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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have applied extended x-ray absorption fine structure (EXAFS) spectroscopy to study the cation distribution in a series of spin-sprayed NiZn-ferrite films, Ni0.15ZnyFe2.85−yO4 (y=0.16, 0.23, 0.40, 0.60). The Ni, Zn, and Fe EXAFS were collected from each sample and analyzed to Fourier transforms. Samples of Ni-ferrite, Zn-ferrite, and magnetite were similarly studied as empirical standards. These standards, together with EXAFS data generated from the theoretical EXAFS FEFF codes, allowed the correlation of features in the Fourier transforms with specific lattice sites in the spinel unit cell. We find that the Ni ions reside mostly on the octahedral (B) sites whereas the Zn ions are predominantly on the tetrahedral (A) sites. The Fe ions reside on both A and B sites in a ratio determined by the ratio of Zn/Fe. The addition of Zn displaces a larger fraction of Fe cations onto the B sites serving to increase the net magnetization. The fraction of A site Ni ions is measured to increase peaking at ≈25% for y=0.6. At higher Zn concentrations (y≥0.5) the lattice experiences local distortions around the Zn sites causing a decrease in the superexchange resulting in a decrease in the net magnetization. © 1996 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 3181-3187 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The aging characteristics of the electrostrictive lead magnesium niobate–lead titanate [(1−x)PMN–xPT] under dc bias field were investigated. It was observed that the amount of aging increases with the PT content for the compositions investigated (x≤0.3). For a fixed composition, the aging rate rises with temperature. It was shown that the aging follows a stretched exponential time law, which is typical for the time-dependent behavior in polar glass and random field systems. In PMN–PT, the dielectric constant shows a much weaker aging than the piezoelectric coefficient, reflecting the importance of the stress coupling of the defect field to the micropolar region during the aging since the polar vector of the microregions can have both 180° and non-180° reorientations while only the non-180° reorientation contributes to the observed piezoelectric effect. Experimental results also reveal that the defect field developed during the aging in these materials under dc bias field is quite different from those in normal ferroelectrics and in Mn-doped PMN and 0.9 PMN–0.1PT. The direction of the defect electric field is opposite to the direction of the original dc bias field, indicating that the defect field is the result of a direct coupling to the external bias field rather than induced by the polar domains. © 1996 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 4822-4824 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The band-gap narrowing effect of GaAs as a function of carbon doping concentration has been measured using photoluminescence (PL) spectroscopy on samples grown by metalorganic chemical-vapor deposition. The range of carbon concentration varies from 3.4×1018 to 1.1×1020 cm−3. The experimental results obtained from PL spectra taking tailing effects into account are in good agreement with recent theoretical calculations. The intensity of PL spectra decreases rapidly when the free-carrier concentration is higher than about 4×1019 cm−3. This phenomenon cannot be explained with only the varying tendency of the minority-electron lifetime of the radiative recombination process, indicating the introduction of additional nonradiative recombination centers in heavily C-doped GaAs. © 1995 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 2770-2776 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The electromechanical response of a polyurethane elastomer was investigated at room temperature and in the temperature range near its glass transition. It was found that the Maxwell stress contribution to the strain response can be significant at temperatures higher than the glass transition temperature. In addition, the material exhibits a very high electrostrictive coefficient Q, about two orders of magnitude higher than that of polyvinylidene fluoride. It was also found that in a polymeric material, the chain segment motions can be divided into those related to the polarization response and those related to the mechanical response and the overlap between the two yields the electromechanical response of the material. In general, the activation energies for different types of motion can be different, resulting in different relaxation times in the dielectric, the elastic compliance, and the electrostrictive data, as observed in the polyurethane elastomer investigated. The experimental results indicate that at the temperatures investigated, the activation energy for the mechanical related segment motions is higher than that of nonmechanical related segment motions. © 1997 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 80 (1996), S. 5503-5505 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Plane wave propagation at the composite–medium interface is analyzed for the piezoceramic polymer composites with laminated periodic structure. It is found that the input acoustic impedance of the composite depends on the elastic properties of the medium at the interface and in general is a complex number and dispersive. It is also found that the reflected wave from the medium–composite interface suffers a more than 180° phase change, which implies that the thickness of the conventional antireflection "quarter wave matching layer'' at the interface should be less than a quarter wave length. © 1996 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 2549-2555 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The electromechanical and dielectric responses of ferroelectric materials near paraelectric–ferroelectric (PF) phase transitions are examined both experimentally and theoretically. It is shown that the type of PF transition, i.e., first order and continuous transitions, and diffused phase transition found in relaxor