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  • 1
    Online Resource
    Online Resource
    Wiley ; 2019
    In:  Chemistry – A European Journal Vol. 25, No. 48 ( 2019-08-27), p. 11285-11293
    In: Chemistry – A European Journal, Wiley, Vol. 25, No. 48 ( 2019-08-27), p. 11285-11293
    Abstract: A series of three bis(merocyanine) dyes comprising chromophores of different conjugation lengths has been synthesized and the intramolecular aggregation process was investigated by UV/Vis absorption spectroscopy. The spectral changes observed upon variation of the solvent polarity reveal a folding process resulting in a cofacial π‐stack of two chromophores with a decrease of the aggregation tendency with increasing chromophore length and solvent polarity. Solvent‐dependent UV/Vis studies of the monomeric reference dyes show a significant increase of the polyene‐like character for dyes with longer polymethine chains in nonpolar solvents, which is reversed upon aggregation due to the polarizability effect of the adjacent chromophore within the dye stack. The pronounced hypsochromic shift of the absorption band observed upon aggregation indicates strong coupling of the dyes’ transition dipole moments, which was confirmed by quantum‐chemical analysis.
    Type of Medium: Online Resource
    ISSN: 0947-6539 , 1521-3765
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 1478547-X
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  • 2
    Online Resource
    Online Resource
    Wiley ; 2017
    In:  Angewandte Chemie International Edition Vol. 56, No. 50 ( 2017-12-11), p. 16008-16012
    In: Angewandte Chemie International Edition, Wiley, Vol. 56, No. 50 ( 2017-12-11), p. 16008-16012
    Abstract: The self‐assembly of a new perylene bisimide (PBI) organogelator with 1,7‐dimethoxy substituents in the bay position affords non‐fluorescent H‐aggregates at high cooling rates and fluorescent J‐aggregates at low cooling rates. Under properly adjusted conditions, the kinetically trapped “off‐pathway” H‐aggregates are transformed into the thermodynamically favored J‐aggregates, a process that can be accelerated by the addition of J‐aggregate seeds. Spectroscopic studies revealed a subtle interplay of π–π interactions and intra‐ and intermolecular hydrogen bonding for monomeric, H‐, and J‐aggregated PBIs. Multiple polymerization cycles initiated from the seed termini demonstrate the living character of this chain‐growth supramolecular polymerization process.
    Type of Medium: Online Resource
    ISSN: 1433-7851 , 1521-3773
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2017
    detail.hit.zdb_id: 2011836-3
    detail.hit.zdb_id: 123227-7
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  • 3
    In: American Journal of Medical Genetics Part A, Wiley, Vol. 167, No. 11 ( 2015-11), p. 2555-2562
    Abstract: Three children from an expanded consanguineous Kuwaiti kindred presented with ankyloblepharon, sparse and curly hair, and hypoplastic nails, suggestive of CHAND syndrome (OMIM 214350) that belongs to the heterogeneous spectrum of ectodermal dysplasias. After exclusion of pathogenic mutations in TP63 we performed homozygosity mapping, followed by exome sequencing of one affected individual. We initially identified three homozygous mutations in the linked region, located in PWP2, MX2 and RIPK4. Recently, mutations in RIPK4 have been reported in Bartsocas‐Papas syndrome (OMIM 263650) that shows overlapping clinical symptoms with the phenotype observed in the affected individuals studied here. Subsequent analysis of affected and non‐affected family members showed that mutation c.850G 〉 A (p.Glu284Lys) in RIPK4 was in complete segregation with the disease phenotype, in accordance with an autosomal recessive inheritance pattern, thus supporting pathogenicity of this variant. Interestingly, however, our patients did not have cleft lip/palate, a common feature encountered in Bartsocas‐Papas syndrome. Whereas in Bartsocas‐Papas syndromes missense mutations are usually located within the serin/threonin kinase of RIPK4, the mutation detected in our family resides just outside of the kinase domain, which could explain the milder phenotype. Our data raise the question if CHAND syndrome indeed is a distinct entity. Alternatively, CHAND and Bartsocas‐Papas syndrome might be allelic disorders or RIPK4 mutations could confer varying degrees of phenotypic severity, depending on their localization within or outside functionally important domains. Our findings indicate that making an accurate diagnosis based only on the prevailing clinical symptoms is challenging. © 2015 Wiley Periodicals, Inc.
