Description: There has been a steady increase in interest in mining of deep-sea minerals in the Clarion–Clipperton Zone (CCZ) in the eastern Pacific Ocean during the last decade. This region is known to be one of the most eddy-rich regions in the world ocean. Typically, mesoscale eddies are generated by intense wind bursts channeled through gaps in the Sierra Madre mountains in Central America. Here, we use a combination of satellite and in situ observations to evaluate the relationship between deep-sea current variability in the region of potential future mining and eddy kinetic energy (EKE) in the vicinity of gap winds. A geometry-based eddy detection algorithm has been applied to altimetry sea surface height data for a period of 24 years, from 1993 to 2016, in order to analyze the main characteristic parameters and the spatiotemporal variability of mesoscale eddies in the northeast tropical Pacific Ocean (NETP). Significant differences between the characteristics of eddies with different polarity (cyclonic vs. anticyclonic) were found. For eddies with lifetimes longer than 1 d, cyclonic polarity is more common than anticyclonic rotation. However, anticyclonic eddies are larger in size, show stronger vorticity, and survive longer in the ocean than cyclonic eddies (often 90 d or more). Besides the polarity of eddies, the location of eddy formation should be taken into consideration when investigating the impacted deep-ocean region as we found eddies originating from the Tehuantepec (TT) gap winds lasting longer in the ocean and traveling farther distances in a different direction compared to eddies produced by the Papagayo (PP) gap winds. Long-lived anticyclonic eddies generated by the TT gap winds are observed to travel distances up to 4500 km offshore, i.e., as far as west of 110∘ W. EKE anomalies observed in the surface of the central ocean at distances of ca. 2500 km from the coast correlate with the seasonal variability of EKE in the region of the TT gap winds with a time lag of 5–6 months. A significant seasonal variability of deep-ocean current velocities at water depths of 4100 m was observed in multiple-year time series data, likely reflecting the energy transfer of the surface EKE generated by the gap winds to the deep ocean. Furthermore, the influence of mesoscale eddies on deep-ocean currents is examined by analyzing the deep-ocean current measurements when an anticyclonic eddy crosses the study region. Our findings suggest that despite the significant modulation of dominant current directions driven by the bottom-reaching eddy, the current magnitude intensification was not strong enough to trigger local sediment resuspension in this region. A better insight into the annual variability of ocean surface mesoscale activity in the CCZ and its effects on deep-ocean current variability can be of great help to mitigate the impact of future potential deep-sea mining activities on the benthic ecosystem. On an interannual scale, a significant relationship between cyclonic eddy characteristics and El Niño–Southern Oscillation (ENSO) was found, whereas a weaker correlation was detected for anticyclonic eddies.

Description: The migration of methane through the gas hydrate stability zone (GHSZ) in the marine subsurface is characterized by highly dynamic reactive transport processes coupled to thermodynamic phase transitions between solid gas hydrates, free methane gas, and dissolved methane in the aqueous phase. The marine subsurface is essentially a water-saturated porous medium where the thermodynamic instability of the hydrate phase can cause free gas pockets to appear and disappear locally, causing the model to degenerate. This poses serious convergence issues for the general-purpose nonlinear solvers (e.g., standard Newton), and often leads to extremely small time-step sizes. The convergence problem is particularly severe when the rate of hydrate phase change is much lower than the rate of gas dissolution. In order to overcome this numerical challenge, we have developed an all-at-once Newton scheme tailored to our gas hydrate model, which can handle rate-based hydrate phase change coupled with equilibrium gas dissolution in a mathematically consistent and robust manner.

Description: The exchange of CH4 by CO2 in gas hydrates is of interest for the production of natural gas from methane hydrate with net zero climate gas balance, and for managing risks that are related to sediment destabilization and mobilization after gas-hydrate dissociation. Several experimental studies on the dynamics and efficiency of the process exist, but the results seem to be partly inconsistent. We used confocal Raman spectroscopy to map an area of several tens to hundreds µm of a CH4 hydrate sample during its exposure to liquid and gaseous CO2. On this scale, we could identify and follow different processes in the sample that occur in parallel. Next to guest-molecule exchange, gas-hydrate dissociation also contributes to the release of CH4. During our examination period, about 50% of the CO2 was bound by exchange for CH4 molecules, while the other half was bound by new formation of CO2 hydrates. We evaluated single gas-hydrate grains with confirmed gas exchange and applied a diffusion equation to quantify the process. Obtained diffusion coefficients are in the range of 10−13–10−18 m2/s. We propose to use this analytical diffusion equation for a simple and robust modeling of CH4 production by guest-molecule exchange and to combine it with an additional term for gas-hydrate dissociation.

Description: Seafloor heat flow measurements are utilized to determine the geothermal regime of the Danube deep-sea fan in the western Black Sea and are presented in the larger context of regional gas hydrate occurrences. Heat flow data were collected across paleo-channels in water depths of 550–1460 m. Heat flow across levees ranges from 25 to 30 mW m−2 but is up to 65 mW m−2 on channel floors. Gravity coring reveals sediment layers typical of the western Black Sea, consisting of three late Pleistocene to Holocene units, notably red clay within the lowermost unit cored. Heat flow derived from the bottom-simulating reflector (BSR), assumed to represent the base of the gas hydrate stability zone (GHSZ), deviates from seafloor measurements. These discrepancies are linked either to fast sedimentation or slumping and associated variations in sediment physical properties. Topographic effects account of up to 50% of heat flow deviations from average values. Combined with climate-induced variations in seafloor temperature and sea-level since the last glacial maximum large uncertainties in the prediction of the base of the GHSZ remain. A regional representative heat flow value is ~30 mW m−2 for the study region but deviations from this value may be up to 100%.

Description: Using observational data, satellite altimeters, and reanalysis model products, we have investigated eddy-induced seawater anomalies and heat and salt transport in the northeastern tropical Pacific Ocean. An eddy detection algorithm (EDA) was used to identify eddy formation at the Mexican Tehuantepec Gulf (TT) in July 2018 during an unusually strong summer wind event. The eddy separated from the coast with a mean translation velocity of 11 cm s−1 and a mean radius of 115 km and traveled 2050–2400 km westwards off the Central American coast, where it was followed at approx 114∘ W and 11∘ N for oceanographic observation between April and May 2019. The in situ observations show that the major eddy impacts are restricted to the upper 300 m of the water column and are traceable down to 1500 m water depth. In the eddy core at 92 m water depth an extreme positive temperature anomaly of 8.2 ∘C, a negative salinity anomaly of −0.78 psu, a positive fluorescence anomaly of +0.8 mg m−3, and a positive dissolved oxygen concentration anomaly of 137 µmol kg−1 are observed. Compared with annual climatological averages in 2018, the water trapped within the eddy is estimated to transport an average positive westward zonal heat anomaly of 85×1012 W and an average westward negative salt anomaly of  kg s−1. The heat transport is the equivalent of 1 % of the total annual zonal eddy-induced heat transport at this latitude in the Pacific Ocean. Understanding the dynamics of long-lived mesoscale eddies that may reach the seafloor in this region of the Pacific Ocean is especially important in light of potential deep-sea mining activities that are being targeted on this area.