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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 169 (1989), S. 211-216 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Kinetik der Freigabe von Diacetylfluorescin (DAF) aus Polymer-Membranen wurde untersucht. Die Membranen wurden aus Polystyrol und Polysulfon in „monolithischer“ Form hergestellt. Zur Ermittlung der Freigabegeschwindigkeit durch Hydrolyse von DAF bei 25°C wurde ein Fluoreszenz-Spektrophotometer benutzt. Die Untersuchung zeigte, daß die Freigabe einer Nullter-Ordnung-Kinetik folgt. Die Effekte verschiedener Beladung mit DAF und von Aceton auf die kontrollierte Freigabe wurden ebenfalls ausgewertet.
    Notes: The release kinetics of diacetylfluorescein (DAF) from the polymeric membranes has been studied. The polymeric membranes were made of polystyrene and polysulfone materials in a monolithic form. This work employed a fluorescence spectrophotometer to monitor the release rates by the hydrolysis of DAF at 25°C. The investigation exhibited that the release rates follow a zero-order kinetic scheme. The effects of different loadings of DAF and acetone on the controlled release rates were also exploited.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 30 (1992), S. 801-807 
    ISSN: 0887-6266
    Keywords: networks of uni- and bimodal PDMS in shear ; stress-strain relations in uni- and bimodal networks of PDMS ; poly(dimethylsiloxane) networks, uni- and bimodal, shear modulus in ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Model networks of poly(dimethylsiloxane) (PDMS) were prepared by tetrafunctionally endlinking hydroxyl-terminated chains of various molecular weights. Some networks were prepared from mixtures of chains so as to yield a bimodal distribution of network chain lengths and, in some cases, these networks were prepared in solution. The stress-strain behavior of these unimodal and bimodal networks was studied in pure shear, which was imposed by stretching a sheet of the network having a large ratio of width to length in the direction perpendicular to the width. The pure-shear moduli of both types of networks generally were found to depend markedly on strain. Stress-strain isotherms for unimodal networks prepared from chains of one or the other of two molecular weights were well interpreted using the constrained-junction model of Flory and Erman. The bimodal networks showed large increases in the pure-shear modulus at high strains which were similar to those reported for uniaxial extension and compression. Endlinking in solution decreases the modulus in general and its upturn in particular, presumably because of diminished chain-junction entangling.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 145-151 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermoplastic elastomers based on poly(butylene terephthalate) (PBT) and poly(ethylene glycol) (PEG) were studied by bending-creep measurements. The dependence of the creep compliance on the composition of the block copolymer was determined, and the experimental results were compared with calculated results to obtain a better understanding of structure-property relationships for this class of materials. The hard PBT domains in the rubbery PEG matrix make a large contribution to the mechanical strength and hardness, presumably serving as reinforcing fillers as well as cross-links. Relaxation effects were found to decrease significantly with increase in hard-segment content. © 1994 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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