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  • 1
    In: Catalysts, MDPI AG, Vol. 11, No. 9 ( 2021-09-09), p. 1086-
    Abstract: NiMo catalysts supported on mesoporous MCM-41 type materials shaped with binder were tested for activity in the hydrodesulfurization of 4,6-dimethyldibenzothiophene (4,6-DMDBT) and the diesel fuel fraction (0.92 wt% of sulfur). The aim of the investigation was to evaluate the effect of ion exchange with protons of Al- or Ti-substituted MCM-41 mesoporous supports. The subjected catalytic systems were NiMo/HAlMCM-41 and NiMo/HTiMCM-41, and for comparison purposes NiMo/AlMCM-41 and NiMo/TiMCM-41. The samples were characterized by N2 sorption (at 77 K), XRD, TEM, XPS, SEM and Py–IR. It was found that the functionalization of AlMCM-41 and TiMCM-41 with protons increased the conversion of 4,6-DMDBT and the pseudo-first-order rate constant. Correspondingly, 4,6-DMDBT HDS reactions over the NiMo/HTiMCM-41 catalyst proceeded to a similar extent via hydrogenation and direct desulfurization, whereas over the NiMo/HAlMCM-41 they proceeded mainly via direct desulfurization. Furthermore, the ion-exchanged catalysts displayed two-fold higher efficiency in direct desulfurization than their non-modified counterparts. The NiMo/HTiMCM-41 catalyst exhibited the highest catalytic efficiency in the HDS of 4,6-DMDBT and the diesel oil fraction. The high activity of the NiMo/HTiMCM-41 catalyst is mainly attributed to its appropriate acidity, as well as the metal–support interaction providing both the high dispersion of the active phase and the desirable multilayered stacking morphology of the active phase slabs.
    Type of Medium: Online Resource
    ISSN: 2073-4344
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
    detail.hit.zdb_id: 2662126-5
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  • 2
    In: Catalysts, MDPI AG, Vol. 12, No. 6 ( 2022-05-31), p. 600-
    Abstract: The effect of a potassium promoter on the stability of and resistance to a carbon deposit formation on the Ni/MnOx catalyst under SRE conditions was studied at 420 °C for different H2O/EtOH molar ratios in the range from 4/1 to 12/1. The catalysts were prepared by the impregnation method and characterized using several techniques to study their textural, structural, and redox properties before being tested in a SRE reaction. The catalytic tests indicated that the addition of a low amount of potassium (1.6 wt.%) allows a catalyst with high stability to be obtained, which was ascribed to high resistance to carbon formation. The restriction of the amount of carbon deposits originates from the potassium presence on the Ni surface, which leads to (i) a decrease in the number of active sites available for methane decomposition and (ii) an increase in the rate of the steam gasification of carbon formed during SRE reactions.
    Type of Medium: Online Resource
    ISSN: 2073-4344
    Language: English
    Publisher: MDPI AG
    Publication Date: 2022
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  • 3
    In: Symmetry, MDPI AG, Vol. 12, No. 11 ( 2020-11-05), p. 1835-
    Abstract: The Cosmic-Ray Extremely Distributed Observatory (CREDO) is a newly formed, global collaboration dedicated to observing and studying cosmic rays (CR) and cosmic-ray ensembles (CRE): groups of at least two CR with a common primary interaction vertex or the same parent particle. The CREDO program embraces testing known CR and CRE scenarios, and preparing to observe unexpected physics, it is also suitable for multi-messenger and multi-mission applications. Perfectly matched to CREDO capabilities, CRE could be formed both within classical models (e.g., as products of photon–photon interactions), and exotic scenarios (e.g., as results of decay of Super-Heavy Dark Matter particles). Their fronts might be significantly extended in space and time, and they might include cosmic rays of energies spanning the whole cosmic-ray energy spectrum, with a footprint composed of at least two extensive air showers with correlated arrival directions and arrival times. As the CRE are predominantly expected to be spread over large areas and, due to the expected wide energy range of the contributing particles, such a CRE detection might only be feasible when using all available cosmic-ray infrastructure collectively, i.e., as a globally extended network of detectors. Thus, with this review article, the CREDO Collaboration invites the astroparticle physics community to actively join or to contribute to the research dedicated to CRE and, in particular, to pool together cosmic-ray data to support specific CRE detection strategies.
