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  • 1
    Digitale Medien
    Digitale Medien
    Determination of 5,10,15,20-tetra-(m-hydroxyphenyl) chlorin in tissues by high performance liquid chromatography (1993)
    New York, NY : Wiley-Blackwell
    Biomedical Chromatography 7 (1993), S. 155-157 
    Details
    ISSN: 0269-3879
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin
    Notizen: A procedure for the extraction and high performance liquid chromatographic (HPLC) determination of the photodynamic therapeutic agent 5,10,15,20-tetra(m-hydroxyphenyl)chlorin in human, rat and mouse tissues following intravenous administration of the drug is described. The tissue (tumour, skin, muscle and liver) was homogenized and extracted into a mixture of methanol:dimethyl sulphoxide:water (32:8:1 by vol.) containing, 5,10,15,20-tetra(p-hydroxyphenyl)chlorin as the internal standard. The precipitated proteins were removed by centrifugation and the supernatant was separated by reversed phase HPLC on a Hypersil-ODS column with 77% (v/v) acetonitrile in 0.1% trifluoroacetic acid as the mobile phase. The solute was detected with high sensitivity and specificity by a UV-VIS detector set at 423 nm.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/bmc.1130070311
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  • 2
    Digitale Medien
    Digitale Medien
    Poly(N-p-pyridyl-2,3-dimethylenepyrrolidine) as a supernucleophilic reagent (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 1391-1392 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1994.070531014
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Determination of 5,10,15,20- tetra- (m-hydroxyphenyl)chlorin in human plasma by high performance liquid chromatography (1993)
    New York, NY : Wiley-Blackwell
    Biomedical Chromatography 7 (1993), S. 45-47 
    Details
    ISSN: 0269-3879
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin
    Notizen: A high performance liquid chromatographic method for the determination of the photodynamic chemotherapeutic agent 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (m-THPC) in human plasma following intravenous infusion is described. The procedure involves extraction of the drug in plasma with methanol/dimethyl sulphoxide (4:1 v/v) containing 5,10,15,20-tetra(p-hydroxyphenyl)clorin as the internal standard and separation on a C18 reversed phase column with acetonitrile:0.1% trifluoroacetic acid (77:23 v/v) as the mobile phase. The drug was detected specifically and sensitively at its absorption maximum of 423 nm with a detection limit of 15 ng/mL (signal-to-noise ratio of 5). The intra- and inter-assay coefficients of variation (CV) on analysis of a plasma spiked with m-THPC (1 μg/mL) were 2.3 and 3.4% (n=6), respectively.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/bmc.1130070112
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  • 4
    Digitale Medien
    Digitale Medien
    Preparation and characterization of negative photosensitive polysiloxaneimide (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 1111-1116 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A photosensitive polysiloxaneimide precursor was synthesized from oxydianiline, bis(p-aminophenoxy)dimethylsilane, and a diacid chloride. This diacid chloride was prepared by the reaction of thionyl chloride with a diacid, which resulted from the reaction of pyromellitic dianhydride with hydroxyethylacrylate in N-methylpyrrolidone (NMP). The adhesion properties between polyimide and substrates such as SiO2 wafer were improved with introduction of siloxane moiety into the polyimide chain. The dielectric constant decreased with increasing siloxane moiety content. The photocrosslinking reaction results show that an 88-90% gel fraction was reached under the irradiation of a high-pressure mercury lamp. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1995.070550714
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  • 5
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    Sensors, Vol. 14, Pages 382-402: Vibration Sensor Data Denoising Using a Time-Frequency Manifold for Machinery Fault Diagnosis (2013)
    MDPI Publishing
    In: Sensors
    Details
    Publikationsdatum: 2013-12-28
    Beschreibung: Vibration sensor data from a mechanical system are often associated with important measurement information useful for machinery fault diagnosis. However, in practice the existence of background noise makes it difficult to identify the fault signature from the sensing data. This paper introduces the time-frequency manifold (TFM) concept into sensor data denoising and proposes a novel denoising method for reliable machinery fault diagnosis. The TFM signature reflects the intrinsic time-frequency structure of a non-stationary signal. The proposed method intends to realize data denoising by synthesizing the TFM using time-frequency synthesis and phase space reconstruction (PSR) synthesis. Due to the merits of the TFM in noise suppression and resolution enhancement, the denoised signal would have satisfactory denoising effects, as well as inherent time-frequency structure keeping. Moreover, this paper presents a clustering-based statistical parameter to evaluate the proposed method, and also presents a new diagnostic approach, called frequency probability time series (FPTS) spectral analysis, to show its effectiveness in fault diagnosis. The proposed TFM-based data denoising method has been employed to deal with a set of vibration sensor data from defective bearings, and the results verify that for machinery fault diagnosis the method is superior to two traditional denoising methods.
