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  • Lucotte, Marc  (5)
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  • 1
    Online-Ressource
    Online-Ressource
    Canadian Science Publishing ; 1994
    In:  Canadian Journal of Earth Sciences Vol. 31, No. 1 ( 1994-01-01), p. 14-27
    In: Canadian Journal of Earth Sciences, Canadian Science Publishing, Vol. 31, No. 1 ( 1994-01-01), p. 14-27
    Kurzfassung: A sequential extraction procedure was applied to separate the oxides and lithogenous phases of iron and manganese and the organic and inorganic phosphorus phases in four box cores and one piston core from the slopes and rises of the Labrador Sea. Sedimentation rate, rather than the location in the basin, appears as a master variable of the diagenetic transformations of Fe, Mn, and P. High sedimentation rate, characteristic of two of the box cores, led to the creation of zones near the redox boundary of partial reprecipitation of dissolved Fe, Mn, and P released in the deeper reducing portions of the sediments. In contrast, surficial sediments from box cores with 10 times lower sedimentation rate only have sufficient reductive capacity to remobilize Mn hydroxides while leaving the Fe oxyhydroxides intact. Under these conditions, there is evidence for a redistribution of reactive inorganic P leading to the crystallization of carbonate fluorapatite in the top 30 cm of the cores. Gradual transformation of buried orthophosphate to authigenic apatite under suboxic conditions is also observed in the top 400 cm of the high sedimentation rate piston core. As in the box cores, the reaction is complete after several thousand years of burial and occurs in sediments characterized by low CaCO 3 content. Depending upon the sedimentation rates, the carbonate fluor-apatite crystallization may be superimposed on the changes in detrital sedimentary fluxes accompanying the onset of deglaciation. A proxy indicator of paleo-redox conditions, and thus of biodegradable organic matter accumulation at the sediment–water interface, is given by the ratio of iron oxides to the reactive inorganic P (solid orthophosphate plus authigenic apatite).
    Materialart: Online-Ressource
    ISSN: 0008-4077 , 1480-3313
    Sprache: Englisch
    Verlag: Canadian Science Publishing
    Publikationsdatum: 1994
    ZDB Id: 417294-2
    ZDB Id: 1491201-6
    SSG: 16,13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Online-Ressource
    Online-Ressource
    Canadian Science Publishing ; 1994
    In:  Canadian Journal of Earth Sciences Vol. 31, No. 1 ( 1994-01-01), p. 1-4
    In: Canadian Journal of Earth Sciences, Canadian Science Publishing, Vol. 31, No. 1 ( 1994-01-01), p. 1-4
    Materialart: Online-Ressource
    ISSN: 0008-4077 , 1480-3313
    Sprache: Englisch
    Verlag: Canadian Science Publishing
    Publikationsdatum: 1994
    ZDB Id: 417294-2
    ZDB Id: 1491201-6
    SSG: 16,13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Online-Ressource
    Online-Ressource
    Canadian Science Publishing ; 1994
    In:  Canadian Journal of Earth Sciences Vol. 31, No. 1 ( 1994-01-01), p. 5-13
    In: Canadian Journal of Earth Sciences, Canadian Science Publishing, Vol. 31, No. 1 ( 1994-01-01), p. 5-13
    Kurzfassung: The main deep water masses present at the time of the CSS Hudson cruises in Labrador and Irminger seas in June 1990 and October–November 1991 have been identified using characteristic temperatures (T) and salinities (S). The purpose of this study was to establish the transfer functions between micropaleontological assemblages of top sediments and thermohaline characteristics of water masses. The water mass at the top of the Labrador Sea (Labrador Sea Water, LSW) is formed after intense movements of winter convection in the first 900-m depth of the water column. Below that depth, the LSW parameters reach a double minimum (S ≈ 34.80 and T ≈ 2.9 °C). Only the sediments located on the continental slopes of Greenland and Labrador between depths of 500 and 1500 m are in contact with the LSW. Below the LSW, the superior fraction of the North East Atlantic Deep Water (NEADW1) is characterized by a temperature maximum (≈ 3.3 °C) and, as such, is distinguishable from the inferior fraction (NEADW2). The latter is characterized by a maximum S (≈ 34, 90) when compared with other intermediary and deep water masses. In contrast to the NEADW1 that freely circulates over the Reykjanes Ridge, the NEADW2 must flow through the Charlie Gibbs Fracture Zone to go from the northeastern Atlantic to the Irminger Sea. The NEADW 1 and 2 respectively bathe the ridge section less than 2000 m deep and the European abyssal basins. On the contrary, the majority of the deep sediments of the Labrador and Irminger seas are in contact with the cold (T  〈  2.6 °C) and salty (≈ 34.85) Denmark Strait Overflow Water. Although this water mass is normally found at depths exceeding 2700 m in pelagic environments, it can be found at less than 2000-m depth on the bottom of the continental slopes of Greenland and Labrador, where it is carried by the strong Deep Northern Boundary Current and Western Boundary Undercurrent. The presence of the NEADW 1 and 2 on the sediments is then restricted to narrow bands on the same continental slopes, between depths of 1800 and 2200 m.
