In:
Acta Crystallographica Section C Crystal Structure Communications, International Union of Crystallography (IUCr), Vol. 59, No. 11 ( 2003-11-01), p. m454-m455
Abstract:
In the title compound, [Cu(C 10 H 4 O 8 )(C 12 H 8 N 2 )] n , the Cu II cation has a four-coordination environment completed by two N atoms from one 1,10-phenanthroline (phen) ligand and two O atoms belonging to two dihydrogen benzene-1,2,4,5-tetracarboxylate anions (H 2 TCB 2− ). There is a twofold axis passing through the Cu II cation and the centre of the phen ligand. The [Cu(phen)] 2+ moieties are bridged by H 2 TCB 2− anions to form an infinite one-dimensional coordination polymer with a zigzag chain structure along the c axis. A double-chain structure is formed by hydrogen bonds between adjacent zigzag chains. Furthermore, there are π–π stacking interactions between the phen ligands, with an average distance of 3.64 Å, resulting in a two-dimensional network structure.
Type of Medium:
Online Resource
ISSN:
0108-2701
DOI:
10.1107/S0108270103021097
DOI:
10.1107/S0108270103021097/ob1146sup1.cif
DOI:
10.1107/S0108270103021097/ob1146Isup2.hkl
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2003
detail.hit.zdb_id:
2025703-X
SSG:
13
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