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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 100 (1994), S. 1946-1952 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Laser induced fluorescence probing of the nitric oxide fragment determines the distribution of rotational and vibrational energies of NO produced in the 226 and 280 nm photolysis of nitrobenzene. Combining these results with kinetic energy measurements using vacuum ultraviolet photoionization to detect the fragment gives a detailed view of the energy release in the photolysis. Boltzmann distributions describe the rotational state populations at both photolysis wavelengths. The rotational temperature of NO from the 226 nm photolysis is (3700±350) K, corresponding to an average rotational energy of (0.32±0.03) eV, and that of NO from the 280 nm photolysis is (2400±200) K, corresponding to an average rotational energy of (0.20±0.03) eV. We observe no vibrationally excited NO and place an upper limit of 10% on the fraction of nitric oxide produced in any one vibrationally excited state. Two different limiting models, impulsive energy release and statistical energy redistribution, both correctly predict much more rotational than vibrational excitation, but neither completely describes the observed internal and kinetic energies. The impulsive model finds more NO rotational and translational energy, but much less phenoxy fragment internal energy than we observe. The statistical model does better for the NO rotation and phenoxy fragment internal energy, but underestimates the translational energy substantially. A combination of these two types of behavior provides a physical picture that qualitatively explains our observations. It is likely that statistical energy redistribution occurs during the approach to the transition state for isomerization of nitrobenzene to phenyl nitrite and impulsive energy release dominates during the subsequent rupture of the CO–NO bond.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2012-05-26
    Description: Modeling sub-canopy elevation is an important step in the processing of waveform lidar data to measure three dimensional forest structure. Here, we present a methodology based on high resolution discrete-return lidar (DRL) to correct the ground elevation derived from large-footprint Laser Vegetation Imaging Sensor (LVIS) and to improve measurement of forest structure. We use data acquired over Barro Colorado Island, Panama by LVIS large-footprint lidar (LFL) in 1998 and DRL in 2009. The study found an average vertical difference of 28.7 cm between 98,040 LVIS last-return points and the discrete-return lidar ground surface across the island. The majority (82.3%) of all LVIS points matched discrete return elevations to 2 m or less. Using a multi-step process, the LVIS last-return data is filtered using an iterative approach, expanding window filter to identify outlier points which are not part of the ground surface, as well as applying vertical corrections based on terrain slope within the individual LVIS footprints. The results of the experiment demonstrate that LFL ground surfaces can be effectively filtered using methods adapted from discrete-return lidar point filtering, reducing the average vertical error by 15 cm and reducing the variance in LVIS last-return data by 70 cm. The filters also reduced the largest vertical estimations caused by sensor saturation in the upper reaches of the forest canopy by 14.35 m, which improve forest canopy structure measurement by increasing accuracy in the sub-canopy digital elevation model.
    Electronic ISSN: 2072-4292
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Published by MDPI Publishing
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