Description: The Middle Cambrian Mount Read Volcanics of western Tasmania, Australia, host several world-class volcanic-hosted massive sulfide (VHMS) deposits, representing a wide range of deposit styles. Although the deposits and their host sequences are variably deformed and locally preserve spectacular examples of primary textures and structures, rapid lateral and vertical facies changes, and faults with uncertain sense and magnitude of displacement, have made it impossible to correlate stratigraphy across the belt. Previous dating studies in the area have yielded relatively imprecise crystallization ages. We have employed the chemical abrasion isotope dilution thermal ionization mass spectroscopy (ID-TIMS) U-Pb zircon method to obtain highly precise crystallization ages for a total of 18 samples of volcanic and intrusive rock units from throughout the Mount Read Volcanics and underlying mafic-ultramafic complexes. The new data permit detailed resolution of age relationships within the belt. The study establishes an age of 516.0 ± 0.9 Ma for the McIvor Hill gabbro, which is part of a mafic-ultramafic complex interpreted to underlie the Mount Read Volcanics. Magmatism in the central Mount Read Volcanics lasted at least 12.7 m.y., from 506.8 ± 1.0 Ma for a massive dacite unit in the lower part of the Central Volcanic Complex to 496.0 ± 0.9 Ma for a welded ignimbrite in the lower Tyndall Group. Together with previous age constraints, results of the study provide a precise chronostratigraphic framework for magmatism and VHMS deposit formation within the Mount Read Volcanics. The precise age data indicate that, north of the Henty fault, magmatism occurred in three discrete pulses, at least two of which were separated by periods of sedimentation. We demonstrate that VHMS deposits in the Mount Lyell, Roseberry-Hercules, and Que-Hellyer districts, comprising the majority of the known, significant VHMS deposits in the belt, formed within a narrow time interval at ~500 ± 1 Ma, at a relatively late stage in the evolution of the belt. Some of the larger intrusions in the belt (e.g., the Bonds Range porphyry; 500.4 ± 0.8 Ma) were emplaced contemporaneously with VHMS deposit formation; however, other bodies such as the Murchison granite (497.3 ± 0.9 Ma) are younger than the deposits and are unlikely to have been involved in their genesis as has previously been suggested. These conclusions will aid explorers in targeting VHMS mineralization in the Mount Read Volcanics.

Description: The Glacier Creek volcanogenic massive sulfide (VMS) deposit, Alaska, is hosted within Late Triassic, oceanic back-arc or intraarc, rift-related bimodal volcanic rocks of the allochthonous Alexander terrane, known as the Alexander Triassic metallogenic belt. The Alexander Triassic metallogenic belt is host to the world-class Greens Creek Zn-Pb-Ag VMS deposit near Juneau in the south and the giant Windy Craggy Cu-Co VMS deposit in British Columbia, about 250 km to the north. The Glacier Creek deposit, located ~80 km southeast of Windy Craggy, consists of four tabular massive sulfide lenses within a bimodal mafic volcaniclastic and rhyolitic sequence. The mineralization-hosting stratigraphy is folded by a deposit-scale anticline and offset by a thrust fault near the axial surface of the fold. A resource of 8.13 Mt has been inferred from drilling, with grades of 1.41% Cu, 5.25% Zn, 0.15% Pb, 0.32 g/t Au, and 31.7 g/t Ag. Six main mineralization types are recognized, dominated by massive barite-sphalerite-pyrite, which is replaced at the base and center of the main lenses by massive and semimassive chalcopyrite-pyrite-quartz. The flanks and tops of the lenses are carbonate rich and consist of interbedded calcite-dolomite, barite and sulfide, resedimented massive barite-sulfide, and mineralized massive carbonate rocks. Tuffaceous hydrothermal sediment, with a distinct positive Eu anomaly, overlies the massive sulfide. Pyrrhotite and chalcopyrite in stringers constitute the main "feeder zone." Stringer-style sphalerite-pyrite mineralization occurs above and below the lenses. Fe-poor sphalerite is dominant throughout the lenses, whereas Fe-rich sphalerite occurs at the stratigraphic top and bottom of the lenses in pyrrhotite-rich zones. Galena, tennantite-tetrahedrite, and arsenopyrite are the most important trace minerals within massive barite-sphalerite-pyrite mineralization, which is generally enriched in Sb, Hg, and Tl. Mineralization-related gangue minerals include barite, quartz, barian muscovite, calcite, dolomite, albite, chlorite, hyalophane, and celsian. Four types of alteration are recognized in the dominantly basaltic host rocks: pervasive muscovite-rich alteration, quartz-pyrite alteration associated with sulfide stringers, stratabound carbonate-bearing alteration, and background epidote-bearing alteration. Mass balance calculations indicate gains