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  • 2010-2014  (21)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 28 (2013): 307–318, doi:10.1002/palo.20030.
    Description: Antarctic Intermediate Water (AAIW) and Subantarctic Mode Water (SAMW) are the main conduits for the supply of dissolved silicon (silicic acid) from the deep Southern Ocean (SO) to the low-latitude surface ocean and therefore have an important control on low-latitude diatom productivity. Enhanced supply of silicic acid by AAIW (and SAMW) during glacial periods may have enabled tropical diatoms to outcompete carbonate-producing phytoplankton, decreasing the relative export of inorganic to organic carbon to the deep ocean and lowering atmospheric pCO2. This mechanism is known as the “silicic acid leakage hypothesis” (SALH). Here we present records of neodymium and silicon isotopes from the western tropical Atlantic that provide the first direct evidence of increased silicic acid leakage from the Southern Ocean to the tropical Atlantic within AAIW during glacial Marine Isotope Stage 4 (~60–70 ka). This leakage was approximately coeval with enhanced diatom export in the NW Atlantic and across the eastern equatorial Atlantic and provides support for the SALH as a contributor to CO2 drawdown during full glacial development.
    Description: The work is part of a wider project on the MIS 5/4 transition, supervised by S. B. and supported by NERC (UK) grant NE/F002734/1. K.R.H. is funded by National Science Foundation grant MCG-1029986. T.v.d.F. acknowledges funding from the European Commission (IRG 230828).
    Description: 2013-12-27
    Keywords: Silica leakage ; Diatom ; Carbon dioxide ; SAMW ; AAIW
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 28 (2013): 253–262, doi:10.1002/palo.20025.
    Description: Six Ocean Drilling Program (ODP) sites, in the Northwest Atlantic have been used to investigate kinematic and chemical changes in the “Western Boundary Undercurrent” (WBUC) during the development of full glacial conditions across the Marine Isotope Stage 5a/4 boundary (~70,000 years ago). Sortable silt mean grain size inline image measurements are employed to examine changes in near bottom flow speeds, together with carbon isotopes measured in benthic foraminifera and % planktic foraminiferal fragmentation as proxies for changes in water-mass chemistry. A depth transect of cores, spanning 1.8–4.6 km depth, allows changes in both the strength and depth of the WBUC to be constrained across millennial scale events. inline image measurements reveal that the flow speed structure of the WBUC during warm intervals (“interstadials”) was comparable to modern (Holocene) conditions. However, significant differences are observed during cold intervals, with higher relative flow speeds inferred for the shallow component of the WBUC (~2 km depth) during all cold “stadial” intervals (including Heinrich Stadial 6), and a substantial weakening of the deep component (~3–4 km) during full glacial conditions. Our results therefore reveal that the onset of full glacial conditions was associated with a regime shift to a shallower mode of circulation (involving Glacial North Atlantic Intermediate Water) that was quantitatively distinct from preceding cold stadial events. Furthermore, our chemical proxy data show that the physical response of the WBUC during the last glacial inception was probably coupled to basin-wide changes in the water-mass composition of the deep Northwest Atlantic.
    Description: This work was supported by the Natural Environment Research Council (NERC, UK) grants NE/F002734/1, NE/I006370/1 and NE/G004021/1. We also thank the Comer Science and Education Foundation and the Leverhulme Trust for financial support.
    Description: 2013-11-30
    Keywords: Western Boundary Undercurrent ; Abrupt climate change ; North Atlantic ; Glacial ; Ocean circulation
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 28 (2013): 237–252, doi:10.1002/palo.20024.
