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  • 1
    Publication Date: 2023-11-23
    Description: Offshore meteoric groundwater (OMG) has long been hypothesized to be a driver of seafloor geomorphic processes in continental margins worldwide. Testing this hypothesis has been challenging because of our limited understanding of the distribution and rate of OMG flow and seepage, and their efficacy as erosive/destabilizing agents. Here we carry out numerical simulations of groundwater flow and slope stability using conceptual models and evolving stratigraphy—for passive siliciclastic and carbonate margin cases—to assess whether OMG and its evolution during a late Quaternary glacial cycle can generate the pore pressures required to trigger mechanical instabilities on the seafloor. Conceptual model results show that mechanical instabilities using OMG flow are most likely to occur in the outer shelf to upper slope, at or shortly before the Last Glacial Maximum sea‐level lowstand. Models with evolving stratigraphy show that OMG flow is a key driver of pore pressure development and instability in the carbonate margin case. In the siliciclastic margin case, OMG flow plays a secondary role in preconditioning the slope to failure. The higher degree of spatial/stratigraphic heterogeneity of carbonate margins, lower shear strengths of their sediments, and limited generation of overpressures by sediment loading may explain the higher susceptibility of carbonate margins, in comparison to siliciclastic margins, to mechanical instability by OMG flow. OMG likely played a more significant role in carbonate margin geomorphology (e.g., Bahamas, Maldives) than currently thought.
    Description: Plain Language Summary: The flow of fresh to brackish groundwater has been proposed as an important process shaping the seafloor. However, we still have a poor understanding of how groundwater behaves in the sub‐seafloor and whether it can erode seafloor sediments. In this study, we test this hypothesis by using conceptual and realistic numerical models of two common types of seafloor margins—siliciclastic and carbonate—to assess the role of groundwater in making the seafloor susceptible to erosion. We show that the flow of groundwater offshore could have driven seafloor erosion close to the shelf break during the Last Ice Age, when sea level was lower than at present. Carbonate margins are more susceptible to this type of failure than siliciclastic margins. This may be explained by the higher variability in sediment properties across carbonate margins as well as the lower strength of their sediments. Groundwater has likely played an important role in shaping the seafloor in carbonate margins, and it may be responsible for landforms such as canyons, scars, and depressions in the Bahamas and the Maldives.
    Description: Key Points: Offshore meteoric groundwater (OMG) flow can drive mechanical instabilities in the outer shelf to upper slope. Such instabilities occur at, or shortly after, the Last Glacial Maximum sea‐level lowstand. Carbonate margins are more susceptible to mechanical instability by OMG than siliciclastic margins.
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: National Science Foundation http://dx.doi.org/10.13039/100000001
    Description: https://doi.org/10.5281/zenodo.7094202
    Description: https://www.rocscience.com/software/slide2
    Description: https://figshare.com/s/5336d42d19ef771d4ad8
    Description: https://figshare.com/s/5027cd5ca22a7e96b3d1
    Keywords: ddc:551.3 ; offshore groundwater ; mechanical instability ; continental margins ; seafloor geomorphology ; siliciclastic ; carbonate
    Language: English
    Type: doc-type:article
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  • 2
    Publication Date: 2023-02-16
    Description: Mechanisms of fluid flow localization and pockmark formation remain an open question. Many conceptual models have been proposed, but very few predictive models exist. We propose a model based on erosive fluidization where seepage induced erosion, fluidization, and transport of granular material leads the formation of fluid escape structures (FES) like pipes, chimneys and pockmarks. The model predicts: 1) formation of conical focused flow conduits with brecciated core and annular gas channels encased within a halo of low permeability sediment, 2) pockmarks of diverse shapes and sizes, including W-, U-, and ring-shapes, and 3) pulsed gas release. Results show that the morphology of FES depends on properties related to sediment-fluid interactions (like erodibility and flow anisotropy), not on intrinsic sediment properties (like permeability). Although the study is theoretical, we show that our predicted FES have many real world analogs, highlighting the broad scope of the predictive capability of our model.
