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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 3183-3192 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An aspen 4-O-methylglucuronoxylan was grafted with poly(sodium acrylate) (PSA) in 3.4N NaOH at 25-30°C. with the use of a persulfate-thiosulfate redox initiator system. The formation of a true graft copolymer was indicated by fractional precipitation and light-scattering studies, physical mixtures of the two pure polymers being used as references. A grafted fraction was isolated, containing no ungrafted xylan but possibly some PSA homopolymer, which contained 96.5% PSA and 3.5% xylan, or an average of 3.2 PSA chains of M̄n approximately 90,500 per xylan chain of M̄n approximately 10,500.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2024-02-07
    Description: The Earth climate system is out of energy balance, and heat has accumulated continuously over the past decades, warming the ocean, the land, the cryosphere, and the atmosphere. According to the Sixth Assessment Report by Working Group I of the Intergovernmental Panel on Climate Change, this planetary warming over multiple decades is human-driven and results in unprecedented and committed changes to the Earth system, with adverse impacts for ecosystems and human systems. The Earth heat inventory provides a measure of the Earth energy imbalance (EEI) and allows for quantifying how much heat has accumulated in the Earth system, as well as where the heat is stored. Here we show that the Earth system has continued to accumulate heat, with 381±61 ZJ accumulated from 1971 to 2020. This is equivalent to a heating rate (i.e., the EEI) of 0.48±0.1 W m−2. The majority, about 89 %, of this heat is stored in the ocean, followed by about 6 % on land, 1 % in the atmosphere, and about 4 % available for melting the cryosphere. Over the most recent period (2006–2020), the EEI amounts to 0.76±0.2 W m−2. The Earth energy imbalance is the most fundamental global climate indicator that the scientific community and the public can use as the measure of how well the world is doing in the task of bringing anthropogenic climate change under control. Moreover, this indicator is highly complementary to other established ones like global mean surface temperature as it represents a robust measure of the rate of climate change and its future commitment. We call for an implementation of the Earth energy imbalance into the Paris Agreement's Global Stocktake based on best available science. The Earth heat inventory in this study, updated from von Schuckmann et al. (2020), is underpinned by worldwide multidisciplinary collaboration and demonstrates the critical importance of concerted international efforts for climate change monitoring and community-based recommendations and we also call for urgently needed actions for enabling continuity, archiving, rescuing, and calibrating efforts to assure improved and long-term monitoring capacity of the global climate observing system. The data for the Earth heat inventory are publicly available, and more details are provided in Table 4.
    Type: Article , PeerReviewed
    Format: text
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  • 3
    Publication Date: 2012-02-21
    Description: The paraglacial reworking of glacial sediments by rivers and mass wasting is an important conditioning factor for modern sediment yields in mountainous catchments in formerly glaciated regions. Catchment scale and patterns of sediment storage are important influences in the rate of postglacial adjustment. We develop a quantitative framework to estimate the volume, sediment type, and fractional size distribution of legacy glacial materials in a large (1 230 km 2 ) watershed in the North Cascade Mountains in southwestern British Columbia, Canada. Chilliwack Valley is exceptional because of the well-dated bounds of deglaciation. Interpolation of paleo-surfaces from partially eroded deposits in the valley allows us to estimate the total evacuated sediment volume. We present a chronology of sediment evacuation from the valley and deposition in the outlet fan, based on infrared stimulated luminescence (IRSL) and 14  C dating of river terraces and fan strata, respectively. The effects of paraglacial sedimentation in Chilliwack Valley were intensified through a major fall in valley base-level following ice retreat. The steepened mainstem valley gradient led to deep incision of valley fills and fan deposits in the lower valley network. The results of this integrated study provide a postglacial chronology and detailed sediment budget, accounting for long term sorting of the original sediments, lag deposit formation in the mainstem, deposition in the outlet fan, and approximate downstream losses of suspended sediment and wash load. The mass balance indicates that a bulk volume of approximately 3.2 km 3 of glacial material has been evacuated from the valley. Copyright © 2012 John Wiley & Sons, Ltd.
    Print ISSN: 0197-9337
    Electronic ISSN: 1096-9837
    Topics: Geography , Geosciences
    Published by Wiley-Blackwell
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  • 4
    Publication Date: 2011-08-20
    Description: A long-term precipitation database has been developed by the U.S. Department of Agriculture (USDA) Agricultural Research Service (ARS) Pasture Systems and Watershed Management Research Unit to support intensive hydrologic and water quality research within WE-38, a 7.3 km2 experimental subwatershed of Mahantango Creek Watershed located in east central Pennsylvania and draining to the Susquehanna River. Daily precipitation data were collected at three sites, with record lengths of 40 years (1968–2007) at two sites and of 29 years (1979–2007) at a third site. Data are available on the USDA ARS's Sustaining the Earth's Watersheds—Agricultural Research Data System (STEWARDS) Web site.
    Print ISSN: 0043-1397
    Electronic ISSN: 1944-7973
    Topics: Architecture, Civil Engineering, Surveying , Geography
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  • 5
    Publication Date: 2012-04-15
    Description: ABSTRACT The paraglacial reworking of glacial sediments by rivers and mass wasting is an important conditioning factor for modern sediment yields in mountainous catchments in formerly glaciated regions. Catchment scale and patterns of sediment storage are important influences in the rate of postglacial adjustment. We develop a quantitative framework to estimate the volume, sediment type, and fractional size distribution of legacy glacial materials in a large (1230 km 2 ) watershed in the North Cascade Mountains in south-western British Columbia, Canada. Chilliwack Valley is exceptional because of the well-dated bounds of deglaciation. Interpolation of paleo-surfaces from partially eroded deposits in the valley allows us to estimate the total evacuated sediment volume. We present a chronology of sediment evacuation from the valley and deposition in the outlet fan, based on infrared stimulated luminescence (IRSL) and 14  C dating of river terraces and fan strata, respectively. The effects of paraglacial sedimentation in Chilliwack Valley were intensified through a major fall in valley base-level following ice retreat. The steepened mainstem valley gradient led to deep incision of valley fills and fan deposits in the lower valley network. The results of this integrated study provide a postglacial chronology and detailed sediment budget, accounting for long-term sorting of the original sediments, lag deposit formation in the mainstem, deposition in the outlet fan, and approximate downstream losses of suspended sediment and wash load. The mass balance indicates that a bulk volume of approximately 3.2 km 3 of glacial material has been evacuated from the valley. Copyright © 2012 John Wiley & Sons, Ltd.
    Print ISSN: 0197-9337
    Electronic ISSN: 1096-9837
    Topics: Geography , Geosciences
    Published by Wiley-Blackwell
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  • 6
    Publication Date: 2011-08-20
    Description: A long-term streamflow discharge database has been developed by the U.S. Department of Agriculture (USDA) Agricultural Research Service (ARS) Pasture Systems and Watershed Management Research Unit to support intensive hydrologic and water quality research within WE-38, a 7.3 km2 experimental subwatershed of Mahantango Creek Watershed located in east central Pennsylvania and draining to the Susquehanna River. Daily streamflow discharge data were collected at the outflow of WE-38 from 1968 to 2007, producing a 40 year record of streamflow. Data are available on USDA ARS's Sustaining the Earth's Watersheds—Agricultural Research Data System (STEWARDS) Web site.
    Print ISSN: 0043-1397
    Electronic ISSN: 1944-7973
    Topics: Architecture, Civil Engineering, Surveying , Geography
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