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  • Electronic books.  (4)
  • 2010-2014  (4)
  • 1
    Online-Ressource
    Online-Ressource
    Dordrecht :Springer Netherlands,
    Schlagwort(e): Chromatographic analysis. ; Chemistry, Analytic -- Technique. ; Sustainable development. ; Electronic books.
    Beschreibung / Inhaltsverzeichnis: This book examines counter-current, ion size exclusion, supercritical fluids, high-performance thin layers, and gas and size exclusion chromatographic techniques used to separate and purify organic and inorganic analytes. Includes green prep methods and more.
    Materialart: Online-Ressource
    Seiten: 1 online resource (220 pages)
    Ausgabe: 1st ed.
    ISBN: 9789400777354
    DDC: 543.8
    Sprache: Englisch
    Anmerkung: Intro -- Preface -- Acknowledgements -- Contents -- Contributors -- Chapter-1 -- Saving Solvents in Chromatographic Purifications: The Counter-Current Chromatography Technique -- 1.1 Introduction -- 1.2 CCC Theory -- 1.2.1 High Loadability -- 1.2.2 Scale up Capability -- 1.3 Instrumentation -- 1.3.1 Hydrostatic and Hydrodynamic Instruments -- 1.3.2 Liquid Systems -- 1.4 Counter Current Chromatography, a Green Process -- 1.4.1 Saving Solvents -- 1.4.2 Improving Process Parameters -- 1.4.3 Injecting Crude Samples -- 1.4.4 Greener Solvents -- 1.5 Counter Current Chromatography, a Tool for Green Chemistry Development -- 1.5.1 Natural Products -- 1.5.2 Solute Partition Coefficient Determination -- 1.6 Conclusion -- References -- Chapter-2 -- Ion Size Exclusion Chromatohtaphy on Hypercrosslinked Polystyrene Sorbents as a Green Technology of Separating Mineral Elecyrolites -- 2.1 Introduction -- 2.2 Nanoporous Hypercrosslinked Polystyrene Sorbents -- 2.3 Brief Description of Chromatographic Experiments -- 2.4 Dimensions of Hydrated Ions -- 2.5 Separation of Electrolytes on Nanoporous Hypercrosslinked Sorbents -- 2.6 Basic Features of Size Exclusion Chromatography -- 2.7 Conception of "Ideal Separation Process" -- 2.8 Selectivity of Electrolyte Separation Process -- 2.9 Influence of the Electrolyte Concentration on the Selectivity of Separat -- 2.10 "Acid Retardation", "Base Retardation" and "Salt Retardation" Phenomena -- 2.11 Other Convincing Proofs of Separating Electrolytes via Exclusion Mechanism -- 2.12 Do we Really Need Sorbent Functional Groups to Separate Electrolytes? -- 2.13 Productivity of the Ion Size Exclusion Process -- 2.14 Ion Size Exclusion-Green Technology -- 2.15 Conclusion -- References -- Chapter-3 -- Supercritical Fluid Chromatography: A Green Approach for Separation and Purification of Organic and Inorganic Analytes. , 3.1 Introduction to Green Chemistry and Supercritical Fluid Chromatography -- 3.2 Super Critical Fluids -- 3.2.1 Supercritical Fluid Extraction (SFE) -- 3.3 Supercritical Fluid Chromatography (SFC): An Overview -- 3.3.1 History of Development of Supercritical Fluid Chromatography -- 3.3.2 Instrumentation -- 3.3.2.1 Advantages and Disadvantages of Supercritical Fluid Chromatography -- 3.3.3 Properties of SFC compared to GC and HPLC -- 3.4 Industrial Applications of SCFs and SFCs -- 3.5 Conclusion -- References -- Chapter-4 -- High Performance Thin-Layer Chromatography -- 4.1 Introduction -- 4.2 High Performance Thin-Layer Chromatography -- 4.3 Sample Preparation in HPTLC -- 4.4 Green Separation Modalities in HPTLC -- 4.4.1 "Three R" Philosophy-Replacement of Toxic Solvents with Environmental Friendly Mobi -- 4.4.1.1 Reversed-Phase Chromatography -- 4.4.1.2 Hydrophilic Interaction Chromatography (HILIC) in HPTLC -- 4.4.1.3 Salting-Out Chromatography in HPTLC -- 4.5 Conclusion -- References -- Chapter-5 -- Green Techniques in Gas Chromatography -- 5.1 Introduction -- 5.2 Sample Preparation -- 5.2.1 Direct Methods Without Sample Preparation -- 5.2.2 Solventless Sample Preparation Techniques -- 5.2.2.1 Solid Phase Extraction -- 5.2.2.2 Vapor-Phase Extraction -- 5.2.2.3 Thermal Desorption (TD)/Thermal Extraction (TE) -- 5.2.2.4 Membrane Extraction -- 5.2.3 Sample Preparation Using Environmentally Friendly Solvents -- 5.2.3.1 Supercritical Fluid Extraction (SFE) -- 5.2.3.2 Subcritical Water Extraction (SWE) -- 5.2.3.3 Ionic Liquids (ILs) -- 5.2.3.4 Cloud-Point Extraction -- 5.2.4 Assisted Solvent Extraction -- 5.3 Column Considerations for Green Gas Chromatography -- 5.4 Carrier Gas Considerations for Green Gas Chromatography -- 5.5 Coupling GC with Other Analytical Tools -- 5.6 On-Site Analysis. , 5.7 Conclusion -- References -- Chapter-6 -- Preparation and Purification of Garlic-Derived Organosulfur Compound Allicin by Green Methodologies -- 6.1 Introduction -- 6.2 Green RP-HPLC Purification of the Allicin -- 6.3 Characterization of the Allicin by Green Methodologies -- 6.4 Allicin in Different Garlic Extract by Green RP-HPLC -- 6.5 Allicin Green Chemical Synthesis -- 6.6 Stability of Allicin -- 6.7 Conclusions -- References -- Chapter-7 -- Green Sample Preparation Focusing on Organic Analytes in Complex Matrices -- 7.1 Introduction -- 7.1.1 Trends in Green Analytical Chemistry -- 7.1.2 Green Techniques for Sample Preparation -- 7.1.2.1 Reduction and Solvent Replacement -- Supercritical Fluid Extraction -- Membranes -- 7.1.2.2 Solvent Elimination -- Solid Phase Extraction (SPE) -- Matrix Solid-Phase Dispersion (MSPD) -- Sorptive Extraction Techniques -- Solid Phase Microextraction (SPME) -- Stir-Bar Sorptive Extraction -- 7.2 Conclusions -- References -- Chapter-8 -- Studies Regarding the Optimization of the Solvent Consumption in the Determination of Organochlor -- 8.1 Introduction -- 8.2 Materials and Methods -- 8.2.1 Materials -- 8.2.2 Methods -- 8.3 Results -- 8.4 Discussions -- 8.4.1 TRM1 -- 8.4.2 TRM2 -- 8.5 Conclusions -- References -- Chapter-9 -- Size Exclusion Chromatography a Useful Technique For Speciation Analysis of Polydimethylsiloxanes -- 9.1 Introduction to SEC -- 9.2 SEC Retention Mechanisms -- 9.2.1 Ideal Size Exclusion Mechanism -- 9.2.2 Non-Ideal Size Exclusion Mechanism -- 9.3 The Stationary Phase in SEC -- 9.4 The Mobile Phase in SEC -- 9.5 Analytical Problems -- 9.6 Methods for Column Calibration -- 9.7 Applications of SEC Biomedical and Pharmaceutical -- 9.7.1 SEC as a Useful Technique for Linear Polydimethylsiloxanes Speciation Analysis. , 9.8 Methodology for Linear Polydimethylsiloxanes Speciation Analysis -- 9.8.1 Mobile Phase Selection -- 9.8.2 Stationary Phase Selection -- 9.8.3 Column Conditions -- 9.8.4 Column Calibration -- 9.8.5 Separation of Polydimethylsiloxanes -- 9.9 Conclusions -- References -- Erratum -- Index.
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  • 2
    Online-Ressource
    Online-Ressource
    Dordrecht :Springer Netherlands,
    Schlagwort(e): Solvents. ; Electronic books.
    Beschreibung / Inhaltsverzeichnis: This book offers an overview of types of solvents and discusses their applications in extraction, organic synthesis, biocatalytic processes, production of fine chemicals, biochemical transformations, composite material, energy storage, polymers and more.
    Materialart: Online-Ressource
    Seiten: 1 online resource (517 pages)
    Ausgabe: 1st ed.