    Digitale ISSN: 1424-8220
    Thema: Chemie und Pharmazie , Elektrotechnik, Elektronik, Nachrichtentechnik
    Publiziert von MDPI Publishing
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  • 6
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    Sustainable limits to crop residue harvest for bioenergy: maintaining soil carbon in Australia's agricultural lands (2014)
    Wiley-Blackwell
    Details
    Publikationsdatum: 2014-03-09
    Beschreibung: The use of crop residues for bioenergy production needs to be carefully assessed because of the potential negative impact on the level of soil organic carbon (SOC) stocks. The impact varies with environmental conditions and crop management practices and needs to be considered when harvesting the residue for bioenergy productions. Here, we defined the sustainable harvest limits as the maximum rates that do not diminish SOC and quantified sustainable harvest limits for wheat residue across Australia's agricultural lands. We divided the study area into 9432 climate-soil (CS) units and simulated the dynamics of SOC in a continuous wheat cropping system over 122 years (1889 – 2010) using the Agricultural Production Systems sIMulator (APSIM). We simulated management practices including six fertilization rates (0, 25, 50, 75, 100, and 200 kg N ha −1 ) and five residue harvest rates (0, 25, 50, 75, and 100%). We mapped the sustainable limits for each fertilization rate and assessed the effects of fertilization and three key environmental variables – initial SOC, temperature, and precipitation – on sustainable residue harvest rates. We found that, with up to 75 kg N ha −1 fertilization, up to 75% and 50% of crop residue could be sustainably harvested in south-western and south-eastern Australia, respectively. Higher fertilization rates achieved little further increase in sustainable residue harvest rates. Sustainable residue harvest rates were principally determined by climate and soil conditions, especially the initial SOC content and temperature. We conclude that environmental conditions and management practices should be considered to guide the harvest of crop residue for bioenergy production and thereby reduce greenhouse gas emissions during the life cycle of bioenergy production.
    Print ISSN: 1757-1693
    Digitale ISSN: 1757-1707
    Thema: Energietechnik
    Publiziert von Wiley-Blackwell
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  • 7
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    Optimal Retrofit Design of Crude Distillation Units for Processing Shale Gas/Natural Gas Condensate Oil (2015)
    Wiley-Blackwell
    Details
    Publikationsdatum: 2015-11-21
    Beschreibung: Condensate oil is a kind of light crude oil with API gravity higher than 50 degrees. The increasing production of condensate oil due to shale gas/natural gas booming has economically motivate refiners to add this valuable and abundant crude source into their feedstock. Many refineries, however, were originally built to process heavier crudes, whose design must be retrofitted to enable the processing of the changed feedstock. In this paper, the conceptual retrofit design of crude distillation units for processing condensate oil has been studied. Four retrofit designs are proposed and simulated including facilities of preflash column, atmospheric distillation unit, and vacuum distillation unit. All retrofit designs are comprehensively evaluated by steady-state modeling for feasibility check, energy consumption analysis for operating cost evaluation, and retrofit cost evaluation. With the help of Aspen Plus, Aspen Energy Analyzer, and Aspen Capital Cost Estimator, the developed methodology provides a quantitative technology support to identify the optimal retrofit design. A comparison of the results shows that the retrofit design with preflash columns in sequence potentially could be the most economical case.
    Print ISSN: 0930-7516
    Digitale ISSN: 1521-4125
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Publiziert von Wiley-Blackwell
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  • 8
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    Atmosphere, Vol. 6, Pages 1633-1651: The Influence of Sandstorms and Long-Range Transport on Polycyclic Aromatic Hydrocarbons (PAHs) in PM2.5 in the High-Altitude Atmosphere of Southern China (2015)
    MDPI Publishing
    Details
    Publikationsdatum: 2015-10-31
    Beschreibung: PM2.5 (Particulate Matter 2.5) samples were collected at Mount Heng and analyzed for polycyclic aromatic hydrocarbons (PAHs). During sampling, a sandstorm from northern China struck Mount Heng and resulted in a mean PM2.5 concentration of 150.61 μg/m3, which greatly exceeded the concentration measured under normal conditions (no sandstorm: 58.50 μg/m3). The average mass of PAHs in PM2.5 was 30.70 μg/g, which was much lower than in the non-sandstorm samples (80.80 μg/g). Therefore, the sandstorm increased particle levels but decreased PAH concentrations due to dilution and turbulence. During the sandstorm, the concentrations of 4- and 5-ring PAHs were below their detection limits, and 6-ring PAHs were the most abundant. Under normal conditions, the concentrations of 2-, 3- and 6-ring PAHs were higher, and 4- and 5-ring PAHs were lower relative to the other sampling sites. In general, the PAH contamination was low to medium at Mount Heng. Higher LMW (low molecular weight) concentrations were primarily linked to meteorological conditions, and higher HMW (high molecular weight) concentrations primarily resulted from long-range transport. Analysis of diagnostic ratios indicated that PM2.5 PAHs had been emitted during the combustion of coal, wood or petroleum. The transport characteristics and origins of the PAHs were investigated using backwards Lagrangian particle dispersion modeling. Under normal conditions, the “footprint” retroplumes and potential source contributions of PAHs for the highest and lowest concentrations indicated that local sources had little effect. In contrast, long-range transport played a vital role in the levels of PM2.5 and PAHs in the high-altitude atmosphere.
