes.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/oms.1210071217
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  • 8
    Digitale Medien
    Digitale Medien
    35Cl nuclear quadrupole resonance in 2,4- and 2,6-dichlorobenzyl alcohols (1992)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 30 (1992), S. 616-620 
    Details
    ISSN: 0749-1581
    Schlagwort(e): 35Cl NQR ; Temperature dependence ; Order-disorder transition ; Torsional frequency ; Laser Raman spectra ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: 35Cl nuclear quadrupole resonance (NQR) was studied in 2,4-dichlorobenzyl alcohol (2,4-DCBA) and 2,6-dichlorobenzyl alcohol (2,6-DCBA). The NQR spectrum of 2,4-DCBA show four lines and that of 2,6-DCBA two lines. The temperature dependence of the NQR frequencies from 77 K up to the respective melting points was studied. An order-disorder transition was observed in 2,6-DCBA around 215 K. Torsional frequencies and their temperature coefficients were calculated using the temperature dependence of the NQR frequencies, and were compared with the laser Raman spectra obtained at room temperature.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/mrc.1260300707
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  • 9
    Digitale Medien
    Digitale Medien
    Nuclear magnetic resonance IIIFor Part II see K. M. Biswas, R. N. Dhara and H. Mallik, Indian J. Chem. in press.-13C NMR spectral studies on substituted indoles (1985)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 23 (1985), S. 218-220 
    Details
    ISSN: 0749-1581
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: 13C signal assignments of 3-ethyl-1-methylindole (1), 1-methyl-3-phenylindole (3), 1,3-dimethyl-2-phenylindole (5), 1-methyl-2,3-diphenylindole (10), 1,5-dimethyl-2,3-diphenylindole (12), 7-methoxy-2,3-diphenylindole (13), 7-methoxy-4-methyl-2,3-diphenylindole (14) and 1-(7-methoxy-4-methyl-2,3-diphenyl-6-indolyl)-1-(7-methoxy-2,3-diphenyl-4-indolyl)methane (15) are reported. Contrary to an earlier report on monophenylindoles, the para carbons of the phenyl groups of 3, 5, 10 and 12-15 resonate at lower frequencies than their ortho carbons. The methoxy carbon at position 7 in 15 absorbs at a higher frequency than other similar carbons in 13-15 owing to steric inhibition to resonance.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/mrc.1260230319
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