    ISBN: 9789400728912
    DDC: 541.3482
    Sprache: Englisch
    Anmerkung: Intro -- Green Solvents II -- Preface -- Editor's Biography -- Acknowledgments -- Contents -- Contributors -- Chapter 1: Ionic Liquids as Green Solvents: Progress and Prospects -- 1.1 Introduction -- 1.2 History of Ionic Liquids (ILs) -- 1.3 Structure of Ionic Liquids (ILs) -- 1.3.1 Cations -- 1.3.2 Anions -- 1.4 Synthesis of Ionic Liquids (ILs) -- 1.4.1 Quaternization Reactions -- 1.4.2 Anion-Exchange Reactions -- 1.4.2.1 Lewis-Acid-Based Ionic Liquids (ILs) -- 1.4.2.2 Anion Metathesis -- 1.5 Properties of Ionic Liquids (ILs) -- 1.5.1 Melting Point -- 1.5.2 Volatility -- 1.5.3 Thermal Stability -- 1.5.4 Viscosity -- 1.5.5 Density -- 1.5.6 Polarity -- 1.5.7 Conductivity and Electrochemical Window -- 1.5.8 Toxicity -- 1.5.9 Air and Moisture Stability -- 1.5.10 Cost and Biodegradability -- 1.6 Solvent Properties and Solvent Effects -- 1.6.1 Solute-Ionic Liquids (ILs) Interactions -- 1.6.1.1 Interaction of Ionic Liquids (ILs) with Water -- 1.6.1.2 Interaction of Ionic Liquids (ILs) with Acid and Base -- 1.6.1.3 Interaction of Ionic Liquids (ILs) with Aromatic Hydrocarbon -- 1.6.1.4 Interaction with Chiral Substrates -- 1.7 Conclusions -- References -- Chapter 2: Ionic Liquids as Green Solvents for Alkylation and Acylation -- 2.1 Introduction -- 2.2 Alkylation -- 2.2.1 Ionic Liquids as Green Solvents -- 2.2.2 Ionic Liquids as Dual Green Solvents and Catalysts -- 2.2.3 Ionic Liquids Immobilized on Solid Supports -- 2.3 Acylation -- 2.3.1 Ionic Liquids as Green Solvents -- 2.3.2 Ionic Liquids in Dual Role as Green Solvents and Catalysts -- 2.3.3 Immobilized Ionic Liquids -- 2.4 Remarks -- References -- Chapter 3: Ionic Liquids as Green Solvents for Glycosylation Reactions -- 3.1 Introduction -- 3.2 Preparation of Acid-Ionic Liquids -- 3.3 Reusability of Acid-Ionic Liquids -- 3.4 Tunability and Basicity of Ionic Liquids. , 3.5 Nonvolatility of Ionic Liquids -- 3.6 Conclusions -- References -- Chapter 4: Ionic Liquid Crystals -- 4.1 Introduction -- 4.2 Ionic Liquid Crystals Based on Organic Cationsand Anions -- 4.2.1 Imidazolium-Based Ionic Liquid Crystals -- 4.2.2 Pyrrolidinium-Based Ionic Liquid Crystals -- 4.2.3 Pyridinium and Bipyridinium-Based IonicLiquid Crystals -- 4.2.4 Morpholinium-, Piperazinium-, and Piperidinium-BasedIonic Liquid Crystals -- 4.2.5 Ammonium-Based Ionic Liquid Crystals -- 4.2.6 Guanidinium-Based Ionic Liquid Crystals -- 4.2.7 Phosphonium-Based Ionic Liquid Crystals -- 4.2.8 Anions -- 4.3 Ionic Liquid Crystals Based on Metal Ions -- 4.4 Polymeric Ionic Liquid Crystals -- 4.4.1 Main-Chain Ionic Liquid-Crystalline Polymers -- 4.4.2 Side-Chain Ionic Liquid-Crystalline Polymers -- 4.4.3 Dendrimers -- 4.5 Applications of Ionic Liquid Crystals -- 4.6 Conclusions -- References -- Chapter 5: Application of Ionic Liquids in Extraction and Separation of Metals -- 5.1 Introduction -- 5.2 Processing Metal Oxides and Ores with Ionic Liquids -- 5.2.1 Metal Oxides Processing -- 5.2.2 Mineral Processing -- 5.3 Electrodeposition of Metals Using Ionic Liquids -- 5.3.1 Electrodeposition of Aluminum -- 5.3.2 Electrodeposition of Magnesium -- 5.3.3 Electrodeposition of Titanium -- 5.4 Ionic Liquids in Solvent Extraction of Metal Ions -- 5.5 Conclusions -- References -- Chapter 6: Potential for Hydrogen