ferroelectrics, has marked effect on the electromechanical and dielectric response behavior for materials under electric field bias. It is demonstrated that an exceptionally large piezoelectric and electromechanical response can be achieved in materials with a first order PF transition. For example, in Ba1−xSrxTiO3 (x∼0.35) ceramics at room temperature, a piezoelectric d33 larger than 1500 pm/V with very little frequency dispersion can be obtained. © 1995 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 69 (1998), S. 2939-2947 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: This article discusses the design and construction of guarded hot plate instruments for measuring the heat flow through an evacuated space between plane-parallel glass surfaces. In this structure, the insulating region is surrounded by two pieces of relatively highly conducting material. High resolution measurements of heat flow using these instruments therefore requires the detection of quite small temperature differences (10−4 K) between the metering piece and the guard. The instruments are calibrated, and the linearity evaluated, by measuring radiative heat transfer through the evacuated space between uncoated soda lime glass sheets; this is because this heat flow can be calculated to high accuracy from the infrared optical properties of the glass. The level of parasitic heat flow in the instruments is estimated by measuring radiative heat flow between glass surfaces coated with very low emittance layers, such as evaporated gold. These instruments operate over a range of temperatures from 0 to about 70 °C. It is shown that the heat flow between evacuated glass surfaces can be measured with these instruments to high resolution (∼10 μW) and high accuracy (∼1%) over an area of ∼1 cm2. The departures from linearity, and the level of parasitic heat flow, are within the measurement resolution. For a temperature difference across the sample of 20 K, the measurement resolution corresponds to an uncertainty in the thermal conductance of the sample of ∼0.005 W m−2 K−1. © 1998 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 1662-1669 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Lead zirconate titanate (PZT) thin films on platinized silicon were fabricated and their structural development upon annealing was characterized by x-ray diffraction and transmission electron microscopy (TEM). The amount of a transient intermetallic phase Pt3Pb was found initially to increase with annealing time and to decay after reaching a maximum. The kinetic process of growth and decay was simulated by using the Avrami equation. The Avrami coefficient n and growth rate constant k were determined by comparing the experimental results and the simulated curves, from which activation energies of 40 and 145 kJ/mol were obtained for the growth and decay of the intermetallic Pt3Pb phase, respectively. The perovskite PZT was found by using TEM to nucleate epitaxially on top of the Pt3Pb phase. Evidence is presented that the Pt3Pb phase plays a major role in determining the crystallite's orientation at the nucleation stage of the perovskite PZT. This depends strongly on the annealing temperature and the orientation changes little during the following growth process. © 1999 American Institute of Physics.
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  • 9
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A dilatometer based on the cantilever beam concept has been developed. The dilatometer is easy to use and capable of measuring transverse strain response of soft polymer films in a broad strain range (from 10−7 to 10−1) without mechanical constraining of the sample. It is capable of detecting strain over a relatively wide frequency range from mHz to above 100 Hz under different load and temperature. Using the setup, the electric field induced transverse strains of the electrostrictive poly(vinylidene fluoride-trifluoroethylene) copolymer films were characterized which shows that a large transverse strain can be achieved in this class of polymer. In addition, the effect of mechanical tensile load on the transverse strain was also evaluated and the results show that the strain response will be affected by the load. However, depending on the load level, the strain response of the polymer film under a given electric field may increase or decrease with load. Based on the phenomenological theory, it is shown that for a ferroelectric based material, the mechanical load will shift the Curie temperature. Hence, to a large extent, the change of the strain response with load observed here can be understood by linking it to the strain change with temperature. © 1999 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 86 (1999), S. 4871-4875 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Results from x-ray photoelectron spectroscopy (XPS) measurements of molybdenum-containing carbon films (Mo–C:H) deposited using an electron cyclotron resonance chemical vapor deposition (ECR-CVD) system are reported in this article. The Mo–C:H films were deposited using a technique with two Mo screen grids incorporated inside the ECR-CVD chamber. The versatility of this technique arises from the ability to control the degree of plasma ionization, sputtering rate of the metal grids, and energy of the impinging ions. Variation of the (CH4/Ar) gas flow ratio results in a change of the Mo fraction within the range of 0.32–15.11 at. %. For large amounts of Mo, the C 1s peak was split into four components with binding energies of 283.05, 284.67, 286.22, and 288.17 eV. These were identified as carbidic (metallic), polymeric, and oxidic (single- and double-bond) carbon, respectively. The presence of oxygen was detected in the films, due possibly to free-radical absorption at the film surface during deposition, or oxidation of the metallic Mo at the surface upon exposure to atmosphere. The results showed that the ECR-CVD technique is useful and effective for the deposition of Mo–C:H films with low- and high-Mo content. © 1999 American Institute of Physics.
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