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  • 1995-1999  (2)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 227 (1998), S. 19-22 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A microwave acid digestion method prior to the determination of210Pb and210Po in sediments and soils is described. It involves an acid (HNO3, HCl, HF and H3BO3 mixture) digestion with microwave heating in closed vessels at high pressures. Analyses carried out for various reference materials showed that the results were statistically equal to certified values and reproducibility was also assured. The advantage of the microwave technique compared to the traditional leaching procedures is that the solid materials are completely dissolved and, therefore, ca. 100% efficiency is achieved in the extraction of210Po and210Pb, even though a fraction is associated to the silica net. Moreover, time of analysis is drastically reduced, as are the risks associated to vapour inhalation and material corrosion.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-2932
    Keywords: Lake Redó ; lake sediments ; lead ; metal pollution ; mining ; 210Pb-dating ; Pyrenees ; stable Pb isotopes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Variations in Pb concentration in lake sediments reflect changes in the fluxes of this element in the past. A sediment core from a lake in the Pyrenees (Lake Redó at 2,240 m a.s.l., NE Spain) was studied, with the aim of reconstructing past environmental and climatic conditions in the lake and its catchment area. The core was dated using both 210Pb and 14C. A surface peak of Pb concentration, which was about 10 times higher than the background level, was found. This peak is attributed to mining activities since the beginning of this century. Although Pb pollution due to the combustion of gasoline is expected to be present, no evidence can be deduced from Pb isotope ratios of sediment due to the masking effect of Pb from mines. A second peak appeared in a deeper layer, with a maximum Pb concentration of about 17 times higher than the background level. The origin of this peak is unclear. All evidence suggests that the ancient peak is due to mining operations in the central Pyrenees area, which were not documented historically.
    Type of Medium: Electronic Resource
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