Sulfide Removal Using Ionic Liquid Solvents -- 6.1 Introduction -- 6.2 Ionic Liquids as Physical Solvents for H 2 S Removal -- 6.3 Hybrid Solvents Comprising Ionic Liquids and Amines -- 6.4 Conclusions and Outlook -- References -- Chapter 7: Biocatalytic Reactions in Ionic Liquid Media -- 7.1 Introduction -- 7.2 Biocatalyst Tested in Ionic Liquids -- 7.2.1 Lipases -- 7.2.2 Esterases and Proteases -- 7.2.3 Glycosidases -- 7.2.4 Oxidoreductases. , 7.3 Effect of the Ionic Liquid Composition on the Activity and Stability of Enzymes -- 7.4 Biotransformation in Ionic Liquids -- 7.4.1 Synthesis of Flavour Esters -- 7.4.2 Biotransformations of Polysaccharides and Nucleotides -- 7.4.3 Synthesis of Biodiesel -- 7.4.4 Synthesis of Polyesters -- 7.4.5 Resolution of Racemates -- 7.4.6 Synthesis of Carbohydrates -- 7.5 Conclusions -- References -- Chapter 8: Ionic Liquids/Supercritical Carbon Dioxide as Advantageous Biphasic Systems in Enzymatic Synthesis -- 8.1 Introduction -- 8.2 Supercritical Carbon Dioxide in Enzymatic Synthesis -- 8.3 Ionic Liquids as Reaction Media in Enzymatic Synthesis -- 8.4 Supercritical Carbon Dioxide/Ionic Liquid Biphasic System in Enzymatic Synthesis -- 8.5 Conclusions -- References -- Chapter 9: Ionic Liquids as Lubricants -- 9.1 Introduction -- 9.2 Overview of Ionic Liquids (ILs) -- 9.2.1 Definition and Types of Ionic Liquids (ILs) -- 9.2.2 Relationship Between Molecular Structure and Properties of Ionic Liquids (ILs) -- 9.3 Common Ionic Liquids (ILs) as Lubricants -- 9.3.1 Ionic Liquids (ILs) as Lubrication Oils -- 9.3.1.1 Ionic Liquids (ILs) as Lubrication Oils for Fe Alloy/Steel or Steel/Steel Contacts -- 9.3.1.2 Ionic Liquids (ILs) as Lubrication Oils of Light Alloys -- 9.3.1.3 Ionic Liquids (ILs) as Lubrication Oils for Specific Contacts -- 9.3.1.4 Ionic Liquids (ILs) as Lubrication Oils Under Vacuum -- 9.3.2 Ionic Liquids (ILs) as Lubrication Additives -- 9.3.2.1 Ionic Liquids (ILs) as Water Additives -- 9.3.2.2 Ionic Liquids (ILs) as Mineral Oil Additives -- 9.3.2.3 Ionic Liquids (ILs) as Synthetic Oil and Lubrication Grease Additives -- 9.3.2.4 Ionic Liquids (ILs) as Polymer Material Additives -- 9.3.3 Additives of Ionic Liquid (IL) Lubricants -- 9.3.4 Thin Films -- 9.4 Function of Ionic Liquids (ILs) as Lubricants. , 9.4.1 Function of Ionic Liquids (ILs) as Lubrication Oils -- 9.4.2 Function of Ionic Liquids (ILs) as Additives or Thin Films -- 9.5 Lubrication Mechanism -- 9.6 Conclusions and Outlook -- References -- Chapter 10: Stability and Activity of Enzymes in Ionic Liquids -- 10.1 Introduction -- 10.1.1 Ionic Liquid in Reference to Its Origin -- 10.1.2 Ionic Liquid as a Solvent -- 10.1.3 Enzymes in Ionic Liquids -- 10.2 Enzyme Stability in Ionic Liquids -- 10.2.1 Stability of Lipases -- 10.2.2 Stability of Monellin -- 10.2.3 Stability of Cytochrome c -- 10.2.4 Stability of α -Chymotrypsin -- 10.2.5 Stability of Penicillin G Acylase -- 10.3 Methods of Stabilizing Proteins/Enzymes in Ionic Liquids -- 10.3.1 Stabilization by Ionic Liquid Coating -- 10.3.2 Stabilization by Anchoring with Carbon Nanotubes -- 10.3.3 Stabilization by Capping with Nanoparticles -- 10.3.4 Stabilization by Entrapment in Hydrogels -- 10.3.5 Stabilization by Enzyme Modification -- 10.3.6 Stabilization by Emulsification of Ionic Liquids -- 10.4 Catalytic Activity of Enzymes in