of S, Fe, Si, and K with coincident losses of Ca, Na, and Mg in all of the alteration types. Trace elements, Tl, Sb, Hg, Ba, Zn, Cu, and As were added to the rocks, whereas Sr was lost. Short wavelength infrared (SWIR) spectroscopy shows an increase in the wavelength of the AlOH absorption feature toward mineralization at a scale of 30 to 50 m, coincident with a general decrease in the Na, K, and Al and increase in the Fe, Mg, and Ba content of muscovite. The Glacier Creek deposit is transitional in character between Greens Creek, which is more Zn, Pb, and precious metal rich, and the Windy Craggy deposit, which is more Cu and Co rich, reflecting differences in the basement rocks and depositional settings within the Alexander Triassic metallogenic belt. Mineral-chemical studies and sulfur isotope data suggest that the Glacier Creek deposit formed under initially oxidized and sulfate-rich conditions that evolved to more reduced conditions in the latest stages of mineralization. The abundant argillite and presence of hyalophane rather than barite in the immediate hanging wall of the deposit may be an indication of a deepening basin and development of local anoxia, similar to Greens Creek.

Description: The Chahnaly low-sulfidation epithermal Au deposit and nearby Au prospects are located northwest of the intermittently active Bazman stratovolcano on the western end of the Makran volcanic arc, which formed as the result of subduction of the remnant Neo-Tethyan oceanic crust beneath the Lut block. The arc hosts the Siah Jangal epithermal and Kharestan porphyry prospects, near Taftan volcano, as well as the Saindak Cu-Au porphyry deposit and world-class Reko Diq Cu-Au porphyry deposit, near Koh-i-Sultan volcano to the east-northeast in Pakistan. The host rocks for the Chahnaly deposit include early Miocene andesite and andesitic volcaniclastic rocks that are intruded by younger dacitic domes. Unaltered late Miocene dacitic ignimbrites overlie these rocks. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology data yield ages between 21.8 and 9.9 Ma for the acidic-intermediate regional volcanism. The most recent volcanic activity of the Bazman stratovolcano involved extrusion of an olivine basalt during Pliocene to Quaternary times. Interpretation of geochemical data indicate that the volcanic rocks are synsubduction and calc-alkaline to subalkaline. The lack of a significant negative Eu anomaly, a listric-shaped rare earth element pattern, and moderate La/Yb ratios of host suites indicate a high water content of the source magma. Gold and electrum are temporally and spatially related to a series of structurally controlled, 030°-trending, subvertical hydrothermal breccias with chalcedony-adularia that cut porphyritic andesite and andesitic volcaniclastic rocks. Gold is associated with pyrite, a siliceous matrix of hydrothermal breccia, and previously formed vein clasts, as well as with iron oxides and hydroxides in oxidized zones. Rare silver minerals include Ag-bearing electrum and naumannite, iodargyrite, an unnamed silver diiodide, and hessite. Hydrothermal alteration is generally well developed surrounding the ore-bearing hydrothermal breccia. The main types of alteration in the area include an inner ~0.5- to 20-m-thick gold-bearing hydrothermal breccia composed of quartz-chalcedonyadularia-illite-pyrite, a ~5- to 50-m-thick zone of quartz, chalcedony, pyrite, illitic phengite, phengite, illitic muscovite, illite, illitic paragonite, paragonite, muscovite, montmorillonite and, rarely, siderite, and a 30- to 70-m outer propylitic zone of Fe-Mg chlorite, calcite, ankerite, dolomite, epidote, palygorskite, and pyrite. The Chahnaly Au deposit formed during the early stages of magmatism. LA-ICP-MS zircon U-Pb geochronology of host andesite and 40Ar/39Ar dating of two samples of gold-associated adularia show that the ore-stage adularia (19.83 ± 0.10 and 19.2 ± 0.5 Ma) is younger, by as much as 1.5 million years, than the volcanic host rock (20.32 ± 0.4 Ma). Therefore, either hydrothermal activity continued well after volcanism or a second magmatic event rejuvenated hydrothermal activity. This second magmatic event may be related to eruption of porphyritic andesite at ~20.32 ± 0.40 Ma, which is within error of ~19.83 ± 0.10 Ma adularia. The new LA-ICP-MS zircon U-Pb host rock and vein adularia 40Ar/39Ar ages suggest that early Miocene magmatism and mineralization in the Bazman area is of a similar age to that of the Saindak porphyry and Tanjeel porphyry center of the giant Reko Diq deposit. This confirms the existence of early Miocene arc magmatism and mineralization along the Iranian part of the Makran volcanic arc. Ore, alteration mineralogy, and alteration patterns indicate that the Chahnaly deposit is a typical low-sulfidation epithermal Au deposit, located in a poorly explored part of the Makran volcanic arc in Iran.

