Description: The oxygen isotope composition of speleothems is a widely used proxy for past climate change. Robust use of this proxy depends on understanding the relationship between precipitation and cave drip water δ18O. Here, we present the first global analysis, based on data from 163 drip sites, from 39 caves on five continents, showing that drip water δ18O is most similar to the amount-weighted precipitation δ18O where mean annual temperature (MAT) is 〈 10 °C. By contrast, for seasonal climates with MAT 〉 10 °C and 〈 16 °C, drip water δ18O records the recharge-weighted δ18O. This implies that the δ18O of speleothems (formed in near isotopic equilibrium) are most likely to directly reflect meteoric precipitation in cool climates only. In warmer and drier environments, speleothems will have a seasonal bias toward the precipitation δ18O of recharge periods and, in some cases, the extent of evaporative fractionation of stored karst water.

Description: Although quantitative isotope data from speleothems has been used to evaluate isotope-enabled model simulations, currently no consensus exists regarding the most appropriate methodology through which to achieve this. A number of modelling groups will be running isotope-enabled palaeoclimate simulations in the framework of the Coupled Model Intercomparison Project Phase 6, so it is timely to evaluate different approaches to using the speleothem data for data–model comparisons. Here, we illustrate this using 456 globally distributed speleothem δ18O records from an updated version of the Speleothem Isotopes Synthesis and Analysis (SISAL) database and palaeoclimate simulations generated using the ECHAM5-wiso isotope-enabled atmospheric circulation model. We show that the SISAL records reproduce the first-order spatial patterns of isotopic variability in the modern day, strongly supporting the application of this dataset for evaluating model-derived isotope variability into the past. However, the discontinuous nature of many speleothem records complicates the process of procuring large numbers of records if data–model comparisons are made using the traditional approach of comparing anomalies between a control period and a given palaeoclimate experiment. To circumvent this issue, we illustrate techniques through which the absolute isotope values during any time period could be used for model evaluation. Specifically, we show that speleothem isotope records allow an assessment of a model’s ability to simulate spatial isotopic trends. Our analyses provide a protocol for using speleothem isotope data for model evaluation, including screening the observations to take into account the impact of speleothem mineralogy on δ18O values, the optimum period for the modern observational baseline and the selection of an appropriate time window for creating means of the isotope data for palaeo-time-slices.

Description: The North Atlantic Oscillation (NAO) is known to influence precipitation δ18O (δ18Op) through its control on air temperature and on the trajectory of the westerly winds that carry moisture onto Europe during boreal winters. Hence, paleoclimate studies seeking to reconstruct the NAO can exploit the δ18O signal that is commonly preserved in natural archives such as stalagmites, ice cores, tree rings and lake sediments. However, such reconstructions should consider the uncertainties that arise from non-stationarities in the δ18Op-NAO relationship. Here, new insights into the causes of these temporal non-stationarities are presented for the European region using both observations (GNIP database) and the output of an isotope-enabled general circulation model (ECHAM5-wiso). The results show that, although the East Atlantic (EA) pattern is generally uncorrelated to δ18Op during the instrumental period, its polarity affects the δ18Op-NAO relationship. Non-stationarities in this relationship result from spatial shifts of the δ18Op-NAO correlated areas as a consequence of different NAO/EA combinations. These shifts are consistent with those reported previously for NAO-winter climate variables and the resulting non-stationarities mean that δ18O-based NAO reconstructions could be compromised if the balance of positive and negative NAO/EA states differs substantially in a calibration period compared with the period of interest in the past. The same approach has been followed to assess the relationships between δ18Op and both winter total precipitation and winter mean surface air temperature, with similar results. Crucially, this study also identifies regions within Europe where temporal changes in the NAO, air temperature and precipitation can be more robustly reconstructed using δ18O time series from natural archives, irrespective of concomitant changes in the EA.

Description: Magnesium calcites were synthesized from aqueous solutions supersaturated with respect to calcite at 25, 40, 60, and 80 °C in gas tight batch reactors for up to 35 days. Any amorphous material still present in the precipitates was removed using a partial dissolution treatment. Resulting purified Mg-calcite had Mg contents ranging from 6 to 32 mol% MgCO3. An isotopic steady-state was attained between the fluid and the precipitated solids within two weeks at 25 °C. δ18O values derived from the experiments at steady-state, depend on both temperature and the Mg content of the calcite in accord with: 1000lnαMg-calcite–H2O=18,030/T−32.42+(6×108/T3–5.47×106/T2+16,780/T−17.21)×CMg where αMg-calcite–H2O represents the calcite–water oxygen isotope fractionation factor, T refers to the temperature in °K and CMg denotes the mole percent of MgCO3 in the calcite. These results indicate that the addition of 5 mol% MgCO3 into the calcite increases 1000lnαMg-calcite–H2O by 0.88 as compared to that of pure calcite at 25 °C. This difference could lead to a 4.2 °C decrease in estimated formation temperature estimates. These results demonstrate that the accurate interpretation of oxygen isotope fractionation in magnesium calcites requires explicit provision for the effect of magnesium on oxygen isotope fractionation factors. Highlights ► The effect of Mg on calcite–aqueous fluid oxygen isotope fractionation was investigated. ► Mg incorporation is increasing the calcite–aqueous fluid oxygen isotope fractionation. ► This effect is reduced at higher temperatures. ► Obtained results are important for paleo-temperature estimation. Gadget timed out while loading

Description: Climate variability in the North Atlantic sector is commonly ascribed to the North Atlantic Oscillation. However, recent studies have shown that taking into account the second and third mode of variability (namely the East Atlantic – EA – and the Scandinavian – SCA – patterns) greatly improves our understanding of their controlling mechanisms, as well as their impact on climate. The most commonly used EA and SCA indices span the period from 1950 to present which is too short, for example, to calibrate palaeoclimate records or assess their variability over multi-decadal scales. To tackle this, here, we make available seasonal (3-months) EOF-based indices of NAO, EA and SCA indices covering the period from 1851 to present (Dataset 2); and compare them with their equivalent instrumental indices calculated as standarised sea-level pressure anomalies from Valentia Observatory, Ireland and Bergen Florida, Norway (Dataset 1)