Ionic Liquids -- 10.4.1 Biotransformations by Lipases and Esterases -- 10.4.1.1 Esterification and Transesterification Reaction -- 10.4.1.2 Enantioselective Hydrolysis Reaction -- 10.4.1.3 Enantioselective Acylation Reaction -- 10.4.1.4 Kinetic Resolution of Alcohols -- 10.4.2 Reactions Catalyzed by Proteases -- 10.4.3 Carbohydrate Synthesis by Glycosidases -- 10.4.4 Hydrocyanation Reaction by Lyases -- 10.4.5 Biocatalytic Redox Reactions by Oxidoreductases -- 10.4.6 Enzymatic Polymerization Reaction in Ionic Liquids -- 10.5 Stability/Activity Vis-à-vis Solvent Property of Ionic Liquids: A Structure-Activity Relationship (SAR) Analysis -- 10.6 Conclusions -- References -- Chapter 11: Supported Ionic Liquid Membranes: Preparation, Stability and Applications -- 11.1 Introduction. , 11.2 Methods of Preparation and Characterization of Supported Ionic Liquid Membranes -- 11.3 Stability of Supported Ionic Liquid Membranes -- 11.4 Mechanism of Transport Through Supported Ionic Liquid Membranes -- 11.5 Fields of Application of Supported Liquid Membranes -- 11.6 Conclusions -- References -- Chapter 12: Application of Ionic Liquids in Multicomponent Reactions -- 12.1 Introduction -- 12.1.1 Ionic Liquids Based on 1-Butyl-3-methylimidazolium -- 12.1.1.1 1-Butyl-3-methylimidazolium -- 12.1.1.2 1-Butyl-3-methylimidazolium Hexafluorophosphate -- 12.1.1.3 1-n-Butyl-3-methylimidazolium Bromide -- 12.1.1.4 Butyl Methyl Imidazolium Hydroxide -- 12.1.1.5 Other 1-Butyl-3-methylimidazolium-Based Ionic Liquids -- 12.1.2 Other Imidazole-Based Ionic Liquids -- 12.1.2.1 Ionic Liquid-Supported Iodoarenes -- 12.1.2.2 1,3- n -Dibutylimidazolium Bromide -- 12.1.2.3 1- n -Butylimidazolium Tetrafluoroborate -- 12.1.2.4 1-Ethyl-3-methylimidazole Acetate -- 12.1.2.5 An Acidic Ionic Liquid -- 12.1.2.6 Task-Specific Ionic Liquids -- 12.1.2.7 1-Methyl-3-heptyl-imidazolium Tetrafluoroborate -- 12.1.2.8 1-[2-(Acetoacetyloxy)ethyl]-3-methylimidazolium Hexafluorophosphate-Bound Acetoacetate -- 12.1.2.9 1-[2-(Acetoacetyloxy)ethyl]-3-methylimidazolium Tetrafluoroborate- or Hexafluorophosphate-Bound b -oxo Esters -- 12.1.2.10 1-(2-Hydroxyethyl)-3-methylimidazolium Tetrafluoroborate or Hexafluorophosphate and N -(2-Hydroxyethyl)pyridinium Tetrafluoroborate or Hexafluorophosphate -- 12.1.2.11 PEG-1000-Based Dicationic Acidic Ionic Liquid -- 12.1.2.12 1-Ethyl-3-methylimidazolium ( S)-2-Pyrrolidinecarboxylic Acid Salt -- 12.1.2.13 1-Methyl-3-pentylimidazolium Bromide -- 12.1.2.14 3-Methyl-1-sulfonic Acid Imidazolium Chloride -- 12.1.3 Other Ionic Liquids -- 12.2 Conclusions -- References. , Chapter 13: Ionic Liquids as Binary Mixtures with Selected Molecular Solvents, Reactivity Characterisation and Molecular-Microscopic Properties.
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  • 3
    Online-Ressource
    Online-Ressource
    Dordrecht :Springer Netherlands,
    Schlagwort(e): Ion exchange. ; Ion exchange. fast. ; Electronic books.
    Beschreibung / Inhaltsverzeichnis: This overview of the industrial applications of ion-exchange materials focuses on their use in a host of fields including chemical and biochemical separation, water purification, biomedical science, toxic metal recovery and manufacturing alcoholic drinks.
    Materialart: Online-Ressource
    Seiten: 1 online resource (462 pages)
    Ausgabe: 1st ed.
