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  • 1
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Analytical chemistry 63 (1991), S. 1755-1759 
    ISSN: 1520-6882
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Biochemistry 33 (1994), S. 13769-13774 
    ISSN: 1520-4995
    Quelle: ACS Legacy Archives
    Thema: Biologie , Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Time domain tunable diode laser absorption spectroscopy has been used to measure rotationally resolved transient absorption line shapes and nascent rotational populations for CO2 molecules excited into the (0111) vibrational state by collisions with translationally hot hydrogen atoms. The even rotational levels are more heavily populated than the odd levels, in agreement with propensity rules derived earlier by Alexander and Clary. The nascent populations and transient linewidths are interpreted in terms of a theoretical model that lends insight into the H–CO2 collision dynamics. The cross section for exciting (0111) is ∼0.23 times the cross section for exciting (0001), and ∼0.38 times the cross section for exciting (1000).
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    ISSN: 1520-5010
    Quelle: ACS Legacy Archives
    Thema: Medizin
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Journal of the American Chemical Society 113 (1991), S. 7104-7109 
    ISSN: 1520-5126
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 11 (1991), S. 103-128 
    ISSN: 1572-8986
    Schlagwort(e): RF plasma torch ; injection probe ; modeling
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Flow, temperature, and electromagnetic (EM) fields in a radio-frequency thermal plasma torch designed for the preparation of superconducting powders or films have been analysed by using a new two-dimensional modeling approach with the electric field intensity as the fundamental EM field variable. The insertion of a stainless steel injection tube into the torch leads to large induction currents in this tube. Although such large induction currents cause pronounced changes of the EM fields near the injection tube, flow and temperature fields are little affected. There exists only one large toroidal vortex in the upper part of the present torch, while the maximum temperature appears at an off-axis location within the coil region.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 11 (1991), S. 151-168 
    ISSN: 1572-8986
    Schlagwort(e): Drag force on a sphere ; thermal plasma flow ; experiments
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Experimental data are presented concerning the drag force on a stationary phere exposed to an argon plasma flow with temperatures about 104 K and velocities about 102 m/s. A novel probe construction has been employed in the drag measurements in order to exclude the effect of the supporting wire on the sphere drag data. By using the new probe construction with a compensating wire, drag forces on an individual steel sphere in the plasma flow have been measured and compared with those obtained by using the probe construction ernployed by a few previous authors. Experimental results show that the measured drag forces are always less than their counterparts obtained from the standard sphere-drag curve under isothermal flow conditions with the same Reynolds numbers based on the oncoming plasma properties. The drag force on a sphere increases only slightly with the increasing surface temperature of the sphere before it melts. Appreciable diference was found between the experimental data and the predicted results of the available expressions for drag on a sphere exposed to a thermal plasma flow. Further research effort is required to build a more suitable drag correlation.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 11 (1991), S. 229-249 
    ISSN: 1572-8986
    Schlagwort(e): Thermal plasma reactor ; counterflow ; modeling
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Modeling of a counterflow plasma reactor is presented, using liquid injection for the synthesis of fine particles. An experimental reactor has been developed in this laboratory, and feasibility has been demonstrated for synthesizing advanced ceramic powders. The flow field calculations show two major recirculating regions which are of importance for increasing the particles' residence time inside of the reactor. In addition, the temperature within these recirculation zones remains relatively uniform. For simulation, water droplet trajectories have been calculated for droplets produced by an injection probe. It is shown that the droplets in a size range below 50 μm in diameter will follow the streamlines and evaporate completely within a short traveling distance. This finding suggests that this reactor configuration provides a favorable environment for the synthesis of fine particles using liquid precursors.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 12 (1992), S. 345-370 
    ISSN: 1572-8986
    Schlagwort(e): Thermophoresis ; free-molecule regime ; analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Analytical results of the thermophoretic force on a metallic or nonmetallic spherical particle immersed into a rarefied plasma with a heat flux within the plasma are presented for the extreme case of free-molecule regime and thin plasma sheath. It has been shown that the thermophoresis is predominantly caused by atoms at low plasma temperatures with negligible gas ionization, while it is mainly due to ions and electrons at high plasma temperatures with great degree of ionization. The ion flux incident to a particle is constant on the whole sphere surface, while the electron flux to the metallic sphere is dependent on the θ-position with slightly greater value at the fore stagnation point. Consequently, there is a small difference between the metallic and nonmetallic spheres in their θ-distributions of the floating potential on the surface, which causes the thermophoretic force on a nonmetallic sphere to be appreciably greater than that on a metallic sphere at high plasma temperatures. Expressions for the total thermophoretic force on a metallic sphere and its components due to, respectively, atoms, ions, and electrons have been given in a closed form. Calculated results are also presented on the effects of pressure and of electron/heavy-particle temperature ratio. These results can be understood based on the variation of atom, ion, and electron thermal conductivities with the gas pressure, the temperature, and the temperature ratio.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Springer
    Plasma chemistry and plasma processing 14 (1994), S. 163-192 
    ISSN: 1572-8986
    Schlagwort(e): Thermophoresis ; evaporating particle ; free-molecule regime ; analysis
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Technik allgemein
    Notizen: Abstract Analytical results of the thermophoretic force on an evaporating spherical particle immersed in a rarefied plasma with a large temperature gradient are presented for the extreme case of free-molecule regime and thin plasma sheath. It has been shown that the existence of a temperature gradient in the plasma causes a nonuniform distribution of the local heat flux density on the sphere surface with its maximum value at the fore-stagnation point of the sphere, although the total heal flux to the whole particle is independent of the temperature gradient existing in the plasma. This nonuniform-distribution of the local heat flux density causes a nonuniform distribution of the. local evaporated-mass flux and related reaction force around the surface of an evaporating particle, and thus causes an additional force on the particle. Calculated results show that the thermophoretic force on an evaporating particle may substantially exceed that on a nonevaporating one, especially for the case of a metallic particle (with infinite electric conductivity). The effect of evaporation on the thermophoretic force is more pronounced as the evaporation latent heat of the particle material is comparatively low and as high plasma temperatures are involved.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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