Beschreibung: Radiocarbon (14C) ages cannot provide absolutely dated chronologies for archaeological or paleoenvironmental studies directly but must be converted to calendar age equivalents using a calibration curve compensating for fluctuations in atmospheric 14C concentration. Although calibration curves are constructed from independently dated archives, they invariably require revision as new data become available and our understanding of the Earth system improves. In this volume the international 14C calibration curves for both the Northern and Southern Hemispheres, as well as for the ocean surface layer, have been updated to include a wealth of new data and extended to 55,000 cal BP. Based on tree rings, IntCal20 now extends as a fully atmospheric record to ca. 13,900 cal BP. For the older part of the timescale, IntCal20 comprises statistically integrated evidence from floating tree-ring chronologies, lacustrine and marine sediments, speleothems, and corals. We utilized improved evaluation of the timescales and location variable 14C offsets from the atmosphere (reservoir age, dead carbon fraction) for each dataset. New statistical methods have refined the structure of the calibration curves while maintaining a robust treatment of uncertainties in the 14C ages, the calendar ages and other corrections. The inclusion of modeled marine reservoir ages derived from a three-dimensional ocean circulation model has allowed us to apply more appropriate reservoir corrections to the marine 14C data rather than the previous use of constant regional offsets from the atmosphere. Here we provide an overview of the new and revised datasets and the associated methods used for the construction of the IntCal20 curve and explore potential regional offsets for tree-ring data. We discuss the main differences with respect to the previous calibration curve, IntCal13, and some of the implications for archaeology and geosciences ranging from the recent past to the time of the extinction of the Neanderthals.

Beschreibung: The concentration of radiocarbon (14C) differs between ocean and atmosphere. Radiocarbon determinations from samples which obtained their 14C in the marine environment therefore need a marine-specific calibration curve and cannot be calibrated directly against the atmospheric-based IntCal20 curve. This paper presents Marine20, an update to the internationally agreed marine radiocarbon age calibration curve that provides a non-polar global-average marine record of radiocarbon from 0–55 cal kBP and serves as a baseline for regional oceanic variation. Marine20 is intended for calibration of marine radiocarbon samples from non-polar regions; it is not suitable for calibration in polar regions where variability in sea ice extent, ocean upwelling and air-sea gas exchange may have caused larger changes to concentrations of marine radiocarbon. The Marine20 curve is based upon 500 simulations with an ocean/atmosphere/biosphere box-model of the global carbon cycle that has been forced by posterior realizations of our Northern Hemispheric atmospheric IntCal20 14C curve and reconstructed changes in CO2 obtained from ice core data. These forcings enable us to incorporate carbon cycle dynamics and temporal changes in the atmospheric 14C level. The box-model simulations of the global-average marine radiocarbon reservoir age are similar to those of a more complex three-dimensional ocean general circulation model. However, simplicity and speed of the box model allow us to use a Monte Carlo approach to rigorously propagate the uncertainty in both the historic concentration of atmospheric 14C and other key parameters of the carbon cycle through to our final Marine20 calibration curve. This robust propagation of uncertainty is fundamental to providing reliable precision for the radiocarbon age calibration of marine based samples. We make a first step towards deconvolving the contributions of different processes to the total uncertainty; discuss the main differences of Marine20 from the previous age calibration curve Marine13; and identify the limitations of our approach together with key areas for further work. The updated values for ΔR, the regional marine radiocarbon reservoir age corrections required to calibrate against Marine20, can be found at the data base http://calib.org/marine/.

Beschreibung: Ice cores are exceptional archives which allow us to reconstruct a wealth of climatic parameters as well as past atmospheric composition over the last 800 kyr in Antarctica. Inferring the variations in past accumulation rate in polar regions is essential both for documenting past climate and for ice core chronology. On the East Antarctic Plateau, the accumulation rate is so small that annual layers cannot be identified and accumulation rate is mainly deduced from the water isotopic composition assuming constant temporal relationships between temperature, water isotopic composition and accumulation rate. Such an assumption leads to large uncertainties on the reconstructed past accumulation rate. Here, we use high-resolution beryllium-10 (10Be) as an alternative tool for inferring past accumulation rate for the EPICA Dome C ice core, in East Antarctica. We present a high-resolution 10Be record covering a full climatic cycle over the period 269 to 355 ka from Marine Isotope Stage (MIS) 9 to 10, including a period warmer than pre-industrial (MIS 9.3 optimum). After correcting 10Be for the estimated effect of the palaeo-magnetic field, we deduce that the 10Be reconstruction is in reasonably good agreement with EDC3 values for the full cycle except for the period warmer than present. For the latter, the accumulation is up to 13% larger (4.46cmieyr−1 instead of 3.95). This result is in agreement with the studies suggesting an underestimation of the deuterium-based accumulation for the optimum of the Holocene (Parrenin et al., 2007a). Using the relationship between accumulation rate and surface temperature from the saturation vapour relationship, the 10Be-based accumulation rate reconstruction suggests that the temperature increase between the MIS 9.3 optimum and present day may be 2.4 K warmer than estimated by the water isotopes reconstruction. We compare these reconstructions to the available model results from CMIP5-PMIP3 for a glacial and an interglacial state, i.e. for the Last Glacial Maximum and pre-industrial climates. While 3 out of 7 models show relatively good agreement with the reconstructions of the accumulation–temperature relationships based on 10Be and water isotopes, the other models either underestimate or overestimate it, resulting in a range of model results much larger than the range of the reconstructions. Indeed, the models can encounter some difficulties in simulating precipitation changes linked with temperature or water isotope content on the East Antarctic Plateau during glacial–interglacial transition and need to be improved in the future.