    ISBN: 9789400740266
    Sprache: Englisch
    Anmerkung: Intro -- Ion Exchange Technology II -- Preface -- Editors' Bios -- Contents -- Contributors -- List of Abbreviations -- Chapter 1: Separation of Amino Acids, Peptides, and Proteins by Ion Exchange Chromatography -- Chapter 2: Application of Ion Exchanger in the Separation of Whey Proteins and Lactin from Milk Whey -- Chapter 3: Application of Ion Exchangers in Speciation and Fractionation of Elements in Food and Beverages -- Chapter 4: Applications of Ion Exchangers in Alcohol Beverage Industry -- Chapter 5: Use of Ion Exchange Resins in Continuous Chromatography for Sugar Processing -- Chapter 6: Application of Ion Exchange Resins in the Synthesis of Isobutyl Acetate -- Chapter 7: Therapeutic Applications of Ion Exchange Resins -- Chapter 8: Application of Ion Exchange Resins in Kidney Dialysis -- Chapter 9: Zeolites as Inorganic Ion Exchangers for Environmental Applications: An Overview -- Chapter 10: Ion Exchange Materials and Environmental Remediation -- Chapter 11: Metal Recovery, Separation and/or Pre-concentration -- Chapter 12: Application of Ion Exchange Resins in Selective Separation of Cr(III) from Electroplating Effluents -- Chapter 13: Effect of Temperature, Zinc, and Cadmium Ions on the Removal of Cr(VI) from Aqueous Solution via Ion Exchange with Hydrotalcite -- Chapter 14: An Overview of '3d' and '4f' Metal Ions: Sorption Study with Phenolic Resins -- Chapter 15: Inorganic Ion Exchangers in Paper and Thin-Layer Chromatographic Separations -- Chapter 16: Cation-Exchanged Silica Gel-Based Thin-Layer Chromatography of Organic and Inorganic Compounds -- Chapter 17: Ion Exchange Technology: A Promising Approach for Anions Removal from Water -- Index.
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  • 4
    Online-Ressource
    Online-Ressource
    Hauppauge :Nova Science Publishers, Incorporated,
    Schlagwort(e): Polymerization. ; Polymers. ; Electronic books.
    Beschreibung / Inhaltsverzeichnis: It is well known that polymeric and composite materials are finding various applications in some critical areas of human endeavors, such as medicine, medical appliances, energy and the environment. This edition will, hopefully, evoke interest from scientists working in the fields of chemistry, polymer chemistry, electrochemistry and material science. Its applications and uses include: polymer electrolyte membrane fuel cells, sensors, actuators, coatings, electrochromic and electroluminescent materials, magnetic polymers, organo-metallic polymers, tissue engineering, methods of the immobilization of biological molecules, and dental and orthopedic applications. This edition is a highly valuable source for scientists, researchers, upper-level undergraduate and graduate students, as well as college and university professors, because it provides the most up-to-date reference work summarizing the pioneering research work in the field of polymeric and composite materials.
    Materialart: Online-Ressource
    Seiten: 1 online resource (372 pages)
    Ausgabe: 1st ed.
    ISBN: 9781629480619
    Serie: Polymer Science and Technology
    DDC: 620.192
    Sprache: Englisch
    Anmerkung: Intro -- ADVANCED FUNCTIONAL POLYMERS AND COMPOSITES: MATERIALS, DEVICES AND ALLIED APPLICATIONS. VOLUME 1 -- ADVANCED FUNCTIONAL POLYMERS AND COMPOSITES: MATERIALS, DEVICES AND ALLIED APPLICATIONS. VOLUME 1 -- Library of Congress Cataloging-in-Publication Data -- Dedication -- Contents -- Preface -- Contributors -- About the Editor -- Acknowledgments -- Chapter 1: Advances in Membranes for High Temperature Polymer Electrolyte Membrane Fuel Cells -- Abstract -- Abbreviations -- 1. Introduction -- 2. Proton Exchange Membrane Fuel Cells (PEMFCS) -- 2.1. Role of Proton Conducting Membrane in Proton Exchange Membrane Fuel Cells -- 2.2. Requirement for Proton Conducting Membrane for Proton Exchange Membrane Fuel Cells -- 2.3. Current Status of Perfluorinated Sulfonic Acid and Alternative Proton Conducting Membranes -- 2.4. Proton Transport in Sulfonic Acid Membranes -- 2.5. Challenges Facing Sulfonic Acid Membranes in Proton Exchange Membrane Fuel Cells -- 3. High Temperature