Description: Integrated Ocean Drilling Program Expedition 311 is based on extensive site survey data and historic research at the northern Cascadia margin since 1985. This research includes various regional geophysical surveys using a broad spectrum of seismic techniques, coring and logging by the Ocean Drilling Program Leg 146, heat flow measurements, shallow piston coring, and bottom video observations across a cold-vent field, as well as novel controlled-source electromagnetic and seafloor compliance surveying techniques. The wealth of data available allowed construction of structural cross-sections of the margin, development of models for the formation of gas hydrate in an accretionary prism, and estimation of gas hydrate and free gas concentrations. Expedition 311 established for the first time a transect of drill sites across the northern Cascadia margin to study the evolution of gas hydrate formation over the entire gas hydrate stability field of the accretionary complex. This paper reviews the tectonic framework at the northern Cascadia margin and summarizes the scientific studies that led to the drilling objectives of Expedition 311 Cascadia gas hydrate.

Description: Downhole electrical resistivity measurements can be exploited for gas hydrate concentration estimates. However, to do so requires that several assumptions be made, in particular about in situ pore water salinity and porosity. During Integrated Ocean Drilling Program Expedition 311, electrical resistivity was measured in four boreholes along a transect across the northern Cascadia margin, offshore Vancouver Island, Canada. Logging-while-rilling and conventional wireline logging data of resistivity, density, and neutron-porosity are used together with measurements of porosity and pore water salinity of the recovered core to systematically estimate gas hydrate concentrations at these four sites. Using Ar- chie’s law, empirical parameters a and m are determined from gas hydrate–free zones by means of a Pickett plot. The in situ salinity baseline trend for each site was estimated directly from the measured pore water salinity values, as well as indirectly by calculating the trend using Archie’s law and simultaneously solving for gas hydrate saturation and in situ salinity. Results showed that the in situ salinities at Sites U1325, U1326, and U1329 were well determined from a smooth trend through the highest measured salinity values of the recovered core. Only Site U1327 exhibitsstrongly decreasing pore water salinity, reaching 22‰ at the base of the gas hydrate stability field. This regional low salinity requires special analyses to estimate gas hydrate concentration from resistivity and introduces a large uncertainty. It is suggested that the decreased salinity results largely (90%) from a deeper fresh water source with the remaining freshening being the result of dissociation of pervasive gas hydrate (~3% of the pore space). Considering estimates from density porosity to be the most accurate, gas hydrate saturations average ~9% ± 7% at Site U1326, ~10% ± 7% at Site U1325, and 11% ± 7% at Site U1327 over the entire range of gas hydrate occurrence. No significant gas hydrate is inferred at Site U1329, although small am ounts may be present just above the bottom-simulating reflector. In two localized zones at Site U1326 (60–100 mbsf [meters below seafloor]) and Site U1327 (120–150 mbsf), significantly higher gas hydrate concentrations of 〉30% of the pore space were encountered.

Description: A 1.5 km long, 1 km wide and 70–80 m high carbonate mound was identified on the mid-slope region of the subduction accretionary sedimentary prism offshore Vancouver Island ∼ 3.5 km west of Ocean Drilling Program (ODP) Site 889 and Integrated Ocean Drilling Program (IODP) Site U1327. Seabed-video images show the presence of seafloor carbonate as well as chemosynthetic communities. A high-resolution single channel seismic survey with close line spacing, recording coherent reflectivity down to about 400 m beneath the seafloor, provided acoustic images of this mound and of the gas hydrate bottom-simulating reflector (BSR) beneath it. The mound is interpreted to have developed as a structural topographic high in the hanging wall of a large reverse fault formed at the base of the current seaward slope. The fault zone provides pathways for fluids including gas to migrate to the seafloor where diagenetic carbonate forms and cements the near-surface sediments. To examine the thermal effect of possible upward fluid flow beneath the mound, heat flow at the mound and in the neighbouring region was calculated from the depth of the BSR below the seafloor. These data were combined with heat flow calculated over a broader region from previous multi-channel seismic data. Heat flow within the flattest portion of the surrounding 4 km by 8 km region averages ∼ 74 mW/m2. Taking this value to represent the regional or background heat flow, a simple 2D analytical method was used to calculate theoretical heat flow variations due to topography. Across the mound, most of the variability is explained by topographic effects, including a local 6 mW/m2 negative anomaly over the central mound and a large 20 mW/m2 positive anomaly over the mound steep side slope. However, just south of the mound, there is a 6–7 mW/m2 positive anomaly in a 2-km-long band that has predominantly flat seafloor. Most of this anomaly is probably unrelated to topographic effects, but rather likely due to warm upward fluid flow along faults or fracture zones.

