In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 37, No. 10 ( 1982-10-1), p. 1289-1293
Abstract:
The phosphinothioformimidato complex (1) crystallizes triclinic in the space group P1̄ with lattice constants a = 989.4(9) pm, b - 1042.0(8) pm, c = 1088.5(8) pm, α = 91.45(4)°, β = 97.10(4)°, γ = 100.53(5)°. The four-membered chelate ring is folded over the P-S edge by a dihedral angle of 167.1°. The crystal system of the thiophosphoryl thioformimidato complex (2) is monoclinic with the space group P2 1 /c, and the lattice parameters are a = 1109.5(3) pm, b = 966.0(3) pm, c = 2256.7(3) pm, β=103.11(2)°. The chelate ligand is linked to the metal by two S atoms forming a five-membered ring in the “envelope” conformation with the thiophosphoryl S atom at the apical position.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1982-1013
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1982
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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