Polymer Electrolyte -- Membrane Fuel Cell -- 3.1. Proton Exchange Membranes for High Temperature Proton Exchange Membrane Fuel Cells -- 3.2. Membranes Obtained by Modification with Hygroscopic Inorganic Fillers -- 3.3. Membranes Obtained by Modification with Solid Proton Conductors -- 3.4. Membranes Obtained by Modification with Less Volatile Proton Assisting Solvent -- 3.4.1. Doping with Heterocyclic Solvents -- 3.4.2. Doping with Phosphoric Acid -- 3.4.3. Radiation Grafted and Acid Doped Membranes -- 3.5. Disadvantages of Using Phosphoric Acid Composite Membranes for High Temperature Proton Exchange Membrane Fuel Cell Applications -- 3.6. Alternative Membranes Based on Benzimidazole Derivatives -- 3.7. Alternative Benzimidazole Polymers Doped with Heteropoly Acids -- 3.8. Membrane Impregnated with Ionic Liquids -- 3.9. Summary of Membranes Obtained by Modification of Sulfonic. , Acid Ionomers -- 4. Proton Conduction Mechanism in High Temperature Proton Conducting Membrane -- Conclusion and Prospectives -- Acknowledgments -- References -- Chapter 2: Surface-Confined Ruthenium and Osmium Polypyridyl Complexes as Electrochromic Materials -- Abstract -- Abbreviations -- 1. Introduction -- 1.1. Electrochromic Windows, Displays and Mirrors -- 1.2. Classes of Electrochromic Materials -- 1.3. Metal Complexes As Electrochromic Materials -- 1.3.1. Ruthenium (II) Complexes As Electrochromic Materials -- (I). Optical Behavior of Ruthenium Complexes -- (II). Redox Behavior of Ruthenium Complexes -- (III). Role of Spacers in Dinuclear Ruthenium Complexes -- 1.3.2. Osmium (II) Complexes As Electrochromic Materials -- 1.3.3. Other Metal Complexes As Electrochromic Materials -- 1.4. Substrates Used for Electrochromic Material -- 1.5. Modification of Substrates -- 2. Surface-Confined Ruthenium Complexes -- As Electrochromic Materials -- 2.1. Chemically Adsorbed Ruthenium Complexes -- 2.2. Physically Adsorbed Ruthenium Complexes -- 3. Surface-Confined Osmium Complexes -- As Electrochromic Materials -- 3.1. Osmium Complex-Based Monolayer -- 3.2. Osmium Complex-Based Multilayer -- 4. Surface-Confined Hetero-Metallic -- Complexes As Electrochromic Materials -- 4.1. Coordinative Supramolecular Assembly As Thin Films -- Conclusion -- Acknowledgments -- References -- Chapter 3: Magnetic Polymeric Nanocomposite Materials: Basic Principles Preparations and Microwave Absorption Application -- 1Department of Materials Science, School of Applied Physics, Faculty of Science -- and Technology, Universiti Kebangsaan Malaysia, Bangi, Selangor, Malaysia -- 2Institute of Hydrogen Economy, Universiti Teknologi Malaysia, -- Jalan Semarak, Kuala Lumpur, Malaysia -- Abstract -- Abbreviations -- 1. Introduction -- 2. Historical Background. , 3. Interaction Mechanisms of Electromagnetic Wave -- with Materials -- 3.1. Interaction Mechanism with Conductor Materials -- 3.2. Interaction Mechanism with Dielectric Materials -- 3.3. Interaction Mechanism with Magnetic Materials -- 4. The Reason of Using Microwave Absorbing Materials -- 5. The Criteria for Choosing the Filler and the -- Importance of Matching Conditions for Ideal -- Microwave Absorbing Materials -- 5.1. Metal-Backed Single Layer Absorber Mode -- 5.2. Stand-Alone Absorbing Material Model -- 6. Types and Properties of Polymers -- 7. Magnetic Polymer Nanocomposites -- 7.1. Nanomaterials -- 7.2. Magnetic Polymer Nanocomposites' Properties -- 7.3. Magnetic Polymer Nanocomposites' Applications -- 7.4. The Importance of Dispersion in Magnetic Polymer Nanocomposites -- 8. Preparation and Processing of -- Magnetic Polymer Nanocomposites -- 8.1. In-Situ Oxidative Polymerization Method (with Sonication) -- 8.2. One-Step Chemical Method -- 8.3. Surface-Initiated Polymerization Method -- 8.4. Microemulsion Chemical Oxidative Polymerization Method -- 8.5. Reverse Micelle Microemulsion Method -- 8.6. In-Situ Inverse Microemulsion Polymerization -- 8.7. Irradiation Induced Inverse Emulsion Polymerization -- 8.8. Miniemulsion Polymerization -- 8.9. Mechanical Melt Blending Method -- 8.10. Melt Processing Method Using Ultrasonic Bath -- 8.11. Template Free Method -- 8.12. Solution Casting Method -- 8.13. Sonochemical