    Type: Article , NonPeerReviewed , info:eu-repo/semantics/article
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  • 3
    Publication Date: 2023-02-08
    Description: Highlights • Code comparisons build confidence in simulators to model interdependent processes. • International hydrate reservoir simulators are compared over five complex problems. • Geomechanical processes significantly impact response of gas hydrate reservoirs. • Simulators yielded comparable results, however many differences are noted. • Equivalent constitutive models are required to achieve agreement across simulators. Geologic reservoirs containing gas hydrate occur beneath permafrost environments and within marine continental slope sediments, representing a potentially vast natural gas source. Numerical simulators provide scientists and engineers with tools for understanding how production efficiency depends on the numerous, interdependent (coupled) processes associated with potential production strategies for these gas hydrate reservoirs. Confidence in the modeling and forecasting abilities of these gas hydrate reservoir simulators (GHRSs) grows with successful comparisons against laboratory and field test results, but such results are rare, particularly in natural settings. The hydrate community recognized another approach to building confidence in the GHRS: comparing simulation results between independently developed and executed computer codes on structured problems specifically tailored to the interdependent processes relevant for gas hydrate-bearing systems. The United States Department of Energy, National Energy Technology Laboratory, (DOE/NETL), sponsored the first international gas hydrate code comparison study, IGHCCS1, in the early 2000s. IGHCCS1 focused on coupled thermal and hydrologic processes associated with producing gas hydrates from geologic reservoirs via depressurization and thermal stimulation. Subsequently, GHRSs have advanced to model more complex production technologies and incorporate geomechanical processes into the existing framework of coupled thermal and hydrologic modeling. This paper contributes to the validation of these recent GHRS developments by providing results from a second GHRS code comparison study, IGHCCS2, also sponsored by DOE/NETL. IGHCCS2 includes participants from an international collection of universities, research institutes, industry, national laboratories, and national geologic surveys. Study participants developed a series of five benchmark problems principally involving gas hydrate processes with geomechanical components. The five problems range from simple geometries with analytical solutions to a representation of the world's first offshore production test of methane hydrates, which was conducted with the depressurization method off the coast of Japan. To identify strengths and limitations in the various GHRSs, study participants submitted solutions for the benchmark problems and discussed differing results via teleconferences. The GHRSs evolved over the course of IGHCCS2 as researchers modified their simulators to reflect new insights, lessons learned, and suggested performance enhancements. The five benchmark problems, final sample solutions, and lessons learned that are presented here document the study outcomes and serve as a reference guide for developing and testing gas hydrate reservoir simulators.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2023-02-08
    Description: The migration of methane through the gas hydrate stability zone (GHSZ) in the marine subsurface is characterized by highly dynamic reactive transport processes coupled to thermodynamic phase transitions between solid gas hydrates, free methane gas, and dissolved methane in the aqueous phase. The marine subsurface is essentially a water-saturated porous medium where the thermodynamic instability of the hydrate phase can cause free gas pockets to appear and disappear locally, causing the model to degenerate. This poses serious convergence issues for the general-purpose nonlinear solvers (e.g., standard Newton), and often leads to extremely small time-step sizes. The convergence problem is particularly severe when the rate of hydrate phase change is much lower than the rate of gas dissolution. In order to overcome this numerical challenge, we have developed an all-at-once Newton scheme tailored to our gas hydrate model, which can handle rate-based hydrate phase change coupled with equilibrium gas dissolution in a mathematically consistent and robust manner.