    Type of Medium: Online Resource
    ISSN: 2073-8994
    Language: English
    Publisher: MDPI AG
    Publication Date: 2020
    detail.hit.zdb_id: 2518382-5
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  • 4
    In: Materials, MDPI AG, Vol. 15, No. 17 ( 2022-09-03), p. 6132-
    Abstract: Three-dimensional concrete printing (3DCP) is an innovative technology that can lead to breakthrough modifications of production processes in the construction industry. The paper presents for the first time the possibility of 3D printing concrete–geopolymer hybrids reinforced with aramid roving. Reference concrete samples and concrete–geopolymer hybrids composed of 95% concrete and 5% geopolymer based on fly ash or metakaolin were produced. The properties of the samples without reinforcement and samples with 0.5% (wt.) aramid roving were compared. The frost resistance tests, UV radiation resistance, and thermal conductivity were evaluated for samples that were 3D-printed or produced by the conventional casting method. Compressive strength tests were carried out for each sample exposed to freeze–thaw cycles and UV radiation. It was observed that after the frost resistance test, the samples produced by the 3D printing technology had a minor decrease in strength properties compared to the samples made by casting. Moreover, the thermal conductivity coefficient was higher for concrete–geopolymer hybrids than concrete reinforced with aramid roving.
    Type of Medium: Online Resource
    ISSN: 1996-1944
    Language: English
    Publisher: MDPI AG
    Publication Date: 2022
    detail.hit.zdb_id: 2487261-1
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  • 5
    In: Materials, MDPI AG, Vol. 16, No. 17 ( 2023-09-02), p. 6032-
    Abstract: Recent years have witnessed a growing global interest in 3D concrete printing technology due to its economic and scientific advantages. The application of foamed concrete, renowned for its exceptional thermal and acoustic insulation properties, not only holds economic attractiveness but also aligns seamlessly with the principles of sustainable development. This study explores various solutions related to 3D printing technology in construction, discussing the design, production, and properties of foamed concrete mixtures. The integration of 3D printing and the potential for automating the entire process offers opportunities to boost productivity and reduce construction costs. Furthermore, the utilization of foamed concrete with its commendable insulation properties will enable a reduction in the usage of materials other than concrete (e.g., mineral wool, facade mesh, and polystyrene), significantly facilitating the recycling process during building demolition. This, in turn, will lead to the preservation of nonrenewable natural resources and a decrease in CO2 emissions. Despite the promising results, there have been limited studies focusing on 3D printing with foamed materials, whereas a survey of the existing body of literature indicates a notable absence of endeavors pertaining to the utilization of aerated concrete within the realm of 3D printing, especially geopolymer composites (GP) and hybrid geopolymer composites (HGP). The outcomes delineated in the ensuing discourse are demonstrative for conventionally used materials rather than the additive manufacturing variant. Hence, this work aims to systematically review existing practices and techniques related to producing foamed concrete with 3D printing technology. This analysis also contributes to the establishment of a foundational framework and furnishes a preliminary basis upon which future endeavors aimed at the 3D printing of aerated concrete can be embarked. The findings from the literature analysis justify the desirability of continuing research on this topic, particularly when considering the potential for large-scale industrial implementation. This article provides a comprehensive state of the knowledge on the development of 3D printing techniques for foamed concrete mixtures. By consolidating and analyzing findings from different studies, this article offers insights into the advancements, challenges, and potential applications of foamed concrete in additive manufacturing processes. This, in turn, contributes to the overall understanding and advancement of 3D printing technologies using foamed concrete as a versatile and sustainable construction material. The encouraging results obtained from the analysis further underscore the need for the continued exploration of 3D printing, especially with an eye towards its industrial-scale implementation.
    Type of Medium: Online Resource
    ISSN: 1996-1944
    Language: English
    Publisher: MDPI AG
    Publication Date: 2023
    detail.hit.zdb_id: 2487261-1
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  • 6
    In: Sensors, MDPI AG, Vol. 8, No. 10 ( 2008-10-23), p. 6507-6548
    Type of Medium: Online Resource
    ISSN: 1424-8220
    Language: English
    Publisher: MDPI AG
    Publication Date: 2008
    detail.hit.zdb_id: 2052857-7
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  • 7
    In: Materials, MDPI AG, Vol. 16, No. 17 ( 2023-08-23), p. 5772-
    Abstract: The intensive development of 3D Concrete Printing (3DCP) technology causes constantly increased its share in the construction sector. However, in order to produce products with controlled properties, optimization of the technological process is still required. Automation of production based on additive manufacturing methods streamlines the process by comprehensively manufacturing building components that meet, among others, strength, visual, and insulation requirements. Moreover, the possibility of using computer simulations to assess the properties of the designed elements allows for a multitude of analyzed versions of the constructed partitions, which can be verified at the design stage. Thanks to such an opportunity, the process of designing building elements can be significantly improved. The article presents results related to the assessment of the level of thermal insulation of products that can be produced by additive technology, depending on the applied spatial geometry of the vertical partition and the amount and type of materials used. Eight original solutions of in-fill pattern were designed, for which both Finite Element Method (FEM) computer simulations of thermal conductivity and experimental measurements of thermal conductivity of samples were performed. On the basis of the obtained results, both the correctness of the simulation results for the various analyzed materials and their consistency with the practical results were found. Depending on the investigated geometry, for samples of the same dimensions and using the same material, the differences in the U-factor obtained by FEM analysis amounted to 61%. The best solution from the investigated spatial geometries of the vertical partitions has been indicated. The U parameter in the variant with the best thermal insulation was 0.183 W/m2K, which meets the requirements of Polish construction law. The issues discussed in this work can be the basis for the selection of the best solution possible for practical use during the production of building walls using the 3DCP method fulfilling the guidelines of applicable standards. Furthermore, they can be used as a tool for optimizing geometry in terms of energy savings and reducing waste production by both engineers developing 3DCP technologies and architects using innovative techniques for manufacturing building structures.