Method -- 8.14. Electrochemical Synthesis -- 9. Electromagnetic Wave Absorption Application of Magnetic Polymer Nanocomposites -- 9.1. The Crucial Role of Magnetic Nanoparticles and Sample Thickness in the Determination of the Microwave Absorption Application -- 9.2. Effect of Magnetic Filler Size on the Microwave Absorption and/or Electromagnetic Interference Shielding Application. , 9.3. Broadening the Microwave Absorption Range for Low and High Frequency Applications Using Binary Magnetic Nanofillers -- 9.4. The Enhancement of the Microwave Absorption for Electromagnetic Interference Shielding Application Using Magnetic and Dielectric Nanofillers -- Conclusion -- References -- Chapter 4: Polyetheramide-Birth of a New Coating Material -- Abstract -- Abbreviations -- 1. Introduction -- 2. Raw Materials and Test Methods -- 3. Linseed Oil Based Polyetheramides[LPEtA] -- 4. Soybean Oil Based Polyetheramides (SPEtA) -- 5. Albizia Lebbek Benth Oil Based PEtA (ABOPEtA) -- 6. Jatropha Seed Oil Based PEtA(JPEtA) -- 6. Olive Oil Based PEtA (OPEtA) -- Conclusion -- Acknowledgments -- References -- [1] Sørensen, P. A., Kiil,S., Dam-Johansen, K. & -- Weinell, C. E. (2009). Anticorrosive coatings: a review, J. Coat. Technol. Res., 6(2), 135-176. -- Chapter 5: Advanced Functional Polymers and Composite Materials and Their Role in Electroluminescent Applications -- Abstract -- Introduction & -- Scope of the Work -- 1. Light Emitting Diodes (LEDs), Characteristics and Categories -- (a) LED- Device Configuration -- (b) Recent Developments in The LED's Technology -- In-organic Light Emitting Diode -- Materials & -- Characteristics -- 3-I. Luminescence and Scintillation from the Inorganic Phosphor Materials -- An Ideal Luminescencent Material's Characteristics -- 3-II. Scintillation -- 3-III. Inorganic Electroluminescent Materials & -- Devices -- Organic Light Emitting Diodes Devices (OELDs) -- 4- (i). OLED Characteristics -- 4-(ii). OLED- Device Configuration & -- Working Principle -- 4-(iii). General Electroluminescent Materials Used for OLED Devices -- 4-(iv). OLED Device Fabrication -- 4-(v). OLED- Electro-Optical (EO) Properties -- 4-(vi). Quantum Efficiency of OLED Devices -- The Classifications of OLED types. , 4-I. An Overview of Historical Background about Polymeric OLEDs -- (P-OLEDs) -- 4-II. Polymeric OLEDs (P-OLEDs) as Electroluminescent Devices -- 4- III. Polymeric OLEDs (P-OLEDs) Employed in Various Device's Applications -- Conclusion -- Acknowledgments -- References -- [1] Akcelrud, L. Prog. Polym. Sci. 28 (2003). 875-962. -- Chapter 6: Poly(Methacrylic Acid) and Poly (Itaconic Acid) Applications as pH-Sensitive Actuators -- Abstract -- Abbreviations -- 1. Introduction -- 2. Methacrylic Acid and Itaconic Acid -Basic Properties -- 2. Poly(methacrylic acid) and Poly(Itaconic Acid) pH-sensitive Polymers -- 2.1. Linear Systems -- 2.2. Hydrogels -- 2.3. Amphiphillic Block and Graft Copolymers (Micelles) -- 2.4. Modified Surfaces and Membranes -- Conclusion -- Acknowledgments -- References -- Chapter 7: Cell Scaffolds and Fabrication Technologies for Tissue Engineering -- Abstract -- Abbreviations -- 1. Introduction -- 2. Cell Based-Therapies for Tissue Engineering -- 3. Scaffolds Preparation Technologies -- 3.1. Nanofibrous -- 3.2. Freeze-Drying -- 3.3. Fiber Bonding -- 3.4. Phase Separation -- 3.5. Gas Foaming -- 3.6. Rapid Prototyping -- 4. Special Applications in Tissue Ingineering -- 4.1. Injectable Matrices for Cell Therapy -- 4.2. Bioceramic Matrices for Cell Therapy -- Conclusion -- Acknowledgments -- References -- Chapter 8: Immobilization of Lipase by Physical Adsorption on Selective Polymers -- Abstract -- Abbreviations -- 1. Introduction -- 2. The Mechanism of Action of Lipases -- 3. Properties of Enzymes Influenced by Immobilization -- 4. Properties of Matrices for Immobilization -- 5. Methods for Enzyme Immobilization -- 5.1. Physical Adsorption -- Advantages and Disadvantages of Enzymes Immobilization Using the Adsorption Technique -- 5.2. Ionic Binding -- 5.3. Covalent Binding. , Advantages and Disadvantages of Enzymes Immobilization Using the Covalent Technique.
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