    Description: The North Atlantic and Norwegian Sea are prominent sinks of atmospheric CO2 today, but their roles in the past remain poorly constrained. In this study, we attempt to use B/Ca and δ11B ratios in the planktonic foraminifera Neogloboquadrina pachyderma (sinistral variety) to reconstruct subsurface water pH and pCO2 changes in the polar North Atlantic during the last deglaciation. Comparison of core-top results with nearby hydrographic data shows that B/Ca in N. pachyderma (s) is mainly controlled by seawater B(OH)4−/HCO3− with a roughly constant partition coefficient of 1.48 ± 0.15 × 10−3 (2σ), and δ11B in this species is offset below δ11B of the borate in seawater by 3.38 ± 0.71‰ (2σ). These values represent our best estimates with the sparse available hydrographic data close to our core-tops. More culturing and sediment trap work is needed to improve our understanding of boron incorporation into N. pachyderma (s). Application of a constant KD of 1.48 × 10−3 to high resolution N. pachyderma (s) B/Ca records from two adjacent cores off Iceland shows that subsurface pCO2 at the habitat depth of N. pachyderma (s) (~50 m) generally followed the atmospheric CO2 trend but with negative offsets of ~10–50 ppmv during 19–10 ka. These B/Ca-based reconstructions are supported by independent estimates from low-resolution δ11B measurements in the same cores. We also calibrate and apply Cd/Ca in N. pachyderma (s) to reconstruct nutrient levels for the same down cores. Like today's North Atlantic, past subsurface pCO2 variability off Iceland was significantly correlated with nutrient changes that might be linked to surface nutrient utilization and mixing within the upper water column. Because surface pCO2 (at 0 m water depth) is always lower than at deeper depths and if the application of a constant KD is valid, our results suggest that the polar North Atlantic has remained a CO2 sink during the calcification seasons of N. pachyderma (s) over the last deglaciation.
    Description: This research is funded by Lamont-Doherty Postdoctoral Fellowship, Lawrence Livermore Fellowship and the Australian National University (J.Y.), by NERC RAPID grant NER/T/S/2002/00436 (N. M. and D. T.), and by a NERC PhD studentship (J.R.).
    Description: 2013-11-30
    Keywords: Neogloboquadrina pachyderma (s) ; B/Ca, Cd/Ca, d11B ; Subsurface pH and pCO2 and nutrients
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Publication Date: 2022-05-25
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Climate of the Past 9 (2013): 2073-2084, doi:10.5194/cp-9-2073-2013.
    Description: The overflow of deep water from the Nordic seas into the North Atlantic plays a critical role in global ocean circulation and climate. Approximately half of this overflow occurs via the Iceland–Scotland (I–S) overflow, yet the history of its strength throughout the Holocene (~ 0–11 700 yr ago, ka) is poorly constrained, with previous studies presenting apparently contradictory evidence regarding its long-term variability. Here, we provide a comprehensive reconstruction of I–S overflow strength throughout the Holocene using sediment grain size data from a depth transect of 13 cores from the Iceland Basin. Our data are consistent with the hypothesis that the main axis of the I–S overflow on the Iceland slope was shallower during the early Holocene, deepening to its present depth by ~ 7 ka. Our results also reveal weaker I–S overflow during the early and late Holocene, with maximum overflow strength occurring at ~ 7 ka, the time of a regional climate thermal maximum. Climate model simulations suggest a shoaling of deep convection in the Nordic seas during the early and late Holocene, consistent with our evidence for weaker I–S overflow during these intervals. Whereas the reduction in I–S overflow strength during the early Holocene likely resulted from melting remnant glacial ice sheets, the decline throughout the last 7000 yr was caused by an orbitally induced increase in the amount of Arctic sea ice entering the Nordic seas. Although the flux of Arctic sea ice to the Nordic seas is expected to decrease throughout the next century, model simulations predict that under high emissions scenarios, competing effects, such as warmer sea surface temperatures in the Nordic seas, will result in reduced deep convection, likely driving a weaker I–S overflow.
    Description: Funding was provided by NERC RAPID grant NER/T/S/2002/00436 to I. N. McCave, and a WHOI OCCI post-doctoral scholarship to D. J. R. Thornalley. Work on EW9302 cores was supported by NSF grant OCE01- 18001 to D. W. Oppo and J. F. McManus. The contributions of J. F. McManus and S. Praetorius were also supported in part by the Comer Research and Education Foundation. M. Blaschek,F. J. Davies and H. Renssen are supported by the European Community’s 7th Framework Programme FP7 2007/2013, Marie-Curie Actions, under Grant Agreement No. 10 238111 CASE ITN.