Description: Samples from the bottom of the sea were used in the exact determination of the crystals structures of naturally occurring hydrocarbon hydrates. The hydrates of methane, ethane, and propane had a cubic structure II with hexakaidecahedral and pentagonal dodecahedral cages occupied by the guest molecules.

Description: Amplitude and frequency anomalies associated with lakes and drainage systems were observed in a 3D seismic data set acquired in the Mallik area, Mackenzie Delta, Northwest Territories, Canada. The site is characterized by large gas hydrate deposits inferred from well-log analyses and coring. Regional interpretation of the gas hydrate occurrences is mainly based on seismic amplitude anomalies, such as brightening or blanking of seismic energy. Thus, the scope of this research is to understand the nature of the amplitude behavior in the seismic data. We have therefore analyzed the 3D seismic data to define areas with amplitude reduction due to contamination from lakes and channels and to distinguish them from areas where amplitude blanking may be a geologic signal. We have used the spectral ratio method to define attenuation (Q) over different areas in the 3D volume and subsequently applied Q-compensation to attenuate lateral variations ofdispersive absorption. Underneath larger lakes, seismic amplitude is reduced and the frequency content is reduced to Formula, which is half the original bandwidth. Traces with source-receiver pairs located inside of lakes show an attenuation factor Q of Formula, approximately half of that obtained for source-receiver pairs situated on deep, continuous permafrost outside of lakes. Deeper reflections occasionally identified underneath lakes show low-velocity-related pull-down. The vertical extent of the washout zones is enhanced by acquisition with limited offsets and from processing parameters such as harsh mute functions to reduce noise from surface waves. The strong attenuation and seismic pull-down may indicate the presence of unfrozen water in deeper lakes and unfrozen pore water within the sediments underlying the lakes. Thus, the blanking underneath lakes is not necessarily related to gas migration or other in situ changes in physical properties potentially associated with the presence of gas hydrate.

Description: We present a new three-dimensional (3-D) P-wave velocity model for the upper-crustal structure beneath the Strait of Georgia, southwestern British Columbia based on non-linear tomographic inversion of wide-angle seismic refraction data. Our study, part of the Georgia Basin Geohazards Initiative (GBGI) is primarily aimed at mapping the depth of the Cenozoic sedimentary basin and delineating the near-surface crustal faults associated with recent seismic activities (e.g. M = 4.6 in 1997 and M = 5.0 in 1975) in the region. Joint inversion of first-arrival traveltimes from the 1998 Seismic Hazards Investigation in Puget Sound (SHIPS) and the 2002 Georgia Basin experiment provides a high-resolution velocity model of the subsurface to a depth of ???7 km. In the southcentral Georgia Basin, sedimentary rocks of the Cretaceous Nanaimo Group and early Tertiary rocks have seismic velocities between 3.0 and 5.5 km s-1. The basin thickness increases from north to south with a maximum thickness of 7 (??1) km (depth to velocities of 5.5 km s-1) at the southeast end of the strait. The underlying basement rocks, probably representing the Wrangellia terrane, have velocities of 5.5-6.5 km-1 with considerable lateral variation. Our tomographic model reveals that the Strait of Georgia is underlain by a fault-bounded block within the central Georgia Basin. It also shows a correlation between microearthquakes and areas of rapid change in basin thickness. The 1997/1975 earthquakes are located near a northeast-trending hinge line where the thicknesses of sedimentary rocks increase rapidly to the southeast. Given its association with instrumentally recorded, moderate sized earthquakes, we infer that the hinge region is cored by an active fault that we informally name the Gabriola Island fault. A northwest-trending, southwest dipping velocity discontinuity along the eastern side of Vancouver Island correlates spatially with the surface expression of the Outer Island fault. The Outer Island fault as mapped in our seismic tomography model is a thrust fault that projects directly into the Lummi Island fault, suggesting that they are related structures forming a fault system that is continuous for nearly 90 km. Together, these inferred thrust faults may account for at least a portion of the basement uplift at the San Juan Islands. ?? 2007 The Authors Journal compilation ?? 2007 RAS.