    Materialart: Online-Ressource
    ISSN: 0008-4077 , 1480-3313
    Sprache: Englisch
    Verlag: Canadian Science Publishing
    Publikationsdatum: 1994
    ZDB Id: 417294-2
    ZDB Id: 1491201-6
    SSG: 16,13
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Online-Ressource
    Online-Ressource
    Elsevier BV ; 1991
    In:  Estuarine, Coastal and Shelf Science Vol. 32, No. 3 ( 1991-3), p. 297-312
    In: Estuarine, Coastal and Shelf Science, Elsevier BV, Vol. 32, No. 3 ( 1991-3), p. 297-312
    Materialart: Online-Ressource
    ISSN: 0272-7714
    Sprache: Englisch
    Verlag: Elsevier BV
    Publikationsdatum: 1991
    ZDB Id: 1466742-3
    ZDB Id: 763369-5
    SSG: 21,3
    SSG: 12
    SSG: 14
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 5
    Online-Ressource
    Online-Ressource
    Canadian Science Publishing ; 1994
    In:  Canadian Journal of Earth Sciences Vol. 31, No. 1 ( 1994-01-01), p. 139-158
    In: Canadian Journal of Earth Sciences, Canadian Science Publishing, Vol. 31, No. 1 ( 1994-01-01), p. 139-158
    Kurzfassung: Geochemical and micropaleontological analyses of Labrador Sea sediments allowed us to intercalibrate indicators of paleoproductivity and paleofluxes of carbon and to reconstitute biogeochemical fluxes, notably in relation to deep sea circulation changes (Western Boundary Undercurrent and North Atlantic Deep Water). Linear or logarithmic relations are observed between the subrecent fluxes of paleoproductivity indicators (coccoliths, diatoms, dinocysts, 230 Th), the 13 C content of left-coiling or sinistral Neogloboquadrina pachyderma, the modern surface water carbon production, and the rates of organic and inorganic carbon (C org , C inorg ) burial. All indicators increase by a factor of 10 2 to 10 3 in response to the evolution of paleosea-surface conditions since the last glacial maximum. Correlations are observed between authigenic C inorg , 230 Th, coccoliths, and 13 C content (left-coiling or sinistral Neogloboquadrina pachyderma), and also between authigenic C org , dinocysts, uranium, and sulfur. Relative C inorg /C org burial rates in the deep sediments ( 〉  3000 m) allow us to calculate a net CO 2 production in the basin. The net CO 2 flux was slightly negative between ~ 20 and ~ 15 ka BP. It reached a first maximum at about 9 ka BP (~ 30 μmol∙cm −2 ∙a −1 CO 2 ) followed by a decrease at ~ 8 ka BP (~ 20 μmol∙cm −2 ∙a −1 ). Since about 7 ka BP, it stabilized at ~ 35 μmol∙cm −2 ∙a −1 . The minimum observed at about 8 ka BP corresponds to a significant rate of C org burial accompanied with a maximum flux of redox-sensitive indicators (uranium, sulfur). This event does not correspond to any change in sea-surface temperature or salinity, nor in deep circulation, but may be related to the reorganization of the atmospheric circulation during a major breakup stage of the Laurentide ice sheet. The close correlation between the change in CO 2 production in the Labrador Sea with variations of atmospheric CO 2 concentrations during the last 20 ka BP suggests that the production of biogenic carbonates in subpolar basins plays a role in the global carbon cycle on the scale of glacial–interglacial climate changes.
    Materialart: Online-Ressource
    ISSN: 0008-4077 , 1480-3313
    Sprache: Englisch
    Verlag: Canadian Science Publishing
    Publikationsdatum: 1994
    ZDB Id: 417294-2
    ZDB Id: 1491201-6
    SSG: 16,13
    Standort Signatur Einschränkungen Verfügbarkeit
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