    Digitale ISSN: 2073-4433
    Thema: Geologie und Paläontologie
    Publiziert von MDPI Publishing
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  • 9
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    Unbekannt
    Spatiotemporal patterns and source implications of aromatic hydrocarbons at six rural sites across China's developed coastal regions (2016)
    Wiley-Blackwell
    Details
    Publikationsdatum: 2016-05-27
    Beschreibung: Aromatic hydrocarbons are important anthropogenic precursors of tropospheric ozone and secondary organic aerosols. Here, we measured ambient aromatic hydrocarbons from March 2012 to February 2014 at six rural sites in China's developed coastal regions. On average, benzene (B) comprised 〉 50% of total benzene (B), toluene (T), ethylbenzene (E), and xylenes (X) (BTEX) at sites in the Northeast China Plain (NECP) or in the North China Plain (NCP), whereas T, E, and X accounted for 〉 77% of total BTEX at sites in the Yangtze River Delta (YRD) and the Pearl River Delta (PRD) in the south. BTEX at the northern sites was significantly correlated ( p  〈 0.01) with combustion tracer-carbon monoxide (CO) but weakly correlated with traffic marker-methyl tert-butyl ether (MTBE), suggesting that their main sources were coal and biofuel/biomass burning with substantially elevated B levels during the winter heating period. In contrast, BTEX at the southern sites originated mainly from traffic-related and/or industrial emission sources, as indicated by the poor correlations with CO but highly significant ( p  〈 0.01) correlations with MTBE and tetrachloroethylene, an industrial emission tracer. The B/CO emission ratios from measurement agreed within a factor of two with that of a previous widely used emission inventory of China, but the T/CO ratio at the NECP site and the o-X/CO ratio at the NCP site were 29% and 38% of that in the inventory, respectively; the E/CO and X/CO ratios at the YRD site were 3.2-3.5 fold that in the emission inventory.
    Print ISSN: 0148-0227
    Thema: Geologie und Paläontologie , Physik
    Publiziert von Wiley-Blackwell im Namen von American Geophysical Union (AGU).
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  • 10
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    Water, Vol. 8, Pages 223: Variations in the Runoff-Sediment Relationship of the Weihe River Basin Based on the Copula Function (2016)
    MDPI Publishing
    In: Water
    Details
    Publikationsdatum: 2016-05-26
    Beschreibung: This study investigates the runoff-sediment relationship (RSR) of the Weihe River, a sandy waterway originating from the Loess Plateau, and considers the potential variations in RSR under an evolving environment. The double mass curve method was used to investigate RSR inflection points at six hydrologic stations located in the Weihe River basin (WRB) spanning the period from 1956 to 2010. Because of its ability to accurately define nonlinear and asymmetric correlations between variables, the Copula function provided the joint probability distributions and revealed the joint probabilities of annual runoff and sediment yield through different periods. The results indicated: (1) The sediment yield and runoff exhibit decreasing trends, which was principally related to human activity such as soil and water conservation measures, water projects and industrial and domestic water use, (2) the RSR inflection points principally occurred around 1983 at the Weijiabu, Xianyang, Huaxian and Zhuangtou stations, whereas they were non-significant at the Linjiacun and Zhangjiashan stations. Changes in RSR are attributed to the irregular effect of human activity reducing the runoff and sediment output; and (3) the joint probability distributions of annual runoff and sediment yield varied under an evolving environment and were characterized by spatial variability, which is more evident in the mainstream areas of the Weihe River than in the tributary regions.
    Digitale ISSN: 2073-4441
    Thema: Energietechnik
    Publiziert von MDPI Publishing
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