Description: We examine the usefulness of amplitude versus offset (AVO) analysis of bottom-simulating reflections (BSRs) for estimating associated marine gas hydrate and free-gas concentrations. A nonlinear Bayesian inversion is applied to estimate marginal probability distributions (MPDs) of physical parameters at a BSR interface, which are related to overlying gas hydrate and underlying free-gas concentrations via rock physics modeling. The problem is constrained further by prior information and re-parameterization of inversion results. Inversion of BSR AVO data from offshore Vancouver Island, Canada, shows that gas hydrate and free-gas concentrations are, respectively, 0%-23% and 0%-2% of the pore volume, at a 90% credibility level. This result indicates that the data do not provide sufficient information to independently resolve gas hydrate and free-gas concentrations to useful accuracy. The Study is directed primarily at AVO for gas-hydrate-related BSRs, but may have important applicability in testing the degree of constraint of formation characteristics in other AVO studies. The inversion method is applied also to synthetic AVO data generated from Ostrander's gas-sand model. In this case, MPDs sufficiently constrain the relationship between P- and S-wave velocities in the sandstone unit to determine if it is gas-charged. The variable degree of model constraint obtained in this AVO study highlights the need to include rigorous quantitative uncertainty analysis in all AVO studies.

Description: Recently, several countries have conducted projects to explore and develop natural gas hydrate, which is one of the new alternative energy resources for the future. In Korea, a five-year national research project was initiated in 2000. As part of this project, a seismic survey was performed in the East Sea of Korea to quantify the potential magnitude and distribution of natural gas hydrates. Multi-channel seismic data and core samples have been acquired and recovered in the survey area. Analysis of seismic data show clear bottom simulating reflectors (BSRs), seismic blank zones (or wipe-out zones) with velocity pull-up structure, and pock-marks. In this study, we present the results of seismic surveys which indicate the existence of natural gas hydrates in Korean offshore areas. These results will be applied to select areas for coring (or drilling) and detailed exploration such as 2D seismic survey with long offset or 3D seismic in the future.

Description: This paper presents a comprehensive, multidisciplinary study of cold vents associated with near-seafloor gas hydrate. Several cold vents characterized by seismic blank zones have been identified on the northern Cascadia margin near Ocean Drilling Program (ODP) Site 889/890. The most prominent vent site (Bullseye vent) has been the subject of intense geophysical and geochemical studies, including two- and three-dimensional (2D/3D) seismic imaging, heat flow measurements, piston coring with measurements of sediment physical properties and pore-fluid geochemistry, seafloor video observation, and sampling with the unmanned submersible ROPOS. The main seismically derived constraining observations are: (1) blanking increases with seismic frequency, (2) at low frequencies, layers can be traced through the zones, (3) blank zones widen with depth, (4) blank zones are underlain by a bottom simulating reflector (BSR), and (5) no velocity anomalies were detected across the vents. Constraints from piston core and thermal probe analyses are: (1) massive hydrate was recovered just below the seafloor at Bullseye vent, and (2) chemical alteration of sediments was observed by reduced magnetic susceptibility, increased thermal conductivity, and an elevated sulfate/methane interface. Additional constraints are: (1) no thermal anomaly was observed, (2) widespread carbonates and active chemosynthetic communities were found, and (3) elevated levels of methane were detected in the water column above Bullseye vent. We present a model for the seismic blanking at Bullseye vent that honors the constraints from all observations. The cold vents represent channels or networks of filamentous fractures containing hydrate and/or free gas. Free gas can be present within the hydrate stability field only in fractures, which may be coated with hydrate that prevents the inflow of water. The overall concentration of hydrate or gas within the vent must be small, because there was no observable velocity anomaly.

Description: Gas hydrate samples recovered from a cold vent field offshore Vancouver Island were studied in detail both by macroscopic observations and instrumental methods (powder X-ray diffraction method (PXRD), nuclear magnetic resonance (NMR), and Raman spectroscopy). It was found that gas hydrates were massive from 2.64 to 2.94 m below seafloor (mbsf), elongated, nodular and tabular from 4.60 to 4.81 mbsf, and vein-like from 5.48 to 5.68 mbsf, showing a trend of decreasing hydrate content with increasing depth. All samples were determined to be structure I hydrate from PXRD, NMR, and Raman spectroscopies. The hydration numbers were estimated to be 6.1 ± 0.2 on average as determined from the methane distribution over the cage sites from NMR and Raman analytical results. Estimates of conversion levels indicated that ∼78% of the water in the massive samples was hydrate, down to a low value of ∼0.4% for the pore hydrate samples. The results are compared with measurements on synthetic hydrates and samples recovered from below the permafrost on the Mallik site. Differences in methane content and lattice parameters for synthetic and natural samples are relatively minor. Additional work is needed to address the presence of minor gas components and the heterogeneity of natural hydrate samples.