    Type of Medium: Online Resource
    ISSN: 1996-1944
    Language: English
    Publisher: MDPI AG
    Publication Date: 2023
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  • 8
    In: Sensors, MDPI AG, Vol. 21, No. 14 ( 2021-07-14), p. 4804-
    Abstract: Gamification is known to enhance users’ participation in education and research projects that follow the citizen science paradigm. The Cosmic Ray Extremely Distributed Observatory (CREDO) experiment is designed for the large-scale study of various radiation forms that continuously reach the Earth from space, collectively known as cosmic rays. The CREDO Detector app relies on a network of involved users and is now working worldwide across phones and other CMOS sensor-equipped devices. To broaden the user base and activate current users, CREDO extensively uses the gamification solutions like the periodical Particle Hunters Competition. However, the adverse effect of gamification is that the number of artefacts, i.e., signals unrelated to cosmic ray detection or openly related to cheating, substantially increases. To tag the artefacts appearing in the CREDO database we propose the method based on machine learning. The approach involves training the Convolutional Neural Network (CNN) to recognise the morphological difference between signals and artefacts. As a result we obtain the CNN-based trigger which is able to mimic the signal vs. artefact assignments of human annotators as closely as possible. To enhance the method, the input image signal is adaptively thresholded and then transformed using Daubechies wavelets. In this exploratory study, we use wavelet transforms to amplify distinctive image features. As a result, we obtain a very good recognition ratio of almost 99% for both signal and artefacts. The proposed solution allows eliminating the manual supervision of the competition process.
    Type of Medium: Online Resource
    ISSN: 1424-8220
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
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  • 9
    In: Catalysts, MDPI AG, Vol. 10, No. 5 ( 2020-05-04), p. 506-
    Abstract: Nanosized SSZ-13 was synthesized hydrothermally by applying N,N,N-trimethyl-1-adamantammonium hydroxide (TMAdaOH) as a structure-directing agent. In the next step, the quantity of TMAdaOH in the initial synthesis mixture of SSZ-13 was reduced by half. Furthermore, we varied the sodium hydroxide concentration. After ion-exchange with copper ions (Cu2+ and Cu+), the Cu-SSZ-13 catalysts were characterized to explore their framework composition (XRD, solid-state NMR, ICP-OES), texture (N2-sorption, SEM) and acid/redox properties (FT-IR, TPR-H2, DR UV-Vis, EPR). Finally, the materials were tested in the selective catalytic reduction of NOx with ammonia (NH3-SCR). The main difference between the Cu-SSZ-13 catalysts was the number of Cu2+ in the double six-membered ring (6MRs). Such copper species contribute to a high NH3-SCR activity. Nevertheless, all materials show comparable activity in NH3-SCR up to 350 °C. Above 350 °C, NO conversion decreased for Cu-SSZ-13(2–4) due to side reaction of NH3 oxidation.
    Type of Medium: Online Resource
    ISSN: 2073-4344
    Language: English
    Publisher: MDPI AG
    Publication Date: 2020
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  • 10
    Online Resource
    Online Resource
    MDPI AG ; 2021
    In:  Risks Vol. 9, No. 2 ( 2021-02-06), p. 36-
    In: Risks, MDPI AG, Vol. 9, No. 2 ( 2021-02-06), p. 36-
    Abstract: Low saving rates combined with low effective retirement age herald old-age poverty. This paper examines the preferred strategies of future Polish pensioners in order to sustain the standard of living in the future. A two-step approach is used: as a first-best strategy, we explore determinants of supplementary saving with binary logistic models; as a second-best strategy, we examine alternative options with principal component analysis. Future retirees rarely accumulate long-term savings, do not use dedicated instruments, and they start to save additionally far too late. Savings are concentrated in wealthier and better educated groups. Such myopia is governed by their political stance and not by awareness of dire prospects. Second-best strategies are based on optimistic assumptions about future health (seeking for additional jobs), on the assumed generosity of acquaintances or social institutions (relying on external assistance), or on rebelling. Given the increasing political power of elder generations, balancing the interests of workers and retirees will be an increasingly difficult task for policy makers.
    Type of Medium: Online Resource
    ISSN: 2227-9091
    Language: English
    Publisher: MDPI AG
    Publication Date: 2021
    detail.hit.zdb_id: 2704357-5
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