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  • Stable isotopes  (3)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 120 (2015): 3542-3566, doi:10.1002/2014JC010620.
    Description: We present the results of a 6 week time series of carbonate system and stable isotope measurements investigating the effects of sea ice on air-sea CO2 exchange during the early melt period in the Canadian Arctic Archipelago. Our observations revealed significant changes in sea ice and sackhole brine carbonate system parameters that were associated with increasing temperatures and the buildup of chlorophyll a in bottom ice. The warming sea-ice column could be separated into distinct geochemical zones where biotic and abiotic processes exerted different influences on inorganic carbon and pCO2 distributions. In the bottom ice, biological carbon uptake maintained undersaturated pCO2 conditions throughout the time series, while pCO2 was supersaturated in the upper ice. Low CO2 permeability of the sea ice matrix and snow cover effectively impeded CO2 efflux to the atmosphere, despite a strong pCO2 gradient. Throughout the middle of the ice column, brine pCO2 decreased significantly with time and was tightly controlled by solubility, as sea ice temperature and in situ melt dilution increased. Once the influence of melt dilution was accounted for, both CaCO3 dissolution and seawater mixing were found to contribute alkalinity and dissolved inorganic carbon to brines, with the CaCO3 contribution driving brine pCO2 to values lower than predicted from melt-water dilution alone. This field study reveals a dynamic carbon system within the rapidly warming sea ice, prior to snow melt. We suggest that the early spring period drives the ice column toward pCO2 undersaturation, contributing to a weak atmospheric CO2 sink as the melt period advances.
    Description: We acknowledge support from the Polar Continental Shelf Program (PCSP) of Natural Resources Canada, the Natural Sciences and Engineering Research Council of Canada, the Northern Scientific Training Program, Canada Economic Development, and Fisheries and Oceans Canada.
    Description: 2015-11-19
    Keywords: Sea ice ; Carbon cycling ; CO2 ; Brines ; Stable isotopes ; Arctic Ocean
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 2918–2936, doi:10.1002/2015JC011535.
    Description: We examine the dissolved inorganic carbon maximum in the Canada Basin halocline using a suite of geochemical tracers to gain insight into the factors that contribute to the persistence of this feature. Hydrographic and geochemical samples were collected in the upper 500 m of the southwestern Canada Basin water column in the summer of 2008 and fall of 2009. These observations were used to identify conservative and nonconservative processes that contribute dissolved inorganic carbon to halocline source waters, including shelf sediment organic matter remineralization, air-sea gas exchange, and sea-ice brine export. Our results indicate that the remineralization of organic matter that occurs along the Bering and Chukchi Sea shelves is the overwhelming contributor of dissolved inorganic carbon to Pacific Winter Water that occupies the middle halocline in the southwestern Canada Basin. Nonconservative contributions from air-sea exchange and sea-ice brine are not significant. The broad salinity range associated with the DIC maximum, compared to the narrow salinity range of the nutrient maximum, is due to mixing between Pacific and Atlantic water and not abiotic addition of DIC.
    Description: NSERC; Fisheries and Oceans Canada; US National Science Foundation Office of Polar Programs Grant Number: OPP-0424864; Canadian International Polar Year Office
    Description: 2016-11-04
    Keywords: Arctic Ocean ; Dissolved inorganic carbon ; Nutrients ; Stable isotopes ; Shelf-basin CO2 pump
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 125(1), (2020): e2019JG005414, doi:10.1029/2019JG005414.
    Description: A survey of 25 coastal‐draining rivers across the Canadian Arctic Archipelago (CAA) shows that these systems are distinct from the largest Arctic rivers that drain watersheds extending far south of the Arctic circle. Observations collected from 2014 to 2016 illustrate the influences of seasonal hydrology, bedrock geology, and landscape physiography on each river's inorganic geochemical characteristics. Summertime data show the impact of coincident gradients in lake cover and surficial geology on river geochemical signatures. In the north and central CAA, drainage basins are generally smaller, underlain by sedimentary bedrock, and their hydrology is driven by seasonal precipitation pulses that undergo little modification before they enter the coastal ocean. In the southern CAA, a high density of lakes stores water longer within the terrestrial system, permitting more modification of water isotope and geochemical characteristics. Annual time‐series observations from two CAA rivers reveal that their concentration‐discharge relationships differ compared with those of the largest Arctic rivers, suggesting that future projections of dissolved ion fluxes from CAA rivers to the Arctic Ocean may not be reliably made based on compositions of the largest Arctic rivers alone, and that rivers draining the CAA region will likely follow different trajectories of change under a warming climate. Understanding how these small, coastal‐draining river systems will respond to climate change is essential to fully evaluate the impact of changing freshwater inputs to the Arctic marine system.
    Description: This work was only possible through a network of enthusiastic and devoted collaborators. Partners included Polar Knowledge Canada and the Canadian High Arctic Research Station, the Arctic Research Foundation, the Kugluktuk Angoniatit Association, and the Canadian Arctic GEOTRACES Program. We acknowledge support from the Department of Fisheries and Oceans Canada, the Woods Hole Oceanographic Institution Coastal Ocean Institute, The G. Unger Vetlesen Foundation, Jane and James Orr, and the Woods Hole Research Center. Many thanks go to Austin Maniyogena, Angulalik Pedersen, Adrian Schimnowski, JS Moore, Les Harris, Oksana Schimnowski, as well as Barbara Adjun, Amanda Dumond, and Johnny Nivingalok, and the captains and crew of the research vessels CCGS Amundsen and R/V Martin Bergmann, all of whom supported our research and helped with sample collection. Special thanks also go to Valier Galy, Zhaohui “Aleck” Wang, Marty Davelaar, Michiyo Yamamoto‐Kawai, Hugh McLean, Mike Dempsey, Baba Pedersen, Maureen Soon, Katherine Hoering, Sean Sylva, Ekaterina Bulygina, and Anya Suslova for their invaluable contributions during field program planning, preparations, and laboratory analyses. Robert Max Holmes is thanked for many fruitful discussions. We also thank several anonymous reviewers for their helpful comments on the paper's content and structure. All of the data presented in this paper can be found at https://doi.org/10.1594/PANGAEA.908497.
    Keywords: Arctic Rivers ; Geochemistry ; Major ion chemistry ; Stable isotopes ; Northern hydrology
    Repository Name: Woods Hole Open Access Server
    Type: Article
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