Description: The Chahnaly low-sulfidation epithermal Au deposit and nearby Au prospects are located northwest of the intermittently active Bazman stratovolcano on the western end of the Makran volcanic arc, which formed as the result of subduction of the remnant Neo-Tethyan oceanic crust beneath the Lut block. The arc hosts the Siah Jangal epithermal and Kharestan porphyry prospects, near Taftan volcano, as well as the Saindak Cu-Au porphyry deposit and world-class Reko Diq Cu-Au porphyry deposit, near Koh-i-Sultan volcano to the east-northeast in Pakistan. The host rocks for the Chahnaly deposit include early Miocene andesite and andesitic volcaniclastic rocks that are intruded by younger dacitic domes. Unaltered late Miocene dacitic ignimbrites overlie these rocks. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology data yield ages between 21.8 and 9.9 Ma for the acidic-intermediate regional volcanism. The most recent volcanic activity of the Bazman stratovolcano involved extrusion of an olivine basalt during Pliocene to Quaternary times. Interpretation of geochemical data indicate that the volcanic rocks are synsubduction and calc-alkaline to subalkaline. The lack of a significant negative Eu anomaly, a listric-shaped rare earth element pattern, and moderate La/Yb ratios of host suites indicate a high water content of the source magma. Gold and electrum are temporally and spatially related to a series of structurally controlled, 030°-trending, subvertical hydrothermal breccias with chalcedony-adularia that cut porphyritic andesite and andesitic volcaniclastic rocks. Gold is associated with pyrite, a siliceous matrix of hydrothermal breccia, and previously formed vein clasts, as well as with iron oxides and hydroxides in oxidized zones. Rare silver minerals include Ag-bearing electrum and naumannite, iodargyrite, an unnamed silver diiodide, and hessite. Hydrothermal alteration is generally well developed surrounding the ore-bearing hydrothermal breccia. The main types of alteration in the area include an inner ~0.5- to 20-m-thick gold-bearing hydrothermal breccia composed of quartz-chalcedonyadularia-illite-pyrite, a ~5- to 50-m-thick zone of quartz, chalcedony, pyrite, illitic phengite, phengite, illitic muscovite, illite, illitic paragonite, paragonite, muscovite, montmorillonite and, rarely, siderite, and a 30- to 70-m outer propylitic zone of Fe-Mg chlorite, calcite, ankerite, dolomite, epidote, palygorskite, and pyrite. The Chahnaly Au deposit formed during the early stages of magmatism. LA-ICP-MS zircon U-Pb geochronology of host andesite and 40Ar/39Ar dating of two samples of gold-associated adularia show that the ore-stage adularia (19.83 ± 0.10 and 19.2 ± 0.5 Ma) is younger, by as much as 1.5 million years, than the volcanic host rock (20.32 ± 0.4 Ma). Therefore, either hydrothermal activity continued well after volcanism or a second magmatic event rejuvenated hydrothermal activity. This second magmatic event may be related to eruption of porphyritic andesite at ~20.32 ± 0.40 Ma, which is within error of ~19.83 ± 0.10 Ma adularia. The new LA-ICP-MS zircon U-Pb host rock and vein adularia 40Ar/39Ar ages suggest that early Miocene magmatism and mineralization in the Bazman area is of a similar age to that of the Saindak porphyry and Tanjeel porphyry center of the giant Reko Diq deposit. This confirms the existence of early Miocene arc magmatism and mineralization along the Iranian part of the Makran volcanic arc. Ore, alteration mineralogy, and alteration patterns indicate that the Chahnaly deposit is a typical low-sulfidation epithermal Au deposit, located in a poorly explored part of the Makran volcanic arc in Iran.

