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  • Springer  (4)
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  • 1
    Electronic Resource
    Electronic Resource
    A numerical algorithm for the determination of the adsorptive energy distribution function from isotherm data (1978)
    Springer
    Colloid & polymer science 256 (1978), S. 52-61 
    Details
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zusammenfassung Es wurde ein numerischer Algorithmus (HILDA) entwickelt und zugänglich gemacht, um die Oberflächenheterogenität eines Pulverpräparates in Termen einer “fleckenweisen” Adsorptionsenergieverteilungsfunktion zu bestimmen. Die Adsorption an einheitlich adsorbierenden “Flecken” kann durch die Wahl geeigneter Modellisothermen beschrieben werden. Als solche dienen die Gleichungen nach Hill-de Boer, Fowler-Guggenheim, Langmuir sowie die zweidimensionale Virialgleichung. Es werden Parameter angegeben, mit deren Hilfe HILDA auf eine Vielzahl von Adsorptionssystemen angewendet werden kann, und es wird gezeigt, wie die Monoschichtkapazität einer Oberfläche bestimmt werden kann. Die Ergebnisse werden mit BET-Werten verglichen. HILDA wird weiterhin verwendet, um Änderungen in der Verteilung der Adsorptionsenergie zu verfolgen, welche beim Tempern eines Kochsalzpräparates mit hoher spezifischer Oberfläche erfolgen.
    Notes: Summary A numerical algorithm (HILDA) is developed and made available for the determination of the surface heterogeneity 'of a powder sample in terms of a ‘patchwise’ adsorptive energy distribution function. Adsorption on unisorptic `patches' may be described by a choice of model isotherm functions. These are the Hill-de Boer equation, Fowler-Guggenheim, Langmuir and the two dimensional virial equation. Parameters are presented to enable HILDA to be applied to a variety of adsorption systems. It is demonstrated how the monolayer capacity of a surface can be determined and the results are compared to BET values. HILDA is also used to follow the changes in the adsorptive energy distribution that occur with annealing a high specific area sodium chloride sample. It is concluded that the method has considerable potential for future applications.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01746691
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Adsorption von inerten Gasen an NaCl. I. Bestimmung der Verteilungen der adsorptiven Energie nach einer neuen numerischen Methode (1979)
    Springer
    Colloid & polymer science 257 (1979), S. 671-671 
    Details
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01548840
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Chemical modelling applications to experimental recirculating streams (1989)
    Springer
    Hydrobiologia 178 (1989), S. 93-112 
    Details
    ISSN: 1573-5117
    Keywords: Streams ; carbon dioxide ; oxygen ; calcite ; phosphate coprecipitation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Chemical models describing the precipitation of calcium carbonate, coprecipitation of inorganic phosphate, carbon dioxide and oxygen transfer through the air-water interface have been applied to results from a recirculating experimental stream. The transfer velocities for carbon dioxide and oxygen transfer for the experimental stream were determined as 1.00 × 10−4 m s−1 and 0.0058 m min−1 (at 20°C) respectively. During a 24-hour long experiment the stream, containing a varied biota dominated by the macro-algae Zygnema, was monitored to evaluate changes in the water chemistry. The calcite precipitation rate varied during the experiment reflecting changes in temperature, supersaturation of the water and local variation in the solution chemistry at the growth sites. The rate constant was evaluated from a chemical mechanistic model as 516.7 ± 27.2 mol h−1 at 10 °C. The coprecipitation of inorganic phosphate, which accompanied calcite growth, accounted for 〈 6% of the total phosphorus loss. The constant uptake of phosphorus by plants and algae was estimated as ≃0.22 μmol h−1 g−1 dry weight). The rates of production of oxygen and consumption of inorganic carbon in the experimental stream, after taking account of gas transfer and calcite precipitation, were also computed and found to be in good agreement during the experiment. The maximum rate of production of oxygen was ≃ 3.5 × 10−4 mol h−1 g−1 (dry weight).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00011662
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Die Adsorption von inerten Gasen an NaCl. II. Eine Virialanalyse gasförmig-fest von Argon, das an NaCl adsorbiert ist (1979)
    Springer
    Colloid & polymer science 257 (1979), S. 671-671 
    Details
    ISSN: 1435-1536
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01548841
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    Paper (German National Licenses)
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