    Type: Article , PeerReviewed
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  • 5
    Publication Date: 2024-02-07
    Description: Groundwater seepage leads to the formation of theater-headed valleys (THVs) in unconsolidated sediments. In bedrock, the role of groundwater in THV development remains disputed. Here, we integrate field and remote-sensing observations from Gnejna Valley (Maltese Islands) with numerical modeling to demonstrate that groundwater seepage can be the main driver of THV formation in jointed limestone overlying clays. The inferred erosion mechanisms entail (1) widening of joints and fractures by fluid pressure and dissolution and (2) creeping of an underlying clay layer, which lead to slope failure at the valley head and its upslope retreat. The latter is slower than the removal of the talus by creep and sliding on the valley bed. The location and width of THVs are controlled by the location of the master fault and the extent of the damage zone, respectively. The variability of seepage across the fault zone determines the shape of the valley head, with an exponential decrease in seepage away from the fault giving rise to a theater-shaped head that best matches that of Gnejna Valley. Our model may explain the formation of THVs by groundwater in jointed, strong-over-weak chemical sedimentary lithologies, particularly in arid terrestrial settings.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 6
    Publication Date: 2024-02-07
    Description: Offshore meteoric groundwater (OMG) has long been hypothesised to be a driver of seafloor geomorphic processes in continental margins worldwide. Testing this hypothesis has been challenging because of our limited understanding of the distribution and rate of OMG flow and seepage, and their efficacy as erosive/destabilising agents. Here we carry out numerical simulations of groundwater flow and slope stability using conceptual models and evolving stratigraphy - for passive siliciclastic and carbonate margin cases – to assess whether OMG and its evolution during a late Quaternary glacial cycle can generate the pore pressures required to trigger mechanical instabilities on the seafloor. Conceptual model results show that mechanical instabilities by OMG flow are most likely to occur in the outer shelf to upper slope, at or shortly before the Last Glacial Maximum sea level lowstand. Models with evolving stratigraphy show that OMG flow is a key driver of pore pressure development and instability in the carbonate margin case. In the siliciclastic margin case, OMG flow plays a secondary role in preconditioning the slope to failure. The higher degree of spatial/stratigraphic heterogeneity of carbonate margins, lower shear strengths of their sediments, and limited generation of overpressures by sediment loading may explain the higher susceptibility of carbonate margins, in comparison to siliciclastic margins, to mechanical instability by OMG flow. OMG likely played a more significant role in carbonate margin geomorphology (e.g. Bahamas, Maldives) than currently thought. Key Points Offshore meteoric groundwater (OMG) flow can drive mechanical instabilities in the outer shelf to upper slope Such instabilities occur at, or shortly after, the Last Glacial Maximum sea level lowstand Carbonate margins are more susceptible to mechanical instability by OMG than siliciclastic margins
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 7
    Publication Date: 2024-02-07
    Description: Subsurface flows, particularly hyporheic exchange fluxes, driven by streambed topography, permeability, channel gradient and dynamic flow conditions provide prominent ecological services such as nitrate removal from streams and aquifers. Stream flow dynamics cause strongly nonlinear and often episodic contributions of nutrient concentrations in river-aquifer systems. Using a fully coupled transient flow and reactive transport model, we investigated the denitrification potential of hyporheic zones during peak-flow events. The effects of streambed permeability, channel gradient and bedform amplitude on the spatio-temporal distribution of nitrate and dissolved organic carbon in streambeds and the associated denitrification potential were explored. Distinct peak-flow events with different intensity, duration and hydrograph shape were selected to represent a wide range of peak-flow scenarios. Our results indicated that the specific hydrodynamic characteristics of individual flow events largely determine the average positive or negative nitrate removal capacity of hyporheic zones, however the magnitude of this capacity is controlled by geomorphological settings (i.e. channel slope, streambed permeability and bedform amplitude). Specifically, events with longer duration and higher intensity were shown to promote higher nitrate removal efficiency with higher magnitude of removal efficiency in the scenarios with higher slope and permeability values. These results are essential for better assessment of the subsurface nitrate removal capacity under the influence of flow dynamics and particularly peak-flow events in order to provide tailored solutions for effective restoration of interconnected river-aquifer systems.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 8
    Publication Date: 2024-02-07