Description: The Cerro la Mina Au (Cu-Mo) porphyry-high sulfidation prospect is located in Chiapas State, southeastern Mexico, outside of the major metallogenic provinces of Mexico. The prospect is hosted by Pleistocene alkaline volcanic rocks of the Chiapanecan volcanic arc that formed in a complex triple-junction tectonic setting. Cerro la Mina’s stratigraphy comprises pyroclastic flows that were intruded by monzodiorites and diorites at 1.04 ± 0.04 Ma (U-Pb, zircon), and that were overlain by debris flows and synvolcanic trachyandesite domes. The volcanic stratigraphy of Cerro la Mina is dominated by pyroclastic flows and rare basalts that are cut by the Cerro la Mina breccia pipe, a matrix-rich granular, vertically oriented, downward-tapering, polymict lithic rock unit that is host to all of the significant alteration and mineralization. A NW-trending sinistral wrench fault, which was active throughout the history of Cerro la Mina, is responsible for dismembering the prospect after mineralization. The magmatic hydrothermal system was composed of early porphyry-style potassic veins (quartz + K-feldspar ± biotite) and stage 1 pyrite that are preserved in clasts within the breccia pipe, suggesting that brecciation disrupted an embryonic porphyry system. Late potassic alteration occurred after the formation of the breccia pipe, as its matrix is strongly K-feldspar altered. Hydrothermal fluids then produced phyllic alteration composed of quartz, muscovite, illite, illite-smectite, and chlorite that is associated with stage 2 pyrite ± chalcopyrite ± molybdenite ± quartz veins. An unusual zoned pattern of advanced argillic-argillic alteration overprinted potassic and phyllic alteration. This zoning included a low-temperature (〈110°C) halloysite + kaolinite that extends from 800 to 250 m below present-day surface and is deeper than higher temperature (〉120°C) quartz + dickite ± kaolinite ± pyrophyllite ± alunite that occurs from 250 m to the present-day surface. The advanced argillic-argillic altered rocks host the most significant Au-Cu mineralization, which is associated with stage 3 marcasite, sphalerite, galena, and barite, and stage 4 arsenian pyrite ± enargite ± covellite. The magmatic hydrothermal system at Cerro la Mina began sometime between monzodiorite emplacement (1.04 ± 0.04 Ma; zircon U-Pb) and the precipitation of porphyry stage 2 molybdenite at 780 ± 10 ka (Re-Os). 40 Ar/ 39 Ar dating of biotite (689 ± 13 ka) records the age at which the hydrothermal system cooled below the biotite closure temperature of ~300°C and provides a maximum estimate for the onset of advanced argillic-argillic alteration. Sulfur isotope results of sulfides (–2.5 to +4.9; mean +0.7; n = 20) and a sulfate (barite; +10.5; n = 1) suggest a magmatic source of sulfur for all four stages of mineralization. The lack of residual quartz, rare alunite, and anomalous halloysite-kaolinite alteration may be explained by the high acid-buffering capacity of alkaline volcanic host rocks, high CO 2 contents of the alkaline magma, and/or potentially by a highly reduced magmatic hydrothermal fluid. At the regional metallogenic scale, the Cerro la Mina prospect along with the nearby Santa Fé mine and Campamento deposit represent parts of a porphyry copper system—specifically, a porphyry/high-sulfidation, proximal skarn and intermediate sulfidation deposit, respectively. The characteristics of Cerro la Mina (i.e., anomalous halloysite-kaolinite alteration) broaden the window for additional discoveries to be made in the porphyry-epithermal environment.