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  • 1995-1999  (1)
  • 1980-1984  (1)
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  • 1
    ISSN: 1573-0417
    Keywords: diatoms ; temperature ; sediment traps ; seasonal succession ; resuspension ; Lake Holzmaar
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The seasonal sedimentation pattern of diatom valves in Lake Holzmaar was investigated during 1995 by deploying sediment traps at three different lake depths. According to the sedimentation pattern, the major reproduction zone of diatoms was restricted to the upper 6 m of the water body. The population growth started late in April and blooms of Cyclotella cf. comensis Grun., which dominates the plankton diatoms, and Fragilaria crotonensis Kitton were collected in traps during June and September, and July, respectively. During summer, the seasonal sedimentation pattern of each taxon, as collected in the upper traps, was reflected in the concentrations in the lowest trap. However, in May and from September onwards, the community composition in the lowest trap and augmented trapping rates suggest both sediment focusing and resuspension of bottom sediments. The temperature signals as recorded by δ18O values of diatom valves should, therefore, reflect integrated temperatures between 0 and 6 m depth. However, temperatures during summer and autumn are expected to be accentuated in the sedimentary record since the isotopic signal is weighted by both the number and the weight-mass of the valves. During summer, the transfer of these signals by the sedimenting diatoms retains the information pattern recorded, while in spring and autumn/winter additional influxes caused by resuspension may somewhat alter those temperature informations. The proxy signals finally stored in the sediments, may, therefore, not precisely represent the successive temperatures currently recorded during 1995 within mid-lake.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The kinetics of the cationic polymerization of trioxane initiated by perchloric acid is analyzed as a simultaneous polymerization and crystallization process. The details of the crystal growth such as nucleation, distribution of crystal sizes, development of growth spirals etc. have been investigated by electron and light microscopic techniques. The mechanism of polymerization can be understood as a catalyzed crystal growth. A well defined population of crystals is formed during a nucleation event at the start of the polymerization. An adsorption equilibrium with regard to the catalyst is then established in the presence of the rather large surface area of the growing polymer crystals. Assuming a Langmuir-type adsorption behaviour, the observed growth features (growth spirals) can be quantitatively interpreted on the basis of the BCF-theory of crystal growth. The current concepts on the molecular mechanism of cationic polymerization of cyclic formals have been modified such as to take into account that each chemical step of the polymerization is a building step of the crystal too.
    Additional Material: 24 Ill.
    Type of Medium: Electronic Resource
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