    Description: Highlights • Sedimentation-driven gas hydrate recycling is cyclic in nature with time scales set by reactive multi-phase transport. • Each cycle can be divided into three distinct phases: 1) gas accumulation phase, 2) gas breakthrough phase and 3) uninhibited hydrate build-up phase. • In the presence of sufficient accumulated gas, convex deposition of hydrate acts like a mechanical nozzle for the ascending gas flow. Gas hydrate recycling is an important process in natural hydrate systems worldwide and frequently leads to the high gas hydrate saturations found close to the base of the gas hydrate stability zone (GHSZ). However, to date it remains enigmatic how, and under which conditions, free gas invades back into the GHSZ. Here we use a 1D compositional multi-phase flow model that accounts for sedimentation to investigate the dominant mechanisms that control free gas flow into the GHSZ using a wide-range of parameters i.e. hydrate formation kinetics, sediment permeability, and capillary pressure. In the first part of this study, we investigate free gas invasion into the GHSZ without any sedimentation, and analyse the dynamics of hydrate formation in the vicinity of the base of GHSZ. This helps establish plausible initial conditions for the main part of the study, namely, hydrate recycling due to rapid and continuous sedimentation. For the case study, we apply our numerical model to the Green Canyon Site 955 in the Gulf of Mexico, where the reported high hydrate saturations are likely a result of hydrate recycling driven by rapid sedimentation. In the model, an initial hydrate layer forms due to the invasion of a specified volume of rising free gas. This hydrate layer is consistent with the local pressure, temperature and salinity state. This hydrate layer is then thermally de-stabilised by sedimentation resulting in free gas formation and hydrate recycling. A key finding of our study is that gas hydrate recycling is a cyclic process which can be divided into three phases of 1) gas hydrate melting and free gas nozzling through the hydrate layer, 2) formation of a new gas hydrate layer as the old layer vanishes, and 3) fast uninhibited grow of a new hydrate layer. High hydrate saturations of about 80% can be attained purely through physical, burial-driven recycling of gas hydrates, without any additional gas input from other sources. Hydrate recycling is, therefore, highly dynamic with its own inherent cyclicity rather than a gradual process paced by the rate of sediment deposition.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2024-02-07
    Description: Abrupt fluid emissions from shallow marine sediments pose a threat to seafloor installations like wind farms and offshore cables. Quantifying such fluid emissions and linking pockmarks, the seafloor manifestations of fluid escape, to flow in the sub-seafloor remains notoriously difficult due to an incomplete understanding of the underlying physical processes. Here, using a compositional multi-phase flow model, we test plausible gas sources for pockmarks in the south-eastern North Sea, which recent observations suggest have formed in response to major storms. We find that the mobilization of pre-existing gas pockets is unlikely because free gas, due to its high compressibility, damps the propagation of storm-induced pressure changes deeper into the subsurface. Rather, our results point to spontaneous appearance of a free gas phase via storm-induced gas exsolution from pore fluids. This mechanism is primarily driven by the pressure-sensitivity of gas solubility, and the appearance of free gas is largely confined to sediments in the vicinity of the seafloor. We show that in highly permeable sediments containing gas-rich pore fluids, wave-induced pressure changes result in the appearance of a persistent gas phase. This suggests that seafloor fluid escape structures are not always proxies for overpressured shallow gas and that periodic seafloor pressure changes can induce persistent free gas phase to spontaneously appear. Key Points - Storm-induced pressure changes can lead to spontaneous appearance of free gas phase near the seafloor - This process is driven by pressure-sensitive phase instabilities - This mechanism could help explain elusive gas sources in recently observed pockmarks in the North Sea
    Type: Article , PeerReviewed
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  • 10
    Publication Date: 2024-02-07
    Description: Focused fluid flow through sub-seafloor pipes and chimneys, and their seafloor manifestations as pockmarks, are ubiquitous. However, the dynamics of flow localization and evolution of fluid escape structures remain poorly understood. Models based on geomechanical mechanisms like hydro-fracturing and porosity wave propagation offer some useful insights into fluid flow and escape dynamics, but face limitations in capturing features like mobilized granular matter, especially in the upper sediment layers where the link between fracture and pockmark is not always clear. Here, we propose a mathematical model based on the multiphase theory of porous media, where changes in subsurface and seafloor morphology are resolved through seepage-induced erosion, fluidization, transport, and re-deposition of granular material. Through simulation of an idealized scenario of gas escape from overpressured shallow gas reservoir, we demonstrate that our model can capture flow localization and formation of pipes, chimneys, and pockmarks. Our simulations show (1) formation of conical focused-flow conduits with a brecciated core and annular gas channels; (2) pockmarks of W and ring shapes; and (3) pulsed release of gas. Sediment erodibility and flow anisotropy control the morphology of focused fluid flow and escape structures, while permeability shows negligible impact. While the geological setting for this study is theoretical, we show that our results have real-world analogs.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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