Beschreibung: Condensed pelagic deposits characterize the uppermost sediment sequence of the Maud Rise in the eastern Weddell Sea. The comparison of subbottom profiling data with the sediments drilled at two ODP sites shows that Lithologic Unit Ib deposited during late Miocene to late Pliocene times is generally characterized by acoustic transparency. A prominent reflector with strongly increased amplitude (called Reflector “Pc”) occurs within this mainly homogeneous diatom ooze unit and is correlated with the porcellanite horizon found at ODP Site 689. As evidenced by sediment findings, Reflector “Pc” marks a distinct stratigraphic layer of early Pliocene age. The development of the Reflector “Pc” and its amplitude of reflection in the echosounding records is most likely caused by the silica cementation of porcellanite within this layer. The analyses of the sediment echosounder profiles from five R.V. Polarstern cruises make it possible to map the regional distribution of Reflector “Pc”. In large areas of the central Maud Rise, a patchy but also continuous distribution of Reflector “Pc” was found. The reflector does not occur in sediments below 3000 meters of water. On average Reflector “Pc” is detected around 11 and 12 meters below seafloor, but depth occurrence is highly variable within the range of 8 m to more than 18 m. The apparent amplitude of Reflector “Pc” is higher in those areas where the diatom ooze Unit Ib reaches greater thicknesses, which may be caused by local enhanced tectonic subsidence. In general a good correlation of Reflector “Pc” amplitude and thickness of lithologic Unit Ib is observed. This may imply that the diatom ooze Unit Ib serves as a silica source, since the extent of silica cementation of the porcellanite layer is controlled by the amount of dissolved silica supply. Other possible interpretations for silica sources include silica-rich interstitial water ascending from deeper sediment levels using tectonic structures for migration.

Beschreibung: A porcellanite layer, probably younger than 0.6-0.4 Ma, of a nearly monomineralic composition of opal-CT was sampled on the Southwest Indian Ridge during Polarstern cruise ANT-VI/3. The intense cementation of the rock, together with recent findings by the Ocean Drilling Program (Legs 113 and 120) and the occurrence of a unique older porcellanite from Eltanin Core 47-15, provides evidence of very early silica precipitation in pure diatom oozes of the Southern Ocean. Such porcellanites occur in shallowly buried young sediments and provide a contrast to the established concepts of porcellanite formation.