    Type of Medium: Online Resource
    ISSN: 1552-4825 , 1552-4833
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2015
    detail.hit.zdb_id: 1493479-6
    SSG: 12
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  • 4
    In: BMC Plant Biology, Springer Science and Business Media LLC, Vol. 15, No. 1 ( 2015-12)
    Type of Medium: Online Resource
    ISSN: 1471-2229
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2015
    detail.hit.zdb_id: 2059868-3
    SSG: 12
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  • 5
    In: Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 16, No. 22 ( 2016-11-15), p. 14107-14130
    Abstract: Abstract. The marine aerosol arriving at Barbados (Ragged Point) was characterized during two 3-week long measurement periods in November 2010 and April 2011, in the context of the measurement campaign CARRIBA (Cloud, Aerosol, Radiation and tuRbulence in the trade wInd regime over BArbados). Through a comparison between ground-based and airborne measurements it was shown that the former are representative of the marine boundary layer at least up to cloud base. In general, total particle number concentrations (Ntotal) ranged from as low as 100  up to 800 cm−3, while number concentrations for cloud condensation nuclei (NCCN) at a supersaturation of 0.26 % ranged from some 10 to 600 cm−3. Ntotal and NCCN depended on the air mass origin. Three distinct types of air masses were found. One type showed elevated values for both Ntotal and NCCN and could be attributed to long-range transport from Africa, by which biomass burning particles from the Sahel region and/or mineral dust particles from the Sahara were advected. The second and third type both had values for NCCN below 200 cm−3 and a clear minimum in the particle number size distribution (NSD) around 70 to 80 nm (Hoppel minimum). While for one of these two types the accumulation mode was dominating (albeit less so than for air masses advected from Africa), the Aitken mode dominated the other and contributed more than 50 % of all particles. These Aitken mode particles likely were formed by new particle formation no more than 3 days prior to the measurements. Hygroscopicity of particles in the CCN size range was determined from CCN measurements to be κ  =  0.66 on average, which suggests that these particles contain mainly sulfate and do not show a strong influence from organic material, which might generally be the case for the months during which measurements were made. The average κ could be used to derive NCCN from measured number size distributions, showing that this is a valid approach to obtain NCCN. Although the total particulate mass sampled on filters was found to be dominated by Na+ and Cl−, this was found to be contributed by a small number of large particles ( 〉  500 nm, mostly even in the super-micron size range). Based on a three-modal fit, a sea spray mode observed in the NSDs was found to contribute 90 % to the total particulate mass but only 4 to 10 % to Ntotal and up to 15 % to NCCN. This is in accordance with finding no correlation between Ntotal and wind speed.
    Type of Medium: Online Resource
    ISSN: 1680-7324
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2016
    detail.hit.zdb_id: 2092549-9
    detail.hit.zdb_id: 2069847-1
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  • 6
    In: Advanced Materials Interfaces, Wiley, Vol. 6, No. 2 ( 2019-01)
    Abstract: Amorphous hydrogenated carbon (a‐C:H) films are applied 500 nm thick on Si(100) via plasma‐enhanced chemical vapor deposition (PECVD) using ethyne. Present plasma conditions enrich the sp 2 ‐content especially toward the outermost a‐C:H layers, which in turn are used to attach a photoactive Ru‐polypyridyl complex to the surface. An azo‐bridged dinuclear Ru‐polypyridyl complex is optimized in synthesis and the final mononuclear fragment attached on a‐C:H photochemically under UV‐irradiation with concomitant N 2 release. The Ru‐polypyridyl complex is characterized by MS, NMR, IR, UV/vis, fluorescence spectroscopy, and time‐dependent density functional theory (DFT) calculations. Crystallographic data for the intermediate 4‐nitro‐2‐(pyridin‐2‐yl)pyridine 1‐oxide as essential precursor are established. Morphological characteristics of the a‐C:H @ Si and final Ru(complex) @ a‐C:H @ Si combinations are determined by atomic force microscopy (AFM) revealing individual grain‐like structures. The presence of Ru on the a‐C:H @ Si surface is initially verified qualitatively by laser‐induced breakdown spectroscopy (LIBS) and by inductively coupled plasma‐sector field mass spectrometry (ICP‐SF‐MS) after chemical digestion. With laser ablation‐ICP‐MS mapping, full Ru coverage is proven, also revealing inhomogeneities in terms of “Ru hot spots”. The current investigation proves the successful attachment of a Ru‐complex on a‐C:H and indicates a starting point for the development of further material combinations for feasible sunlight to energy conversions.
