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    Electronic Resource
    Electronic Resource
    Paradigms and Paradoxes Are Acyl Azides Resonance Stabilized? (1999)
    Springer
    Structural chemistry 10 (1999), S. 327-329 
    Details
    ISSN: 1572-9001
    Keywords: Acyl azides ; Curtius rearrangement ; enthalpy of formation ; enthalpy of reaction ; phenyl/vinyl thermochemical equivalence, resonance energy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract By means of the generic isodesmic reaction C6H5COX + RCH3 → C6H5COCH3 + RX, the phenyl/vinyl thermochemical equivalence, and an experimental determination of the enthalpy of the Curtius rearrangement of acryloyl azide, the resonance energy of acyl azides was ascertained to be ca. 29 kJ mol−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022055304484
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