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  • 2010-2014  (2)
  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 12 (2011): Q0AB11, doi:10.1029/2011GC003699.
    Description: We present new olivine-hosted melt inclusion volatile (H2O, CO2, S, Cl, F) and major element data from five historic eruptions of Nyamuragira volcano (1912, 1938, 1948, 1986, 2006). Host-olivine Mg#'s range from 71 to 84, with the exception of the 1912 sample (Mg# = 90). Inclusion compositions extend from alkali basalts to basanite-tephrites. Our results indicate inclusion entrapment over depths ranging from 3 to 5 km, which agree with independent estimates of magma storage depths (3–7 km) based on geophysical methods. Melt compositions derived from the 1986 and 2006 Nyamuragira tephra samples best represent pre-eruptive volatile compositions because these samples contain naturally glassy inclusions that underwent less post-entrapment modification than crystallized inclusions. Volatile concentrations of the 1986 and 2006 samples are as follows: H2O ranged from 0.6 to 1.4 wt %, CO2 from 350 to 1900 ppm, S from 1300 to 2400 ppm, Cl from 720 to 990 ppm, and F from 1500 to 2200 ppm. Based on FeOT and S data, we suggest that Nyamuragira magmas have higher fO2 (〉NNO) than MORB. We estimate the total amount of sulfur dioxide (SO2) released from the 1986 (0.04 Mt) and 2006 (0.06 Mt) Nyamuragira eruptions using the petrologic method, whereby S contents in melt inclusions are scaled to erupted lava volumes. These amounts are significantly less than satellite-based SO2 emissions for the same eruptions (1986 = ∼1 Mt; 2006 = ∼2 Mt). Potential explanations for this observation are: (1) accumulation of a vapor phase within the magmatic system that is only released during eruptions, and/or (2) syn-eruptive gas release from unerupted magma.
    Description: Funding for this work was provided by NSF (grant EAR 0910795 (to SAC) and grant EAR 0646694 (to AMS)), as well as the National Geographic Society (grant 7698-04 (to SAC)).
    Keywords: Effusive volcanism ; Eruption mechanisms ; Excess sulfur ; Melt inclusions ; Volcanic gases
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
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  • 2
    Publication Date: 2011-04-01
    Description: The Taupo Volcanic Zone (TVZ), New Zealand, is the most active region of rhyolitic volcanism on Earth, with 〉50 rhyolitic eruptions and [~]780 km3 of magma erupted in the past 60 k.y. Here we use analyses of quartz-hosted melt inclusions from eight eruptions in the Okataina Volcanic Center (OVC) of the TVZ to constrain magmatic volatile contents, pressures, and temperatures of quartz crystallization, and degassing of H2O, Cl, and minor CO2 from the rhyolitic magmas. The OVC melt inclusions trapped volatile-rich melts with [≤]6 wt% H2O and [≤]0.27 wt% Cl. Our data indicate that vapor-saturated crystallization of quartz occurred at low temperatures (760-805 {degrees}C) over a wide range of pressures (50-200 MPa). For some eruptions, variations in volatiles and major and trace elements provide evidence for simultaneous crystallization and partial loss of H2O, Cl, and CO2 into a vapor phase. Using the combination of melt inclusion and pumice glass volatile contents, we calculate minimum volatile emissions of [~]3 x 1011 to 8 x 1012 kg H2O and [~]7 x 109 to 4 x 1010 kg Cl during the OVC eruptions. We estimate that emissions from the smaller volume ( 100% of the global arc H2O flux and as much as 90% of the global arc Cl flux. These results underscore the importance of individual magmatic provinces in creating large temporal variations in global arc volatile fluxes to Earth's hydrosphere.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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