    Type of Medium: Online Resource
    ISSN: 2196-7350 , 2196-7350
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 2750376-8
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  • 7
    In: Applied Sciences, MDPI AG, Vol. 9, No. 22 ( 2019-11-13), p. 4853-
    Abstract: Optical Character Recognition (OCR) on historical printings is a challenging task mainly due to the complexity of the layout and the highly variant typography. Nevertheless, in the last few years, great progress has been made in the area of historical OCR, resulting in several powerful open-source tools for preprocessing, layout analysis and segmentation, character recognition, and post-processing. The drawback of these tools often is their limited applicability by non-technical users like humanist scholars and in particular the combined use of several tools in a workflow. In this paper, we present an open-source OCR software called OCR4all, which combines state-of-the-art OCR components and continuous model training into a comprehensive workflow. While a variety of materials can already be processed fully automatically, books with more complex layouts require manual intervention by the users. This is mostly due to the fact that the required ground truth for training stronger mixed models (for segmentation, as well as text recognition) is not available, yet, neither in the desired quantity nor quality. To deal with this issue in the short run, OCR4all offers a comfortable GUI that allows error corrections not only in the final output, but already in early stages to minimize error propagations. In the long run, this constant manual correction produces large quantities of valuable, high quality training material, which can be used to improve fully automatic approaches. Further on, extensive configuration capabilities are provided to set the degree of automation of the workflow and to make adaptations to the carefully selected default parameters for specific printings, if necessary. During experiments, the fully automated application on 19th Century novels showed that OCR4all can considerably outperform the commercial state-of-the-art tool ABBYY Finereader on moderate layouts if suitably pretrained mixed OCR models are available. Furthermore, on very complex early printed books, even users with minimal or no experience were able to capture the text with manageable effort and great quality, achieving excellent Character Error Rates (CERs) below 0.5%. The architecture of OCR4all allows the easy integration (or substitution) of newly developed tools for its main components by standardized interfaces like PageXML, thus aiming at continual higher automation for historical printings.
    Type of Medium: Online Resource
    ISSN: 2076-3417
    Language: English
    Publisher: MDPI AG
    Publication Date: 2019
    detail.hit.zdb_id: 2704225-X
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  • 8
    Online Resource
    Online Resource
    Wiley ; 2016
    In:  European Journal of Inorganic Chemistry Vol. 2016, No. 9 ( 2016-03), p. 1333-1339
    In: European Journal of Inorganic Chemistry, Wiley, Vol. 2016, No. 9 ( 2016-03), p. 1333-1339
    Abstract: A series of hexahalocerate(III) salts with the general formula [cation] 3 [CeHal 6 ] have been prepared by dissolving anhydrous cerium trihalides in imidazolium halide ionic liquids. Complexes with different anions, [CeCl 6 ] 3– , [CeBr 6 ] 3– and [CeBr 3 Cl 3 ] 3– , were synthesized and their cationic alkyl chains were varied. To confirm the structures of the prepared salts, X‐ray crystallography was used to characterize [BMIM] 3 [CeCl 6 ]. Two different crystal structures were found: [BMIM] 3 [CeCl 6 ] and the linear coordination polymer [BMIM] x [Ce(µ‐Cl) 2 Cl 2 (EtOH) 2 ] x containing coordinated solvent. All the synthesized compounds were characterized by DSC and TGA. The influence of the cationic and anionic structures on the melting points and decomposition temperatures is discussed. Furthermore, the Ce‐containing salts [BMIM] 3 [CeHal 6 ] show interesting photoluminescence properties: intense Ce 3+ ‐based 5d–4f‐centred emission from the soft UV‐B region to the border of visible light is observed that is driven both by direct excitation of Ce 3+ as well as by a sensitizer effect of the [BMIM] + cation.
    Type of Medium: Online Resource
    ISSN: 1434-1948 , 1099-0682
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 1475009-0
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  • 9
    In: Nature Methods, Springer Science and Business Media LLC, Vol. 13, No. 8 ( 2016-8), p. 665-672
    Type of Medium: Online Resource
    ISSN: 1548-7091 , 1548-7105
    Language: English
    Publisher: Springer Science and Business Media LLC
    Publication Date: 2016
    detail.hit.zdb_id: 2163081-1
    SSG: 12
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  • 10
    Online Resource
    Online Resource
    Bio-Protocol, LLC ; 2016
    In:  BIO-PROTOCOL Vol. 6, No. 5 ( 2016)
    In: BIO-PROTOCOL, Bio-Protocol, LLC, Vol. 6, No. 5 ( 2016)
    Type of Medium: Online Resource
    ISSN: 2331-8325
    Language: English
    Publisher: Bio-Protocol, LLC
    Publication Date: 2016
    detail.hit.zdb_id: 2833269-6
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