ISSN:
1572-8862
Schlagwort(e):
Cluster core M6E8
;
structural characteristics
;
crystal structure
;
hexacobalt cluster complex
;
phosphine
;
sulfide bridging
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Maschinenbau
,
Physik
Notizen:
Abstract Two new members of the hexanuclear series [Co6S8(PR3)6] n+, complexes [Co6S8(PMe2Ph)6](ClO4) (1) and [Co6S8P(OMe)3 6] (2), have been synthesizes and characterized by X-ray diffraction analyses. Their formation process was postulated to go through trinuclear μ3--S bridged moieties. The structural characteristics of the M6E8P6 skeleton of a whole series of [M6E8(PR3)6] n+ (M=Co, Cr, Fe, Mo; E=S, Se, Te) complexes are presented in terms of atomic distances and core volumes.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1022681127451
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