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 5
    Publication Date: 2023-12-18
    Keywords: Age, 14C AMS; Age, comment; Age, dated; Age, dated standard deviation; Apparent partition coefficient, boron to calcite incorporation x1000; BC; Box corer; CD159; Charles Darwin; Coefficient; Denmark Strait; DEPTH, sediment/rock; East Greenland rise; Eirik Drift; Elevation of event; Event label; GS06-144-15MCA; GS06-144-16MCA; GS06-144-19MCA; Hamilton Spur Margin; Labrador shelf; Latitude of event; Longitude of event; MUC; MultiCorer; Neogloboquadrina pachyderma sinistral, Boron/Calcium ratio; Neogloboquadrina pachyderma sinistral, Cadmium/Calcium ratio; Neogloboquadrina pachyderma sinistral, δ11B; Neogloboquadrina pachyderma sinistral, δ11B standard deviation; Norwegian Sea; Orphan Spur; RAPiD-24-13B; RAPiD-26-14B; RAPiD-28-16B; RAPiD-29-18B; RAPiD-31-21B; RAPiD-32-22B; RAPiD-33-23B; RAPiD-34-24B; RAPiD-35-25B; RAPiD-37-26B; RAPiD-38-27B; RAPiD-39-28B; RAPiD-40-29B; RAPiD-41-30B; δ11B
    Type: Dataset
    Format: text/tab-separated-values, 124 data points
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  • 6
    Publication Date: 2023-12-18
    Keywords: AGE; Alkalinity, total; Carbonate ion; Carbon dioxide, partial pressure; CD159; CD159-10; CD159-15; Charles Darwin; DEPTH, sediment/rock; Event label; Neogloboquadrina pachyderma sinistral, δ11B; Neogloboquadrina pachyderma sinistral, δ11B standard deviation; PC; pH; Piston corer; RAPiD-10-1P; RAPiD-15-4P; Reconstructed; Sea surface salinity; Sea surface temperature, annual mean; South of Iceland
    Type: Dataset
    Format: text/tab-separated-values, 56 data points
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  • 7
    Publication Date: 2023-12-18
    Keywords: 6bis2G; AGE; CALYPSO; Calypso Corer; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; IMAGES V; Marion Dufresne (1995); MD114; MD99-2198; Neodymium-143/Neodymium-144 ratio; Neodymium-143/Neodymium-144 ratio, error; Tobago basin; ε-Neodymium; ε-Neodymium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 78 data points
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  • 8
    Publication Date: 2023-12-18
    Keywords: AGE; Alkalinity, total; Carbonate ion; Carbon dioxide, partial pressure; CD159; CD159-10; Charles Darwin; Coefficient; DEPTH, sediment/rock; Neogloboquadrina pachyderma sinistral, Cadmium/Calcium ratio; PC; pH; Phosphorus, dissolved; Piston corer; RAPiD-10-1P; Reconstructed; Sea surface salinity; Sea surface temperature, annual mean; South of Iceland; Tilia spp.; Δ carbon dioxide, partial pressure
    Type: Dataset
    Format: text/tab-separated-values, 1511 data points
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  • 9
    Publication Date: 2023-12-18
    Keywords: Accumulation rate, mass; Accumulation rate, standard deviation; AGE; DEPTH, sediment/rock; Opal, biogenic silica; PC; Piston corer; RC24; RC24-1; Robert Conrad; Uranium, authigenic; Uranium, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 60 data points
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  • 10
    Publication Date: 2023-12-18
    Keywords: Age, 14C AMS; Age, comment; Age, dated; Age, dated standard deviation; Age model; CD159; CD159-17; Charles Darwin; DEPTH, sediment/rock; PC; Piston corer; RAPiD-17-5P; South of Iceland
    Type: Dataset
    Format: text/tab-separated-values, 22 data points
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